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arXiv 1503.04236cond-mat.stat-mechmath-phmath.MPmath.PR
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不可逆反应和扩散逃逸:定态性质

Irreversible Reactions and Diffusive Escape: Stationary Properties

P. L. Krapivsky, E. Ben-Naim

摘要:

我们研究了三个基本的扩散控制反应过程--湮灭、聚结和聚集。我们研究的演变开始与最自然的不均匀的初始配置,其中半线是均匀填充的粒子,而互补的半线是空的。我们表明,渗透到最初空的半线的粒子的总数是有限的,并有一个固定的分布。我们确定平均密度的演变,从中我们得出初始空半行中粒子的平均总数N;例如,对于湮灭,\langle N \rangle = 3/16+1/(4π)。对于聚结过程,我们设计了一个程序,原则上允许计算P(N),在最初的空半行中找到正好N个粒子的概率;我们在第一个非平凡的情况下完成计算(N=1)。作为一个副产品,我们得到两个领先粒子之间的距离分布。

英文摘要:

We study three basic diffusion-controlled reaction processes -- annihilation, coalescence, and aggregation. We examine the evolution starting with the most natural inhomogeneous initial configuration where a half-line is uniformly filled by particles, while the complementary half-line is empty. We show that the total number of particles that infiltrate the initially empty half-line is finite and has a stationary distribution. We determine the evolution of the average density from which we derive the average total number N of particles in the initially empty half-line; e.g., for annihilation \langle N\rangle = 3/16+1/(4π). For the coalescence process, we devise a procedure that in principle allows one to compute P(N), the probability to find exactly N particles in the initially empty half-line; we complete the calculations in the first non-trivial case (N=1). As a by-product we derive the distance distribution between the two leading particles.

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