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arXiv 1610.02206cond-mat.mtrl-sci
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由正组分制备负热膨胀系数的微结构双组分三维超材料

Micro-Structured Two-Component 3D Metamaterials with Negative Thermal-Expansion Coefficient from Positive Constituents

Jingyuan Qu, Muamer Kadic, Andreas Naber, Martin Wegener

摘要:

控制材料的热膨胀具有重要的技术意义。不受控制的热膨胀可导致结构和装置的失效或不可逆的破坏。在普通晶体中,热膨胀由微观结合势的不对称性决定,而这种不对称性不容易调节。在称为超材料的人造晶体中,热膨胀可以通过结构来控制。在这里,根据以前的理论工作,我们制造三维双组分聚合物微晶格使用灰度激光光刻。我们进行交叉相关分析的光学显微镜图像在不同的样品温度。导出的位移矢量场揭示了双材料梁的热膨胀和由此产生的弯曲导致布置在一个超材料单元内的3D棋盘图案上的3D手征十字的旋转。这些旋转可以过度补偿膨胀,并导致所有正成分的有效负的热长度膨胀系数,证明了热膨胀控制的惊人水平。

英文摘要:

Controlling the thermal expansion of materials is of great technological importance. Uncontrolled thermal expansion can lead to failure or irreversible destruction of structures and devices. In ordinary crystals, thermal expansion is governed by the asymmetry of the microscopic binding potential, which cannot be adjusted easily. In artificial crystals called metamaterials, thermal expansion can be controlled by structure. Here, following previous theoretical work, we fabricate three-dimensional two-component polymer microlattices by using gray-tone laser lithography. We perform cross-correlation analysis of optical microscopy images taken at different sample temperatures. The derived displacement-vector field reveals that the thermal expansion and resulting bending of the bi-material beams leads to a rotation of the 3D chiral crosses arranged onto a 3D checkerboard pattern within one metamaterial unit cell. These rotations can over-compensate the expansion and lead to an effectively negative thermal length-expansion coefficient for all positive constituents evidencing a striking level of thermal-expansion control.

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