Surface electronic structure of a topological Kondo insulator candidate SmB6: insights from high-resolution ARPES
M. Neupane, N. Alidoust, S. -Y. Xu, T. Kondo, D. -J. Kim, Chang Liu, I. Belopolski, T. -R. Chang, H. -T. Jeng, T. Durakiewicz, L. Balicas, H. Lin, A. Bansil, S.… 展开作者
M. Neupane, N. Alidoust, S. -Y. Xu, T. Kondo, D. -J. Kim, Chang Liu, I. Belopolski, T. -R. Chang, H. -T. Jeng, T. Durakiewicz, L. Balicas, H. Lin, A. Bansil, S. Shin, Z. Fisk, M. Z. Hasan
The Kondo insulator SmB6 has long been known to exhibit low temperature (T < 10K) transport anomaly and has recently attracted attention as a new topological insulator candidate. By combining low-temperature and high energy-momentum resolution of the laser-based ARPES technique, for the first time, we probe the surface electronic structure of the anomalous conductivity regime. We observe that the bulk bands exhibit a Kondo gap of 14 meV and identify in-gap low-lying states within a 4 meV window of the Fermi level on the (001)-surface of this material. The low-lying states are found to form electron-like Fermi surface pockets that enclose the X and the Gamma points of the surface Brillouin zone. These states disappear as temperature is raised above 15K in correspondence with the complete disappearance of the 2D conductivity channels in SmB6. While the topological nature of the in-gap metallic states cannot be ascertained without spin (spin-texture) measurements our bulk and surface measurements carried out in the transport-anomaly-temperature regime (T < 10K) are consistent with the first-principle predicted Fermi surface behavior of a topological Kondo insulator phase in this material.
We report an angle-resolved photoemission (ARPES) study of $β$-YbAlB$_4$, which is known to harbor unconventional quantum criticality (QC) without any tuning. We directly observe a quasiparticle peak (QP), emerging from hybridization, characterized by a binding energy and an onset of coherence both at about 4 meV. This value conforms with a previously observed reduced Kondo scale at about 40 K. Consistency with an earlier study of carriers in $β$-YbAlB$_4$ via the Hall effect strongly suggests that this QP is responsible for the QC in $β$-YbAlB$_4$. A comparison with the sister polymorph $α$-Y…
Temperature dependence of the electronic structure of SmB6 is studied by high-resolution ARPES down to 1 K. We demonstrate that there is no essential difference for the dispersions of the surface states below and above the resistivity saturating anomaly (~ 3.5 K). Quantitative analyses of the surface states indicate that the quasi-particle scattering rate increases linearly as a function of temperature and binding energy, which differs from Fermi-Liquid behavior. Most intriguingly, we observe that the hybridization between the d and f states builds gradually over a wide temperature region (30 …
A fascinating type of symmetry-protected topological states of matter are topological Kondo insulators, where insulating behavior arises from Kondo screening of localized moments via conduction electrons, and non-trivial topology emerges from the structure of the hybridization between the local-moment and conduction bands. Here we study the physics of Kondo holes, i.e., missing local moments, in three-dimensional topological Kondo insulators, using a self-consistent real-space mean-field theory. Such Kondo holes quite generically induce in-gap states which, for Kondo holes at or near the surfa…
Kondo insulators are emerging as a simplified setting to study both magnetic and metal-to-insulator quantum phase transitions. Here, we study a half-filled Kondo lattice model defined on a magnetically frustrated Shastry-Sutherland geometry. We determine a "global" phase diagram that features a variety of zero-temperature phases; these include Kondo-destroyed antiferromagnetic and paramagnetic metallic phases in addition to the Kondo-insulator phase. Our result provides the theoretical basis for understanding how applying pressure to a Kondo insulator can close its hybridization gap, liberate …
Motivated by the observation of light surface states in SmB6, we examine the effects of surface Kondo breakdown in topological Kondo insulators. We present both numerical and analytic results which show that the decoupling of the localized moments at the surface disturbs the compensation between light and heavy electrons and dopes the Dirac cone. Dispersion of these uncompensated surface states are dominated by inter-site hopping, which leads to a much lighter quasiparticles. These surface states are also highly durable against the effects of surface magnetism and decreasing thickness of the s…
