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arXiv 1312.7705cond-mat.mtrl-sci
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一种用于热场测绘和热导率测定的新型高分辨率非接触式技术:双Laser拉曼测温法

A novel high resolution contactless technique for thermal field mapping and thermal conductivity determination: Two-Laser Raman Thermometry

J. S. Reparaz, E. Chavez-Angel, M. R. Wagner, B. Graczykowski, J. Gomis-Bresco, F. Alzina, C. M. Sotomayor Torres

摘要:

我们提出了一种新的高分辨率非接触式技术的热导率测定和热场映射的基础上创建一个热分布的声子使用加热激光,而第二激光探针的局部温度通过拉曼活性模式的光谱位置。空间分辨率可小至$300$ nm,而其温度精度为$\pm 2$ K。我们验证了这种技术调查的三个独立的单晶硅膜的厚度为250,1000,和2000 nm的热性能。我们表明,对于2维材料,如独立的膜或薄膜,并为小的温度梯度,热场衰减为$T(r) \propto ln(r)$在扩散极限。膜内的大温度梯度的情况导致热场$T \propto exp[-A \cdot ln(r)]$的指数衰减。结果表明,这种新的非接触式方法的热性能定量测定的全部潜力。这种方法适用的材料范围远远超出了这里所展示的Si的情况,因为唯一的要求是拉曼活性模式的存在。

英文摘要:

We present a novel high resolution contactless technique for thermal conductivity determination and thermal field mapping based on creating a thermal distribution of phonons using a heating laser, while a second laser probes the local temperature through the spectral position of a Raman active mode. The spatial resolution can be as small as $300$ nm, whereas its temperature accuracy is $\pm 2$ K. We validate this technique investigating the thermal properties of three free-standing single crystalline Si membranes with thickness of 250, 1000, and 2000 nm. We show that for 2-dimensional materials such as free-standing membranes or thin films, and for small temperature gradients, the thermal field decays as $T(r) \propto ln(r)$ in the diffusive limit. The case of large temperature gradients within the membranes leads to an exponential decay of the thermal field, $T \propto exp[-A \cdot ln(r)]$. The results demonstrate the full potential of this new contactless method for quantitative determination of thermal properties. The range of materials to which this method is applicable reaches far beyond the here demonstrated case of Si, as the only requirement is the presence of a Raman active mode.

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