Dual-comb spectroscopy is extended to the visible spectral range with a set-up based on two frequency-doubled femtosecond ytterbium-doped fiber lasers. The dense rovibronic spectrum of iodine around 19240 cm-1 is recorded within 12 ms at Doppler-limited resolution with a simple scheme that only uses free-running femtosecond lasers.
Absorption spectroscopy is widely used to detect samples with spectral specificity. Here, we propose and demonstrate a method for enhancing the sensitivity of absorption spectroscopy. Exploiting multiple light scattering generated by a boron nitride (h-BN) scattering cavity, the optical path lengths of light inside a diffusive reflective cavity are significantly increased, resulting in more than ten times enhancement of sensitivity in absorption spectroscopy. We demonstrate highly sensitive spectral measurements of low concentrations of malachite green and crystal violet aqueous solutions. Bec…
Open-path dual-comb spectroscopy provides multi-species atmospheric gas concentration measurements with high precision. Here, we extend open-path dual comb spectroscopy to the mid-infrared 5 μm atmospheric window, enabling atmospheric concentration retrievals of the primary greenhouse gases, N$_2$O, CO$_2$, and H$_2$O as well as the criterion air pollutants O$_3$ and CO across 600 m and 2 km round-trip paths. We demonstrate measurements over a five-day period at two-minute temporal resolution with 80% uptime. The achieved precision is sufficient to resolve the atmospheric concentration variati…
A compact green astro-comb with 43-GHz repetition rate is developed based on a Ti:Sapphire optical frequency comb (OFC) and a mode-selecting cavity. The OFC's large repetition rate of 1.6 GHz eases the requirements for the mode-selecting cavity. Unnecessary frequency-modes of the OFC are suppressed down to $5 \times 10^{-4}$ at 535 nm - 550 nm using a single mode-selecting cavity with 70-MHz linewidth. The radial velocity precision $σ\sim 1.4$ m/s is achieved at the High Dispersion Echelle Spectrosraph for the Okayama 188-cm telescope of the National Astronomical Observatory of Japan using our…
We demonstrate broadband and sensitive cavity ring-down spectroscopy using a near infrared frequency comb and a time-resolved Fourier transform spectrometer. The cavity decays are measured simultaneously and spectrally sorted, leading to purely exponential decays for each spectral element. The absorption spectra of atmospheric water and carbon dioxide are retrieved and demonstrate the high frequency resolution and absorption precision of the technique. The experimental apparatus, the measurement concept and the data treatment are described. The technique benefits from the advantages of cavity …
Upconversion Dual-comb Passive Spectroscopy of Mid-IR Incoherent Light
Department of Electrical, Computer, and Energy Engineering, University of Colorado Boulder（科罗拉多大学博尔德分校电气、计算机和能源工程系）；Department of Physics, University of Colorado Boulder（科罗拉多大学博尔德分校物理系）
Quantum cascade laser (QCL) frequency combs have revolutionized mid-infrared (MIR) spectroscopy by their high brightness and fast temporal resolution, and are a promising technology for fully-integrated and cost-effective sensors. As for other integrated comb sources such as micro-combs and interband cascade laser, QCLs have a comb spacing of several GHz, which is adequate for measurements of wide absorbing structures, typically found in liquid or solid samples. However, high-resolution gas-phase spectra require spectral interleaving and frequency calibration. We developed a frequency calibrat…