We propose the notion of spin-selective Kondo insulator, which provides a fundamental mechanism to describe the ferromagnetic phase of the Kondo lattice model with antiferromagnetic coupling. This unveils a remarkable feature of the ferromagnetic metallic phase: the majority-spin conduction electrons show metallic- while the minority-spin electrons show insulating-behavior. The resulting Kondo gap in the minority spin sector, which is due to the cooperation of ferromagnetism and partial Kondo screening, evidences a dynamically-induced commensurability for a combination of minority-spin electro…
The discovery of topological insulators in non-interacting electron systems has motivated the community to search such topological states of matter in correlated electrons both theoretically and experimentally. In this paper we investigate a phase diagram for a topological Kondo insulating system, where an emergent "spin"-dependent Kondo effect gives rise to an inversion for heavy-fermion bands, responsible for a topological Kondo insulator. Resorting to the U(1) slave-boson mean-field analysis, we uncover an additional phase transition inside the Kondo insulating state in two dimensions, whic…
Quantum oscillations have long been regarded as the manifestation of the Fermi surface in metals. However, they were recently observed in Kondo insulators. We examine the Kondo screening due to Landau levels in Kondo insulators. It is shown that even for large Kondo insulating gaps, appreciable amplitudes of quantum oscillations that are consistent with experimental observations are present both in magnetization and resistivity. Specifically, we show that due to the periodic alignment between the Landau levels in the conduction and the f-orbit electrons, the Kondo screening itself undergoes os…
The recent discovery of topological Kondo insulators has triggered renewed interest in the well-known Kondo insulator samarium hexaboride, which is hypothesized to belong to this family. In this Letter, we study the spin texture of the topologically protected surface states in such a topological Kondo insulator. In particular, we derive close relationships between (i) the form of the hybridization matrix at certain high-symmetry points, (ii) the mirror Chern numbers of the system, and (iii) the observable spin texture of the topological surface states. In this way, a robust classification of t…
Kondo insulators are strongly correlated system in which a clean insulating gap emerges only at very low temperature due to many-body effects involving localized $f$-electrons. However, certain Kondo insulators, like SmB$_6$ and Ce${_3}$Bi${_4}$Pt${_3}$, display metallic behaviors at extremely low temperatures, that have defied current understanding. Recent advances in topological effects in materials has raised the attention on the protected surface states in these "topological Kondo insulators" as a potential resolution to some of the puzzling behaviors. Here we resolve these puzzles via a d…
The continuous quantum phase transition and the nature of quantum critical point (QCP) in a modified Kondo lattice model with Ising anisotropic exchange interactions is studied within the density-matrix renormalization group algorithm. We investigate the effect of quantum fluctuations on critical Kondo destruction QCP, by probing static and dynamic properties of the magnetic order and the Kondo effect. In particular, we identify that local Kondo physics itself becomes critical at the magnetic phase transition point, providing unbiased evidences for local quantum criticality between two insulat…
The periodic Anderson lattice model for the crystalline electric field (CEF)split 4f quartet states is used to describe the Yb-based Kondo insulators/semiconductors. In the slave-boson mean-field approximation, we derive the hybridized quasiparticle bands, and find that decreasing the hybridization difference of the two CEF quartets may induce an insulator-to-metal phase transition. The resulting metallic phase has a hole and an electron Fermi pockets. Such a phase transition may be realized experimentally by applying pressure, reducing the difference in hybridization of the two CEF quartets.
