We present a numerical study of quasiperiodic foams, in which the bubbles are generated as duals of quasiperiodic Frank-Kasper phases. These foams are investigated as potential candidates to the celebrated Kelvin problem for the partition of three-dimensional space with equal volume bubbles and minimal surface area. Interestingly, one of the computed structures falls close (but still slightly above) the best known Weaire-Phelan periodic candidate. This gives additional clues to understanding the main geometrical ingredients driving the Kelvin problem.
Quasicrystals have a higher degree of rotational and point-reflection symmetry than conventional crystals. As a result, quasicrystalline heterostructures fabricated from dielectric materials with micrometer-scale features exhibit interesting and useful optical properties including large photonic bandgaps in two-dimensional systems. We demonstrate the holographic assembly of two-dimensional and three-dimensional dielectric quasicrystalline heterostructures, including structures with specifically engineered defects. The highly uniform quasiperiodic arrays of optical traps used in this process al…
We describe the geometry of foams squeezed between two solid plates (2D GG foams) in two main asymptotic regimes: fully dry floor tiles and dry pancakes. We predict an abrupt transition between both regimes, with a substantial change in the Plateau border radius. This should be observable in different types of experiments on such 2D GG foams: when foam is being progressively dried or wetted, when it is being squeezed further or stretched, when it coarsens through film breakage or Oswald ripening.
For a three dimensional system we answer two questions, how simple a particle system might be to show the quasicrystal order and, what system features are the most important for quasicrystal formation? One-component system of particles with isotropic pair interaction is one of the simplest ones. We show that such system may be driven to three-dimensional decagonal (10-fold) quasicrystalline state just by purely repulsive, isotropic and monotonic interaction pair potential with two characteristic length scales; no attraction is needed. The second question we answer defining universal (nearly in…
We study the steady flow properties of different three-dimensional aqueous foams in a wide gap Couette geometry. From local velocity measurements through Magnetic Resonance Imaging techniques and from viscosity bifurcation experiments, we find that these foams do not exhibit any observable signature of shear banding. This contrasts with two previous results (Rodts et al., Europhys. Lett., 69 (2005) 636 and Da Cruz et al., Phys. Rev. E, 66 (2002) 051305); we discuss possible reasons for this dicrepancy. Moreover, the foams we studied undergo steady flow for shear rates well below the critical s…
For sufficiently slow rates of strain, flowing foam can exhibit inhomogeneous flows. The nature of these flows is an area of active study in both two-dimensional model foams and three dimensional foam. Recent work in three-dimensional foam has identified three distinct regimes of flow [S. Rodts, J. C. Baudez, and P. Coussot, Europhys. Lett. {\bf 69}, 636 (2005)]. Two of these regimes are identified with continuum behavior (full flow and shear-banding), and the third regime is identified as a discrete regime exhibiting extreme localization. In this paper, the discrete regime is studied in more …
We utilize total-internal reflection to isolate the two-dimensional `surface foam' formed at the planar boundary of a three-dimensional sample. The resulting images of surface Plateau borders are consistent with Plateau's laws for a truly two-dimensional foam. Samples are allowed to coarsen into a self-similar scaling state where statistical distributions are independent of time, except for an overall scale factor. There we find that statistical measures of side number distributions, size-topology correlations, and bubble shapes, are all very similar to those for two-dimensional foams. However…
We study diamagnetically levitated foams with widely different liquid fractions. Due to the levitation, drainage is effectively suppressed and the dynamics is driven by the coarsening of the foam bubbles. For dry foams, the bubble size increases as the square root of foam age, as expected from a generalized von Neumann law. At higher liquid content, the behavior changes to that of Ostwald ripening where the bubbles grow with the 1/3 power of the age. Using Diffusing Wave Spectroscopy we study the local dynamics in the different regimes and find diffusive behavior for dry foams and kinetic beha…
