The discovery of conducting two-dimensional electron gas (2DEG) and magnetism at the interface between insulating nonmagnetic oxides, as exemplified by the polar LaAlO3 and nonpolar SrTiO3 has raised prospects for attaining interfacial functionalities absent in the component materials. Yet, the microscopic origin of such emergent phenomena remains unclear, posing obstacles to design of improved functionalities. Using first principles defect calculations, we reveal a unifying polarity-induced defect mechanism for both conductivity and magnetism at polar-nonpolar interfaces of nonmagnetic insulating oxides. We demonstrate that the polar-discontinuity across the interface triggers thermodynamically the spontaneous formation of certain defects that in turn cancel the polar field induced by the polar discontinuity. It turns out that the 2DEG originates from those spontaneously formed surface donor defects (oxygen vacancy), but the density of 2DEG is controlled by the interfacial anti-site acceptor defects (Al-on-Ti). The interface magnetism is found to originate from the un-ionized deep Ti-on-Al anti-site donor defects within the LaAlO3 side near the interface. Our results suggest practical design guidelines for inducing and controlling both 2DEG and magnetism at polar-nonpolar oxide interfaces.
Unexpected type-II multiferroic phase in GdMnO3 under high magnetic fields
Huazhong University of Science and Technology（华中科技大学）；Southeast University（东南大学）；Chinese Academy of Sciences（中国科学院）；University of Texas at Austin（德克萨斯大学奥斯汀分校）
Reconfigurable Strain Gradient Polarity in Crystalline Oxide Nanomembranes for Controlled Bending of Functional Materials
Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory（斯坦福材料能源科学研究所，SLAC国家加速器实验室）；Department of Applied Physics, Stanford University（斯坦福大学应用物理系）；Department of Physics, Stanford University（斯坦福大学物理系）
Evidence of room temperature magnetoelectric properties in α-Fe1.6Ga0.4O3 oxide by magnetic field controlled electric properties and electric field controlled magnetism