Possible topological nature of Kondo and mixed valence insulators has been a recent topic of interest in condensed matter physics. Attention has focused on SmB6, which has long been known to exhibit low temperature transport anomaly, whose origin is of independent interest. We argue that it is possible to resolve the topological nature of surface states by uniquely accessing the surface electronic structure of the low temperature anomalous transport regime through combining state-of-the-art laser- and synchrotron-based angle-resolved photoemission spectroscopy (ARPES) with or without spin reso…
Using angle-resolved photoemission spectroscopy (ARPES) and resonant ARPES, we report evidence of strong anisotropic conduction-f electron mixing (c-f mixing) in CeBi by observing a largely expanded Ce-5d pocket at low temperature, with no change in the Bi-6p bands. The Fermi surface (FS) expansion is accompanied by a pronounced spectral weight transfer from the local 4f 0 peak of Ce (corresponding to Ce3+) to the itinerant conduction bands near the Fermi level. Careful analysis suggests that the observed large FS change (with a volume expansion of the electron pocket up to 40%) can most natur…
The physics of a junction composed of a normal metal, quantum dot and 2D topological insulator (in a quantum spin Hall state) is elucidated. It maifests a subtle combination of Kondo correlations and quantum spin Hall edge states moving on the opposite sides of the 2D topological insulator. In a narrow strip geometry these edge states interact and a gap opens in the edge state spectrum. Consequently, Kondo screening is less effective and that affects electron transport through the junction. Specifically, when edge state coupling is strong enough, the tunneling differential conductance develops…
We argue that topological Kondo insulators can also have 'intrinsic' topological order associated with fractionalized excitations on their surfaces. The hydridization between the local moments and conduction electrons can weaken near the surface, and this enables the local moments to form spin liquids. This co-exists with the conduction electron surface states, realizing a surface fractionalized Fermi liquid. We present mean-field solutions of a Kondo-Heisenberg model which display such surfaces.
Strongly correlated electron systems show many exotic properties such as unconventional superconductity, quantum criticality, and Kondo insulating behavior. In addition, the Kondo insulator SmB6 has been predicted theoretically to be a 3D topological insulator with a metallic surface state. We report here transport measurements on doped SmB6, which show that ~3% magnetic and non-magnetic dopants in SmB6 exhibit clearly contrasting behavior, evidence that the metallic surface state is only destroyed when time reversal symmetry is broken. We find as well a quantum percolation limit of impurity c…
Motivated by the recent experimental observations of quantum oscillations in the Kondo insulators SmB$_6$ and YbB$_{12}$, we study magneto-optical conductivity of Kondo insulators. We show that there exist non-trivial cyclotron resonance peaks in a frequency domain below the hybridization gap as a result of the characteristic Landau level structure of the system. Furthermore, these low energy peaks are enhanced near the insulator-metal phase transition driven by an applied magnetic field and stable even at low temperatures. They are smoothly connected via Kondo effect to resonance peaks for un…
To gain further insight into the properties of interacting topological insulators, we study a 1 dimensional model of topological Kondo insulators which can be regarded as the strongly interacting limit of the Tamm-Shockley model. Treating the model in a large $N$ expansion, we find a number of competing ground-state solutions, including topological insulating and valence bond ground-states. One of the effects to emerge in our treatment is a reconstruction of the Kondo screening process near the boundary of the material ("Kondo band bending"). Near the boundary for localization into a valence b…
Impurities and defects in Kondo insulators can have an unusual impact on dynamics that blends with effects of intrinsic electron correlations. Such crystal imperfections are difficult to avoid, and their consequences are incompletely understood. Here we study magnetic impurities in Kondo insulators via perturbation theory of the s-d Kondo impurity model adapted to small bandgap insulators. The calculated magnetization and specific heat agree with recent thermodynamic measurements in samarium hexaboride (SmB$_6$). This qualitative agreement supports the physical picture of multi-channel Kondo s…
