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arXiv 1507.06133cond-mat.mtrl-sci
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一阶磁热材料熵变的间接磁学方法

An indirect magnetic approach for determining entropy change in first-order magnetocaloric materials

Kun Xu, Zhe Li, Yuan-Lei Zhang, Chao Jing

摘要:

考虑相变过程中相分数的影响,基于Clausius-Clapeyron(CC)方程,提出了一种改进的一级磁热材料等温熵变测定方法.结果表明,对于Ni-Mn-Sn Heusler合金,该方法计算的等温熵变值与麦克斯韦关系式(MR)计算的等温熵变值非常吻合,表明Ni-Mn-Sn Heusler合金通常表现为弱场诱导相变行为。与磁共振法相比,该方法只需少量的热磁测量就能得到满意的结果。更重要的是,我们可以消除等温熵变的高估来自MR,这总是存在于Ni-Co-Mn-In和MnAs系统的情况下,具有显着的场诱导转变。这些结果证实了这种基于CC方程的方法是非常实用的,并且在消除虚假尖峰和降低测量成本方面优于基于MR的方法。

英文摘要:

Taking into account the phase fraction during transition for the first-order magnetocaloric materials, an improved isothermal entropy change determination has been put forward based on the Clausius-Clapeyron (CC) equation. It was found that the isothermal entropy change value evaluated by our method is in excellent agreement with those determined from the Maxwell-relation (MR) for Ni-Mn-Sn Heusler alloys, which usually presents a weak field-induced phase transforming behavior. In comparison with MR, this method could give rise to a favorable result derived from few thermomagnetic measurements. More importantly, we can eliminate the isothermal entropy change overestimation derived from MR, which always exists in the cases of Ni-Co-Mn-In and MnAs systems with a prominent field-induced transition. These results confirmed that such a CC-equation-based method is quite practical and superior to the MR-based ones in eliminating the spurious spike and reducing measuring cost.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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