We suggest a scalar model for deformation and flow of an amorphous material such as a foam or an emulsion. To describe elastic, plastic and viscous behaviours, we use three scalar variables: elastic deformation, plastic deformation rate and total deformation rate; and three material specific parameters: shear modulus, yield deformation and viscosity. We obtain equations valid for different types of deformations and flows slower than the relaxation rate towards mechanical equilibrium. In particular, they are valid both in transient or steady flow regimes, even at large elastic deformation. We d…
The equilibrium conditions impose nontrivial geometrical constraints on the configurations that a two-dimensional foam can attain. In the first place, the three centers of the films that converge to a vertex have to be on a line, i.e. all vertices are aligned. Moreover an equilibrated foam must admit a reciprocal figure. This means that it must be possible to find a set of points P_i on the plane, one per bubble, such that the segments (P_i P_j) are normal to the corresponding foam films. It is furthermore shown that these constraints are equivalent to the requirement that the foam be a Sectio…
Under steady shear, a foam relaxes stress through intermittent rearrangements of bubbles accompanied by sudden drops in the stored elastic energy. We use a simple model of foam that incorporates both elasticity and dissipation to study the statistics of bubble rearrangements in terms of energy drops, the number of nearest neighbor changes, and the rate of neighbor-switching (T1) events. We do this for a two-dimensional system as a function of system size, shear rate, dissipation mechanism, and gas area fraction. We find that for dry foams, there is a well-defined quasistatic limit at low shear…
The paper describes a study of wet foams in microgravity whose bubble size distribution evolves due to diffusive gas exchange. We focus on the comparison between the size of bubbles determined from images of the foam surface and the size of bubbles in the bulk foam, determined from Diffuse Transmission Spectroscopy (DTS). Extracting the bubble size distribution from images of a foam surface is difficult so we have used three different procedures : manual analysis, automatic analysis with a customized Python script and machine learning analysis. Once various pitfalls were identified and taken i…
The origin of diffusive transport of light in dry foams is still under debate. In this paper, we consider the random walks of photons as they are reflected or transmitted by liquid films according to the rules of ray optics. The foams are approximately modeled by three-dimensional Voronoi tessellations with varying degree of disorder. We study two cases: a constant intensity reflectance and the reflectance of thin films. Especially in the second case, we find that in the experimentally important regime for the film thicknesses, the transport-mean-free path does not significantly depend on the …
Three-dimensional foam flow resolved by fast X-ray tomographic microscopy
CNRS（法国国家科学研究中心）；Institut de Physique de Rennes（雷恩物理研究所）；Institute for Biomedical Engineering, University and ETH Zurich（苏黎世联邦理工学院生物医学工程研究所）；ETH Zurich（苏黎世联邦理工学院）；Swiss Light Source, Paul Scherrer Institute（瑞士光子源，保罗谢尔研究所）；Laboratoire de Physique, ENS Lyon（里昂高等师范学校物理实验室）
A Stokes experiment for foams is proposed. It consists in a two-dimensional flow of a foam, confined between a water subphase and a top plate, around a fixed circular obstacle. We present systematic measurements of the drag exerted by the flowing foam on the obstacle, \emph{versus} various separately controlled parameters: flow rate, bubble volume, solution viscosity, obstacle size and boundary conditions. We separate the drag into two contributions, an elastic one (yield drag) at vanishing flow rate, and a fluid one (viscous coefficient) increasing with flow rate. We quantify the influence of…
Open cell foams have diverse industrial applications e.g. heat exchangers, structured reactors, filtration due to their unique properties such as high porosity and high specific surface area. In order to theoretically determine the geometric specific surface area and relationships between geometrical parameters of isotropic open cell foams, a generalized mathematical correlation was developed. For this purpose the tetrakaidecahedron geometry was used and different shapes of strut cross-sections of foam structures were taken explicitly into account. The derived correlation to predict geometrica…
In this article, we discuss the stability of soft quasicrystalline phases in a coupled-mode Swift-Hohenberg model for three-component systems, where the characteristic length scales are governed by the positive-definite gradient terms. Classic two-mode approximation method and direct numerical minimization are applied to the model. In the latter approach, we apply the projection method to deal with the potentially quasiperiodic ground states. A variable cell method of optimizing the shape and size of higher-dimensional periodic cell is developed to minimize the free energy with respect to the …