Kondo insulators are primary candidates in the search for strongly correlated topological quantum phases, which may host topological order, fractionalization, and non-Abelian statistics. Within some Kondo insulators, the hybridization gap is predicted to protect a nontrivial topological invariant and to harbor emergent heavy Dirac fermion surface modes. We use high-energy-resolution spectroscopic imaging in real and momentum space on the Kondo insulator, SmB$_6$. On cooling through $T^*_Δ\approx$ 35 K we observe the opening of an insulating gap that expands to $Δ\approx$ 10 meV at 2 K. Within …
The Kondo lattice model of spin-1/2 local moments coupled to the conduction electrons at half-filling is studied for its orbital response to magnetic field on bipartite lattices. Through an effective charge dynamics, in a canonical representation of electrons that appropriately describes the Kondo insulating ground state, the magnetization is found to show de Haas-van Alphen oscillations from intermediate to weak Kondo coupling. These oscillations are ascribed to Lifshitz-like inversion of a dispersion of the gapped quasiparticles, whose chemical potential surface is measured by the oscillatio…
Kondo insulators and in particular their non-cubic representatives have remained poorly understood. Here we report on the development of an anisotropic energy pseudogap in the tetragonal compound CeRu$_4$Sn$_6$ employing optical reflectivity measurements in broad frequency and temperature ranges, and local density approximation plus dynamical mean field theory calculations. The calculations provide evidence for a Kondo insulator-like response within the $a-a$ plane and a more metallic response along the c axis and qualitatively reproduce the experimental observations, helping to identify their…
We investigate the Kondo effect in the two-dimensional electron system with a non-trivial quadratic energy band crossing point. We show that the Kondo effect can induce a new hybrid topological insulator phase which is a coexistence state of the quantum anomalous Hall effect and the TRSbroken quantum spin Hall effect. This hybrid topological insulator exhibits not only a quantized charge Hall current but also a net spin current, which are localized at the edge boundaries. This peculiar topological state arises due to the interplay of two marginally relevant operators, i.e., the Kondo-coupling …
We consider the simplest variant of a Kondo insulator where a doublet of localized $f$-electrons hybridizes with spin-degenerate conduction electrons. We analyse the symmetries of $f$-orbitals involved in the hybridization and point out that the effective four-band model of such systems is adiabatically connected with one that possesses chiral symmetry, which provides further descriptions of clean Kondo insulators. We obtain general conditions for the appearance of topological non-trivial states and discuss implications for rare-earth based compounds. As an example, we derive the full phase di…
We discuss the quasiparticle band structure of the antiferromagnetic phase of the planar Kondo lattice model with a half-filled conduction band, the so-called Kondo insulator. The band structure is obtained by bond fermion technique and good agreement is obtained with the single particle spectral function obtained by Dynamical Cluster Approximation. In particular, various changes of the band structure with J/t observed in the numerical spectra are reproduced qualitatively by the calculation. In the absence of Fermi surface nesting we find a semimetallic phase for sufficiently small exchange co…
We study Kondo physics of a spin-$\frac{1}{2}$ impurity in electronic matter with strong spin-orbit interaction, which can be realized by depositing magnetic adatoms on the surface of a three-dimensional topological insulator. We show that magnetic properties of topological surface states and the very existence of Kondo screening strongly depend on details of the bulk material, and specifics of surface preparation encoded in time-reversal preserving boundary conditions for electronic wavefunctions. When this tunable Kondo effect occurs, the impurity spin is screened by purely orbital motion of…
