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arXiv 1604.03028cond-mat.supr-con
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铜酸盐和磷属元素化物的超导phase diagrams作为HTSC机制的关键

Superconducting phase diagrams of cuprates and pnictides as a key to the HTSC mechanism

K. V. Mitsen, O. M. Ivanenko

摘要:

本文回顾了铜酸盐和磷族化合物的实验相图,以证明在所提出的方法的框架内,它假设形成,在异价掺杂,局部trion复合物组成的掺杂载流子和电荷转移(CT)激子的超导相图的具体功能,在bothHTSC家庭可以理解。在晶体的基面中含有CT激子(CT斑)的这种单元的几何形状由其晶体结构和掺杂剂的类型确定,使得对于每种特定化合物,可以容易地确定对应于CT斑的渗滤簇的存在的掺杂剂浓度范围。这些掺杂剂的浓度范围符合良好的精度与实验范围的超导圆顶的相图中考虑的高温超导化合物。在这种模式中,自由载流子的产生和超导配对机制与相邻CT斑块中出现的双激子复合物(Heitler-London中心)有关。

英文摘要:

This paper reviews experimental phase diagrams of cuprates and pnictides to demonstrate that specific features of the superconducting phase diagrams in bothHTSC families can be understood within the framework of the proposed approach,which assumes the formation, under heterovalent doping, of localized trion complexes consisting of a doped carrier and charge transfer (CT) excitons. The geometry of such cells containing CT excitons (CT plaquettes) in the basal plane of the crystal is determined by its crystal structure and the type of dopant, so that the dopant concentration range corresponding to the existence of a percolation cluster of CT plaquettes can be readily determined for each particular compound. These dopant concentration ranges coincide with good accuracy with the experimental ranges of superconducting domes in the phase diagrams of the HTSC compounds considered. The generation of free carriers and the mechanism of superconducting pairing in this pattern is related to biexciton complexes (Heitler-London centers) emerging in neighboring CT plaquettes.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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