arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1401.2658physics.chem-phcond-mat.mtrl-sci
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为什么铅甲基铵三碘化钙钛矿基太阳能电池需要介孔电子传输支架(但不一定是空穴导体)

Why Lead Methylammonium tri-IODIDE perovskite-based solar cells requires a mesoporous electron transporting scaffold (but not necessarily a hole conductor)

Eran Edri, Saar Kirmayer, Alex Henning, Sabyasachi Mukhopadhyay, Konstantin Gartsman, Yossi Rosenwaks, Gary Hodes, David Cahen

摘要:

采用电子束感应电流(EBIC)对CH 3 NH3 PbI 3基太阳能电池进行了表征,并与CH 3 NH3 PbI 3-xClx基太阳能电池进行了比较。工作电池中的电荷分离效率的空间图示出了两种薄膜电池的p-i-n结构。有效扩散长度,LD,(从EBIC曲线)表明,空穴提取显着更有效地比电子在CH 3 NH3 PbI 3,解释了为什么CH 3 NH3 PbI 3为基础的电池需要介孔电子导体,而CH 3 NH3 PbI 3-xClx的,其中LD值是可比的两种电荷类型,不。

英文摘要:

CH3NH3PbI3-based solar cells were characterized with electron beam-induced current (EBIC), and compared to CH3NH3PbI3-xClx ones. A spatial map of charge separation efficiency in working cells shows p-i-n structures for both thin film cells. Effective diffusion lengths, LD, (from EBIC profile) show that holes are extracted significantly more efficiently than electrons in CH3NH3PbI3, explaining why CH3NH3PbI3-based cells require mesoporous electron conductors, while CH3NH3PbI3-xClx ones, where LD values are comparable for both charge types, do not.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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