Abnormal electronic properties of complex systems require new ideas concerning explanation of their behavior and possibility of realization. In this acticle we show that a colossal magnetoresistance is realized in the state of the topological Kondo insulator, that is similar to the Kondo insulator state in the Kondo lattice. The mechanism of the phenomenon is the following: in the spin gapless phase an external magnetic field induces the gap in the spectrum of spin excitations, the gap in the spectrum of fermions is opened due to a hybridization between spin and fermion subsystems at half fill…
Kondo insulators combine strong electronic correlations with spin orbit coupling and thereby provide a potential realization of correlated topological insulators. We present model calculations which allow us to study the onset of bulk coherence and concomitant topological edge states from the mixed valence to local moment regimes. Our real-space dynamical mean-field results include the detailed temperature dependence of the single particle spectral function on slab geometries as well as the temperature dependence of the topological invariant. The relevance of our calculations for candidate mat…
Topological Kondo insulators (TKIs) are new type of symmetry-protected topological insulators, which develop through the interplay of strong correlations and spin-orbit interactions. In these materials, the bulk is a perfect band insulator due to Kondo screening of localized moments via conduction electrons. Furthermore, strong spin-orbit coupling (SOC) and crystal field effect (CFE) of the localized moments result in a nonlocal odd-parity, time-reversal invariant hybridization between the local-moments and conduction bands, which creates a ground-state with nontrivial topology and gapless sur…
A synergistic effect between strong electron correlation and spin-orbit interaction (SOI) has been theoretically predicted to result in a new topological state of quantum matter on Kondo insulators (KIs), so-called topological Kondo insulators (TKIs). One TKI candidate has been experimentally observed on the KI SmB6(001), and the origin of the surface states (SS) and the topological order of SmB6 has been actively discussed. Here, we show a metallic SS on the clean surface of another TKI candidate YbB12(001), using angle-resolved photoelectron spectroscopy. The SS showed temperature-dependent …
We investigate the competition between the spin-orbit interaction of itinerant electrons and their Kondo coupling with local moments densely distributed on the honeycomb lattice. We find that the model at half-filling displays a quantum phase transition between topological and Kondo insulators at a nonzero Kondo coupling. In the Kondo-screened case, tuning the electron concentration can lead to a new topological insulator phase. The results suggest that the heavy-fermion phase diagram contains a new regime with a competition among topological, Kondo-coherent and magnetic states, and that the r…
The temperature-dependent evolution of the Kondo lattice is a long-standing topic of theoretical and experimental investigation and yet it lacks a truly microscopic description of the relation of the basic $f$-$d$ hybridization processes to the fundamental temperature scales of Kondo screening and Fermi-liquid lattice coherence. Here, the temperature-dependence of $f$-$d$ hybridized band dispersions and Fermi-energy $f$ spectral weight in the Kondo lattice system CeCoIn$_5$ is investigated using $f$-resonant angle-resolved photoemission (ARPES) with sufficient detail to allow direct comparison…
Temperature-induced gap formation in dynamic correlation functions of the one-dimensional Kondo insulator --- Finite-temperature density-matrix renormalization-group study ---
We study a layered three-dimensional heterostructure in which two types of Kondo insulators are stacked alternatingly. One of them is the topological Kondo insulator SmB 6 , the other one an isostructural Kondo insulator AB 6 , where A is a rare-earth element, e.g., Eu, Yb, or Ce. We find that if the latter orders ferromagnetically, the heterostructure generically becomes a magnetic Weyl Kondo semimetal, while antiferromagnetic order can yield a magnetic Dirac Kondo semimetal. We detail both scenarios with general symmetry considerations as well as concrete tight-binding calcu-lations and show…
