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arXiv 1701.04590cond-mat.mes-hall
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laser辐照改性GaAs纳米线的可见光致发光研究

Observing visible-range photoluminescence in GaAs nanowires modified by laser irradiation

P. A. Alekseev, M. S. Dunaevskiy, D. A. Kirilenko, A. N. Smirnov, V. Yu. Davydov, V. L. Berkovits

摘要:

本文研究了聚焦激光在轴向Zn-Zn/WZ异质结GaAs纳米线中引起的结构和化学变化。使用透射电子显微镜、能量色散X射线光谱、拉曼散射和光致发光光谱的组合进行实验。对于异质结的两个组成部分,在大气中的激光照射被发现产生一个双表面层,它是由结晶砷和非晶的GaO $_{x}$。后一种化合物是负责在GaAs纳米线的光致发光光谱中的1.76 eV处的峰的外观。在增加激光功率密度的条件下,由于样品加热,在纳米线的锌包覆部分表面上进行了表面结晶砷的蒸发和$β$ -Ga $_{2}$ O $_{3}$纳米晶的形成。所形成的纳米晶体显示在1.7-2.4 eV的可见光范围内的光致发光带。对于纳米线的纤锌矿部分,在相同的功率密度下,发生了总的非晶化,形成了$β$ -Ga $_{2}$ O $_{3}$纳米晶体.观察到的WZ-GaAs到$β$ -Ga $_{2}$ O $_{3}$纳米晶体的转变为产生用于光电和光子应用的轴向和径向异质结构ZB-GaAs/ $β$ -Ga $_{2}$ O $_{3}$提供了一种可行的方法。

英文摘要:

We study structural and chemical transformations induced by focused laser beam in GaAs nanowires with axial zinc-blende/wurtzite (ZB/WZ) heterostucture. The experiments are performed using a combination of transmission electron microscopy, energy-dispersive X-ray spectroscopy, Raman scattering, and photoluminescence spectroscopy. For the both components of heterostructure, laser irradiation under atmospheric air is found to produce a double surface layer which is composed of crystalline arsenic and of amorphous GaO$_{x}$. The latter compound is responsible for appearance of a peak at 1.76 eV in photoluminescence spectra of GaAs nanowires. Under increased laser power density, due to sample heating, evaporation of the surface crystalline arsenic and formation of $β$-Ga$_{2}$O$_{3}$ nanocrystals proceed on surface of the zinc-blende part of nanowire. The formed nanocrystals reveal a photoluminescence band in visible range of 1.7-2.4 eV. At the same power density for wurtzite part of the nanowire, total amorphization with formation of $β$-Ga$_{2}$O$_{3}$ nanocrystals occurs. Observed transformation of WZ-GaAs to $β$-Ga$_{2}$O$_{3}$ nanocrystals presents an available way for creation of axial and radial heterostuctures ZB-GaAs/$β$-Ga$_{2}$O$_{3}$ for optoelectronic and photonic applications.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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