Sheared wet foam, which stores elastic energy in bubble deformations, relaxes stress through bubble rearrangements. The intermittency of bubble rearrangements in foam leads to effectively stochastic drops in stress that are followed by periods of elastic increase. We investigate global characteristics of highly disordered foams over three decades of strain rate and almost two decades of system size. We characterize the behavior using a range of measures: average stress, distribution of stress drops, rate of stress drops, and a normalized fluctuation intensity. There is essentially no dependenc…
In wet liquid foams, slow diffusion of gas through bubble walls changes bubble pressure, volume and wall curvature. Large bubbles grow at the expenses of smaller ones. The smaller the bubble, the faster it shrinks. As the number of bubbles in a given volume decreases in time, the average bubble size increases: i.e. the foam coarsens. During coarsening, bubbles also move relative to each other, changing bubble topology and shape, while liquid moves within the regions separating the bubbles. Analyzing the combined effects of these mechanisms requires examining a volume with enough bubbles to pro…
Coarsening in foams made from the pure liquid crystal, 8CB, has been studied. The foam was made in the nematic phase ($\textrm{T} = 35 ^{\circ}\textrm{C}$) by bubbling nitrogen through the pure liquid crystal. The coarsening behavior was investigated at three temperatures; at $\textrm{T} = 22 ^{\circ}\textrm{C}$ and $33^{\circ}\textrm{C}$ in the smectic phase and at $\textrm{T} = 34^{\circ}\textrm{C}$ in the nematic phase. In smectic and nematic phases the mean bubble radius $<R>$ has been measured as a function of time $<R > \sim t^λ$. In classical wet soap foams the growth exponent is typica…
In this paper, an enthalpy-based multiple-relaxation-time (MRT) lattice Boltzmann (LB) method is developed for solid-liquid phase change heat transfer in metal foams under local thermal non-equilibrium (LTNE) condition. The enthalpy-based MRT-LB method consists of three different MRT-LB models: one for flow field based on the generalized non-Darcy model, and the other two for phase change material (PCM) and metal foam temperature fields described by the LTNE model. The moving solid-liquid phase interface is implicitly tracked through the liquid fraction, which is simultaneously obtained when t…
Discrete rearranging patterns include cellular patterns, for instance liquid foams, biological tissues, grains in polycrystals; assemblies of particles such as beads, granular materials, colloids, molecules, atoms; and interconnected networks. Such a pattern can be described as a list of links between neighbouring sites. Performing statistics on the links between neighbouring sites yields average quantities (hereafter "tools") as the result of direct measurements on images. These descriptive tools are flexible and suitable for various problems where quantitative measurements are required, whet…
Model patchy particles have been shown to be able to form a wide variety of structures, including symmetric clusters, complex crystals and even two-dimensional quasicrystals. Here, we investigate whether we can design patchy particles that form three-dimensional quasicrystals, in particular targeting a quasicrystal with dodecagonal symmetry that is made up of stacks of two-dimensional quasicrystalline layers. We obtain two designs that are able to form such a dodecagonal quasicrystal in annealing simulations. The first is a one-component system of 7-patch particles but with wide patches that a…
In two dimensional foams at equilibrium, triangular bubbles can be freely exchanged with 3-fold stars --three edges ending at a central vertex. This theorem is deduced here from Moukarzel's duality. Moreover, to probe the method, a few related properties are established: under slow gas diffusion, T2 processes are continuous for triangles but not for other types of bubbles. In general, the gas flow results in different configurations in the presence of a triangle than in the presence of a star.
Systems of active particles are often affected by confinement due to nearby boundaries. Recently, there has been interest in the effect of confinement by complex three dimensional geometries, as might occur in structured environments such as porous media, foams, gels, or biological tissues and ducts. The effects of confinement for particles moving along boundaries has been extensively studied, but in three dimensions active particles move not only parallel to boundaries, but also towards or away from boundaries. The consequences of this fore-aft clearance is less well understood. Swimmers that…
