We demonstrate that Casimir-Polder energies between noble gas atoms (dissolved in water) and oil-water interfaces are highly surface specific. Both repulsion (e.g. hexane) and attraction (e.g. glycerine and cyclodecane) is found with different oils. For several intermediate oils (e.g. hexadecane, decane, and cyclohexane) both attraction and repulsion can be found in the same system. Near these oil-water interfaces the interaction is repulsive in the non-retarded limit and turns attractive at larger distances as retardation becomes important. These highly surface specific interactions may have a role to play in biological systems where the surface may be more or less accessible to dissolved atoms.
We propose a method to separate enantiomers using parity violation in the Casimir-Polder potential between chiral mirrors and chiral molecules. The proposed setup involves a molecular beam composed of chiral molecules passing through a planar cavity consisting of two chiral mirrors. Enantiomers of opposite handedness are deflected differently due to a chiral dependence of the Casimir-Polder potential resulting in the separation of the enantiomers. Our setup provides an alternative experimental tool for enantiomer separation, as well as shedding light on the fundamental properties of the Casimi…
We study the nonequilibrium Casimir-Polder force on an atom prepared in an incoherent superposition of internal energy-eigenstates, which is placed in a magnetoelectric environment of nonuniform temperature. After solving the coupled atom--field dynamics within the framework of macroscopic quantum electrodynamics, we derive a general expression for the thermal Casimir-Polder force.
We propose a new method to measure Casimir-Polder force in an optical cavity by means of atomic excitations. We utilize a framework in which Unruh-DeWitt Hamiltonian mimics the full matter-field interaction and find a connection between the excitation rate of the two-level atom and the Casimir-Polder energy, allowing to map one onto the other. We argue that such a realization opens a route to study Casimir-Polder potentials through measurement of excited state's population in large, spatially compact ensembles of atoms.
We study the effect of two non-interacting impurity atoms near by a one-dimensional nanowire, which is modeled as a tight-binding hopping model. The virtual single-electron hopping between two impurities will induce an additional energy depending on the distance of two impurities, which gives a electronic Casimir-Polder effect. We find that the Casimir-Polder force between the two impurities decreases with the impurity-impurity distance exponentially. And the effects of nanowire and finite temperature on the Casimir-Polder force are also discussed in detail, respectively.
We show that the Casimir-Polder interaction may induce coherent oscillations between degenerate atomic states. We illustrate this effect by computing the Casimir-Polder induced Rabi frequency on a $^{87}$Rb atom as it interacts with a reflecting surface. The atom oscillates between two Zeeman sublevels of its ground state undergoing a periodic exchange of angular momentum with the vacuum photons.
This Resource Letter provides a guide to the literature on van der Waals and Casimir-Polder forces. Journal articles, books, and other documents are cited on the following topics: van der Waals forces, retarded dispersion forces or Casimir-Polder forces between atoms or molecules, Casimir-Polder forces between a molecule and a dielectric or conducting body, the summation of Casimir-Polder forces as leading to the Casimir and Lifshitz forces between conducting and dielectric bodies, Casimir friction, applications to nanotechnology, the nature of the quantum vacuum, and experimental tests of the…
We review different aspects of the atom-atom and atom-wall Casimir-Polder forces. We first discuss the role of a boundary condition on the interatomic Casimir-Polder potential between two ground-state atoms, and give a physically transparent interpretation of the results in terms of vacuum fluctuations and image atomic dipoles. We then discuss the known atom-wall Casimir-Polder force for ground- and excited-state atoms, using a different method which is also suited for extension to time-dependent situations. Finally, we consider the fluctuation of the Casimir-Polder force between a ground-stat…
We develop a dynamical approach to study the Casimir-Polder force between a initially bare molecule and a magnetodielectric body at finite temperature. Switching on the interaction between the molecule and the field at a particular time, we study the resulting temporal evolution of the Casimir-Polder interaction. The dynamical self-dressing of the molecule and its population-induced dynamics are accounted for and discussed. In particular, we find that the Casimir-Polder force between a chiral molecule and a perfect mirror oscillates in time with a frequency related to the molecular transition …
We propose a method to probe dispersive atom-surface interactions by measuring via two-photon Bragg spectroscopy the dynamic structure factor of a Bose-Einstein condensate above corrugated surfaces. This method takes advantage of the condensate coherence to reveal the spatial Fourier components of the lateral Casimir-Polder interaction energy.
An ultracold atom above a horizontal mirror experiences quantum reflection from the attractive Casimir-Polder interaction, which holds it against gravity and leads to quantum levitation states. We analyze this system by using a Liouville transformation of the Schrödinger equation and a Langer coordinate adapted to problems with a classical turning point. Reflection on the Casimir-Polder attractive well is replaced by reflection on a repulsive wall and the problem is then viewed as an ultracold atom trapped inside a cavity with gravity and Casimir-Polder potentials acting respectively as top an…
We use a derivative expansion for gently curved surfaces to compute the leading and the next-to-leading curvature corrections to the Casimir-Polder interaction between a polarizable small particle and a non-planar surface. While our methods apply to any homogeneous and isotropic surface, explicit results are presented here for perfect conductors. We show that the derivative expansion of the Casimir-Polder potential follows from a resummation of its perturbative series, for small in-plane momenta. We consider the retarded, non-retarded and classical high temperature limits.
