利用拉曼光谱监测悬浮石墨烯中的静电诱导偏转、应变和掺杂
Monitoring Electrostatically-Induced Deflection, Strain and Doping in Suspended Graphene using Raman Spectroscopy
摘要:
静电门控提供了同时应变和掺杂原子级薄膜的优雅方法。在这里,我们报告了一个详细的\textit{in situ}拉曼散射研究石墨烯,悬浮在Si/SiO $_2$衬底。在这种分层结构中,石墨烯的拉曼G-和2D-模式特征的强度通过光学干涉效应被强烈调制,并且允许精确确定静电诱导的膜偏转,直到不可逆的塌陷。膜偏转成功地描述了机电模型,我们也使用它来提供有用的指南,器件工程。此外,静电诱导的拉伸应变是通过检查软化的拉曼功能。由于一个小的剩余电荷不均匀性$\sim 5\times 10^{10}~\rm cm^{-2}$,我们发现,非绝热异常声子软化是可以忽略不计相比,应变诱导声子软化。这些结果为二维纳米晶体中基于拉曼散射的创新读出方案开辟了前景。
英文摘要:
Electrostatic gating offers elegant ways to simultaneously strain and dope atomically thin membranes. Here, we report on a detailed \textit{in situ} Raman scattering study on graphene, suspended over a Si/SiO$_2$ substrate. In such a layered structure, the intensity of the Raman G- and 2D-mode features of graphene are strongly modulated by optical interference effects and allow an accurate determination of the electrostatically-induced membrane deflection, up to irreversible collapse. The membrane deflection is successfully described by an electromechanical model, which we also use to provide useful guidelines for device engineering. In addition, electrostatically-induced tensile strain is determined by examining the softening of the Raman features. Due to a small residual charge inhomogeneity $\sim 5\times 10^{10}~\rm cm^{-2}$, we find that non-adiabatic anomalous phonon softening is negligible compared to strain-induced phonon softening. These results open perspectives for innovative Raman scattering-based readout schemes in two-dimensional nanoreso
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