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arXiv 1602.07899cond-mat.str-elcond-mat.other
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准方钴矿Ce PDMATHAAB Os PDMATHAAC Ge $_{13}$单晶中少子Ce $^{3+}$自旋的铁磁有序

Ferromagnetic ordering of minority Ce$^{3+}$ spins in a quasi-skutterudite Ce${_3}$Os${_4}$Ge$_{13}$ single crystal

Om Prakash, A. Thamizhavel, S. Ramakrishnan

摘要:

本文报道了在0.5~K温度下,Ce、${_3}$、Os、${_4}$、Ge、$_{13}$单晶中近8个$\%$、Ce原子的铁磁有序. Ce ${_3}$ Os ${_4}$ Ge $_{13}$以立方结构结晶,空间群为$\it{Pm\bar{3}n}$。结构分析表明,体系中存在位序无序,其中2(a)Ge位部分被Ce原子占据。由于小的Ce $4f$ -配体杂化,这些Ce原子处于Ce $^{3+}$(磁性)状态,而晶胞中的其余Ce原子处于Ce $^{4-δ}$(非磁性)状态。热容在0.5~K以下出现一个峰,对应于Ce $^{3+}$磁矩的铁磁有序。在交流磁化率数据中还观察到低于0.5~K的铁磁有序。在低温下(1.8~K $\leq T\leq 6$ ~K),磁化强度表现出$log(T)$依赖性,而电阻率表现出幂律($T^n$)温度依赖性,表明准粒子的非费米液体行为。

英文摘要:

We report site disorder driven ferromagnetic ordering of nearly 8$\%$ Ce atoms in single crystalline Ce${_3}$Os${_4}$Ge$_{13}$ below 0.5~K. Ce${_3}$Os${_4}$Ge$_{13}$ crystallizes in a cubic structure with space group $\it{Pm\bar{3}n}$. The structural analysis shows the presence of site-disorder in the system, where 2(a) Ge site is partially occupied by the Ce atoms. Due to the small Ce $4f$-ligand hybridization, these Ce atoms are in the Ce$^{3+}$ (magnetic) state while rest of the Ce atoms in the unit cell are in Ce$^{4-δ}$ (non-magnetic) state. The heat capacity shows a peak below 0.5~K corresponding to the ferromagnetic ordering of the Ce$^{3+}$ moments. The ferromagnetic ordering below 0.5~K is also seen in the ac-susceptibility data. At low temperatures (1.8~K$\leq T\leq 6$~K), the magnetization shows $log(T)$ dependence, whereas the resistivity shows power law ($T^n$) temperature dependence indicating the non-Fermi liquid behavior of the quasiparticles.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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