This article reviews recent theoretical and experimental work on a new class of topological material - topological Kondo insulators, which develop through the interplay of strong correlations and spin-orbit interactions. The history of Kondo insulators is reviewed along with the theoretical models used to describe these heavy fermion compounds. The Fu-Kane method of topological classification of insulators is used to show that hybridization between the conduction electrons and localized f-electrons in these systems gives rise to interaction-induced topological insulating behavior. Finally, som…
Temperature dependent band structure of the Kondo insulator
我们提出了一个Qantum Monte Carlo（QMC）研究的近藤绝缘体的温度相关的动力学。在所谓的对称点工作允许执行无负号QMC模拟，从而达到小于传导电子带宽的1%的温度。单粒子格林函数和动态自旋关联函数的温度依赖性的研究显示了一个令人惊讶的复杂的低温能带结构，并给出了两个特征温度的证据，我们确定与近藤和相干温度，分别。特别地，数据显示在相干温度下温度诱导的金属-绝缘体转变。
The half-filled Kondo lattice model is studied at low temperatures on simple cubic lattice using the self-consistent theory developed in Phys. Rev. B 96, 075115 (2017). It is found to have three distinct insulating phases in the temperature-hopping plane, namely, the strong coupling Kondo singlet (KS) phase, the inverted Kondo singlet (iKS) phase distinguished from the KS by inversion, and the antiferromagnetic (AFM) phase. The quasiparticle density of states across the inversion transition is noted to exhibit dimensional reduction, which can differentiate between the KS and iKS insulators in …
Topological Kondo insulators are a rare example of an interaction-enabled topological phase of matter in three-dimensional crystals - making them an intriguing but also hard case for theoretical studies. Here, we aim to advance their theoretical understanding by solving the paradigmatic two-band model for topological Kondo-insulators using a fully spin-rotation invariant slave-boson treatment. Within a mean-field approximation, we map out the magnetic phase diagram and characterize both antiferromagnetic and paramagnetic phases by their topological properties. Among others, we identify an anti…
A Mean-Field Study of Quantum Oscillations in Two-Dimensional Kondo Insulators
Max Planck Institute for the Structure and Dynamics of Matter（马克斯·普朗克物质与结构动力学研究所）；Department of Physics, University of Cincinnati（辛辛那提大学物理系）；Department of Physics and Engineering Physics, Tulane University（杜兰大学物理与工程物理系）
The observation of quantum oscillations in topological Kondo insulators SmB6 and YbB12 is a recent puzzling experimental discovery. Quantum oscillations observed in the resistivity and the magnetization are usually explained by the existence of the Fermi surface. However, Kondo insulators do not have a Fermi surface and thus should not show quantum oscillations. By performing dynamical mean-field calculations for topologically nontrivial Kondo insulators in a magnetic field, we analyze the effect of correlations on the emergence of quantum oscillations in narrow-gap topological Kondo insulator…
Topological Kondo insulators have been attracting great attention from the condensed-matter physics community due to their fascinating topological and strongly correlated properties. Here, we report angle-dependent c-axis magnetoresistance (MR) oscillations in a Kondo insulator, SmB6 single crystal, in a magnetic field of up to 13 T rotated in the ab-plane. Four-fold symmetric MR oscillations are first observed above 8 K, which result from the four-fold (C4) degeneracy of the bulk Fermi surface of SmB6. With decreasing temperature down to 2.3 K, the C4 symmetry of the MR oscillations gradually…
The electronic structures of two mixed valence insulators YbB$_6$ and YbB$_12$ are studied by using the local density approximation (LDA) supplemented with the Gutzwiller method and dynamic mean field theory (DMFT). YbB$_6$ is found to be a moderately correlated Z$_2$ topological insulator, similar to SmB$_6$ but having much larger bulk band gap. Notably, YbB$_12$ is revealed to be in a new novel quantum state, strongly correlated topological crystalline Kondo insulator, which is characterized by its non-zero mirror Chern number. The surface calculations find odd (three) and even (four) number…
Kondo insulating materials lie outside the usual dichotomy of weakly versus correlated - band versus Mott - insulators. They are metallic at high temperatures but resemble band insulators at low temperatures because of the opening of an interaction induced band gap. The first discovered Kondo insulator (KI) SmB$_6$ has been predicted to form a topological KI (TKI) which mimics a topological insulator at low temperatures. However, since its discovery thermodynamic and transport anomalies have been observed that have defied a theoretical explanation. Enigmatic signatures of collective modes insi…
