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arXiv 1405.6491cond-mat.stat-mech
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超临界铁的动态相变

Dynamic transition in supercritical iron

Yu. D. Fomin, V. N. Ryzhov, E. N. Tsiok, V. V. Brazhkin, K. Trachenko

摘要:

最近在理解超临界状态方面的进展假定在临界点以上存在一条新的线,将物质的两种物理上不同的状态分开:刚性液体和非刚性气体状流体。这条线的位置,弗伦克尔线,仍然是未知的重要的真实系统。在这里,我们使用分子动力学模拟绘制超临界铁相图上的弗伦克尔线。在我们的数据的基础上,我们提出了一个通用的配方来定位Frenkel线的任何系统,配方,重要的是不涉及系统特定的详细计算,只依赖于知识的熔化线。进一步讨论了超临界液态金属中Frenkel线与金属-绝缘体相变的关系。我们的研究结果能够预测在几个感兴趣的条件下的超临界铁的状态。特别是,我们预测,在木星核心的液态铁是在“刚性液体”的状态,是高度导电。最后,我们分析了较小行星(如地球和金星)以及系外行星核心铁电导率的演变:随着行星冷却,超临界核心在Frenkel线处过渡到刚性液体导电状态。

英文摘要:

Recent advance in understanding the supercritical state posits the existence of a new line above the critical point separating two physically distinct states of matter: rigid liquid and non-rigid gas-like fluid. The location of this line, the Frenkel line, remains unknown for important real systems. Here, we map the Frenkel line on the phase diagram of supercritical iron using molecular dynamics simulations. On the basis of our data, we propose a general recipe to locate the Frenkel line for any system, the recipe that importantly does not involve system-specific detailed calculations and relies on the knowledge of the melting line only. We further discuss the relationship between the Frenkel line and the metal-insulator transition in supercritical liquid metals. Our results enable predicting the state of supercritical iron in several conditions of interest. In particular, we predict that liquid iron in the Jupiter core is in the "rigid liquid" state and is highly conducting. We finally analyse the evolution of iron conductivity in the core of smaller planets such as Earth and Venus as well as exoplanets: as planets cool off, the supercritical core undergoes the transition to the rigid-liquid conducting state at the Frenkel line.

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