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arXiv 1302.1815cond-mat.str-elcond-mat.mtrl-sci
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$Sr_3 Fe_2 O_{7-x}$的磁性phase diagram

Magnetic phase diagram of $Sr_3 Fe_2 O_{7-x}$

D. C. Peets, J. -H. Kim, P. Dosanjh, M. Reehuis, A. Maljuk, N. Aliouane, C. Ulrich, B. Keimer

摘要:

对含Fe ^{4 +}的钙钛矿相Sr_3Fe_2O_7-x的单晶进行了磁测量、电输运和中子散射测量。虽然这种化合物的晶体结构和电子构型与已被充分研究的铼酸盐和锰酸盐非常相似,但它表现出非常不同的物理性质。全氧化合物(x = 0)在T_D = 340 K时发生电荷反铁磁转变,在T_N = 115 K时发生反铁磁转变。对于温度T \leq T_D,材料是小能隙绝缘体;反铁磁序是无公度的,这意味着Fe ^{4 +}磁矩之间的竞争交换相互作用。完全脱氧的化合物(x = 1)是高度绝缘的,其Fe ^{3 +}磁矩在T_N~600 K以下表现出相当的反铁磁序。具有中间x的化合物在较低的T_N下表现出不同的有序性,这可能是Fe ^{3 +}和Fe ^{4 +}亚晶格之间交换相互作用受阻的结果。以前的提议,磁转变温度达到零是不支持的。

英文摘要:

Magnetometry, electrical transport, and neutron scattering measurements were performed on single crystals of the Fe^{4+}-containing perovskite-related phase Sr_3Fe_2O_7-x as a function of oxygen content. Although both the crystal structure and electron configuration of this compound are closely similar to those of well-studied ruthenates and manganates, it exhibits very different physical properties. The fully-oxygenated compound (x=0) exhibits a charge-disproportionation transition at T_D = 340 K, and an antiferromagnetic transition at T_N = 115 K. For temperatures T \leq T_D, the material is a small-gap insulator; the antiferromagnetic order is incommensurate, which implies competing exchange interactions between the Fe^{4+} moments. The fully-deoxygenated compound (x=1) is highly insulating, and its Fe^{3+} moments exhibit commensurate antiferromagnetic order below T_N ~ 600 K. Compounds with intermediate x exhibit different order with lower T_N, likely as a consequence of frustrated exchange interactions between Fe^{3+} and Fe^{4+} sublattices. A previous proposal that the magnetic transition temperature reaches zero is not supported.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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