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arXiv 1408.4610physics.flu-dyn
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微通道中的浓差极化、表面电流和体平流

Concentration polarization, surface currents, and bulk advection in a microchannel

Christoffer P. Nielsen, Henrik Bruus

摘要:

本文对浓差极化过程中微通道中的盐输运和过限电流进行了全面的分析。我们已经进行了充分的耦合泊松-能斯特-普朗克-斯托克斯问题的数值模拟管理的运输和合理化的系统的行为。一个显着的调查结果是发现强耦合之间的散装平流和表面电流;没有表面电流,散装平流强烈抑制。数值模拟的补充分析模型有效的长通道限制,以及在可忽略的表面电荷的限制。通过包括扩散和平流的影响,在扩散的双电层的一部分,我们扩展了最近发表的分析模型,由于表面传导的过限电流。

英文摘要:

We present a comprehensive analysis of salt transport and overlimiting currents in a microchannel during concentration polarization. We have carried out full numerical simulations of the coupled Poisson-Nernst-Planck-Stokes problem governing the transport and rationalized the behaviour of the system. A remarkable outcome of the investigations is the discovery of strong couplings between bulk advection and the surface current; without a surface current, bulk advection is strongly suppressed. The numerical simulations are supplemented by analytical models valid in the long channel limit as well as in the limit of negligible surface charge. By including the effects of diffusion and advection in the diffuse part of the electric double layers, we extend a recently published analytical model of overlimiting current due to surface conduction.

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