纳米尺度下的电化学动力学和尺寸考虑
Electrochemical kinetics and dimensional considerations at the nanoscale
摘要：
结果表明，考虑在纳米电化学系统的状态密度的变化产生调制的速率常数和伴随的电流。该模型将Marcus-Hush-Chidsey（MHC）动力学的实用性扩展到更大的一类材料，并可用作尺寸特性的测试。研究结果对理解和调控纳米结构电极具有重要意义。
英文摘要：
It is shown that the consideration of the density of states variation in nanoscale electrochemical systems yields modulations in the rate constant and concomitant electrical currents. The proposed models extend the utility of Marcus-Hush-Chidsey (MHC) kinetics to a larger class of materials and could be used as a test of dimensional character. The implications of the study are of much significance to an understanding and modulation of charge transfer nanostructured electrodes.
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