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arXiv 1311.7614cond-mat.str-el
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控制一维和零维分子基磁体中的磁有序和量子无序

Controlling magnetic order and quantum disorder in one- and zero-dimensional molecule-based magnets

T. Lancaster, P. A. Goddard, S. J. Blundell, F. R. Foronda, S. Ghannadzadeh, J. S. Möller, P. J. Baker, F. L. Pratt, C. Baines, L. Huang, J. Wosnitza, R. D. McD… 展开作者

T. Lancaster, P. A. Goddard, S. J. Blundell, F. R. Foronda, S. Ghannadzadeh, J. S. Möller, P. J. Baker, F. L. Pratt, C. Baines, L. Huang, J. Wosnitza, R. D. McDonald, K. A. Modic, J. Singleton, C. V. Topping, T. A. W. Beale, F. Xiao, J. A. Schlueter, R. D. Cabrera, K. E. Carreiro, H. E. Tran, J. L. Manson

摘要:

我们研究了从相同起始组分合成的两种分子基磁体的结构和磁性。它们不同的结构基序促进了对比鲜明的交换途径,从而导致明显不同的磁基态。通过对其结构和磁性的研究,我们发现[Cu(pyz)](H $_{2}$ O)(gly)$_{2}$ ](ClO $_{4}$)$_{2}$可以被认为是准一维量子海森堡反铁磁体,而相关化合物[Cu(pyz)(gly)]由反铁磁相互作用的Cu $^{2+}$自旋的二聚体形成的(ClO $_{4}$)在零场中保持无序低至至少0.03 K,但显示了场-温度相图,使人想起在显示磁振子的玻色-爱因斯坦凝聚的材料中看到的。

英文摘要:

We investigate the structural and magnetic properties of two molecule-based magnets synthesized from the same starting components. Their different structural motifs promote contrasting exchange pathways and consequently lead to markedly different magnetic ground states. Through examination of their structural and magnetic properties we show that [Cu(pyz)(H$_{2}$O)(gly)$_{2}$](ClO$_{4}$)$_{2}$ may be considered a quasi-one-dimensional quantum Heisenberg antiferromagnet while the related compound [Cu(pyz)(gly)](ClO$_{4}$), which is formed from dimers of antiferromagnetically interacting Cu$^{2+}$ spins, remains disordered down to at least 0.03 K in zero field, but shows a field-temperature phase diagram reminiscent of that seen in materials showing a Bose-Einstein condensation of magnons.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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