静电场中通过电子束分散富勒烯沉积的薄聚合C60涂层
Thin polymerized C60 coatings deposited in electrostatic field via electron-beam dispersion of fullerite
摘要：
本研究的目的是澄清富勒烯C60电子束分散（EBD）产品的电荷组成，并通过施加额外的静电场的基板上的沉积涂层的结构上的富勒烯离子和电子的影响进行调查。发现C60 EBD产物中含有正富勒烯离子和正电子。通过使用拉曼和衰减全反射傅里叶变换红外光谱，X-射线光电子能谱学，激光解吸/电离质谱和原子力显微镜，它表明，辅助的电子额外加速到300 eV的结果在形成的哑铃和花生形的C60聚合物的混合物。另外加速至300 eV的正富勒烯离子的协助导致形成共价键合的富勒烯分子的高度交联的随机3D网络。
英文摘要：
The aim of the present study is to clarify the charge composition of fullerite C60 electron-beam dispersion (EBD) products and investigate the influence of fullerene ions and electrons on the structure of the deposited coatings by applying an additional electrostatic field to the substrates. It was found that C60 EBD products contain positive fullerene ions and electrons. By using Raman and attenuated total reflection Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, laser desorption/ionization mass-spectrometry and atomic force microscopy, it was shown that the assistance of the electrons additionally accelerated up to 300 eV results in the formation of a mixture of dumb-bell- and peanut-shaped C60 polymers. The assistance of the positive fullerene ions additionally accelerated up to 300 eV leads to the formation of highly cross-linked random 3D networks of covalently bonded fullerene molecules.
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