We find the low-temperature behavior of the Casimir-Polder free energy for a polarizable and magnetizable atom interacting with a plate made of ferromagnetic dielectric material. It is shown that the corresponding Casimir-Polder entropy goes to zero with vanishing temperature, i.e., the Nernst heat theorem is satisfied, if the dc conductivity of the plate material is disregarded in calculations. If the dc conductivity is taken into account, the Nernst theorem is violated. These results are discussed in light of recent experiments.
We investigate the magnetic dipole coupling between a metallic surface and an atom in a thermal state, ground state and excited hyperine state. This interaction results in a repulsive correction and - unlike the electrical dipole contribution - depends sensitively on the Ohmic dissipation in the material.
We investigate how the combination of nonequilibrium effects and material properties impacts on the Casimir-Polder interaction between an atom and a surface. By addressing systems with temperature inhomogeneities and laser interactions, we show that nonmonotonous energetic landscapes can be produced where barriers and minima appear. Our treatment provides a self-consistent quantum theoretical framework for investigating the properties of a class of nonequilibrium atom-surface interactions.
We investigate theoretically the Casimir-Polder potential of an atom which is driven by a laser field close to a surface. This problem is addressed in the framework of macroscopic quantum electrodynamics using the Green's tensor formalism and we distinguish between two different approaches, a perturbative ansatz and a method based on Bloch equations. We apply our results to a concrete example, namely an atom close to a perfectly conducting mirror, and create a scenario where the tunable Casimir-Polder potential becomes similar to the respective potential of an undriven atom due to fluctuating …
Atom-surface forces using excited states have a host of compelling applications, including repulsive and lateral forces. However, such states can be fragile and difficult to prepare. Here we report an explicit normal-mode based calculation of the Casimir-Polder potential between a ground-state atom and a non-dispersive surface in the presence of an external quantised field. The potential we derive shares some features with that of excited-state Casimir-Polder forces even though we consider a ground-state atom. Our work provides a physically transparent and intuitive picture of driven Casimir-P…
The Casimir-Polder force between two atoms with equal uniform acceleration and separated by a constant distance R is considered. We show that, in the low-acceleration limit, while the near-zone R^{-6} behavior of the interatomic interaction energy is not changed by the acceleration of the atoms, the far-zone interaction energy decreases as R^{-5} instead of the well-known R^{-7} behavior for inertial atoms. Possibility of an indirect detection of the Unruh effect through measurements of the Casimir-Polder force between the two accelerating atoms is also suggested. We also consider a heuristic …
Various applications of the multiple scattering technique to calculating Casimir energy are described. These include the interaction between dilute bodies of various sizes and shapes, temperature dependence, interactions with multilayered and corrugated bodies, and new examples of exactly solvable separable bodies.
For the first time, we have studied the impact of magnetic polarizability of a neutral metallic particle on the dynamical Casimir-Polder force, when the particle is uniformly moving with relativistic velocity parallel to the surface of an ideally conducting plate. The material properties of particle are taken into account within the Drude model approach.
We study the Casimir-Polder interaction at finite temperatures between a polarizable small, anisotropic particle and a non-planar surface using a derivative expansion. We obtain the leading and the next-to-leading curvature corrections to the interaction for low and high temperatures. Explicit results are provided for the retarded limit in the presence of a perfectly conducting surface.
Based on the idea that the vacuum fluctuations of electromagnetic fields can induce instantaneous correlated dipoles, we study the far-zone Casimir-Polder potential between two atoms in the Boulware, Unruh and Hartle-Hawking vacua outside a Schwarzschild black hole. We show that, at spatial infinity, the Casimir-Polder potential in the Boulware vacuum is similar to that in the Minkowski vacuum in flat spacetime with a behavior of $R^{-7}$, so is in the Unruh vacuum as a result of the backscattering of the Hawking radiation from the black hole off the spacetime curvature. However, the interatom…
We consider the out-of-thermal-equilibrium Casimir-Polder interaction between atoms of He$^*$, Na, Cs, and Rb and a cavity wall made of sapphire coated with a vanadium dioxide film which undergoes the dielectric-to-metal phase transition with increasing wall temperature. Numerical computations of the Casimir-Polder force and its gradient as the functions of atom-wall separation and wall temperature are made when the latter exceeds the temperature of the environment. The obtained results are compared with those in experiment on measuring the gradient of the Casimir-Polder force between $^{87}$R…
Reply to Comment [arXiv:0810.3244v1] by R.S. Decca et al. on "Contribution of drifting carriers to the Casimir-Lifshitz and Casimir-Polder interactions with semiconductor materials"
我们表明，R.S. Decca等人反对我们的报纸D.A.R. Dalvit和S.K. Lamoreaux，Phys. Rev. Lett. { \bf 101}，163203（2008），是错误的，明显不符合统计物理学的基本原理。
We study the influence of thermal Casimir-Polder forces on the near-surface trapping of cold polar molecules, with emphasis on LiH and YbF near an Au surface at room temperature. We show that for a molecule initially prepared in its electronic and rovibrational ground state, the Casimir-Polder force oscillates with the molecule-wall separation. The non-resonant force contribution and the evanescent part of the resonant force contribution almost exactly cancel at high temperature which results in a saturation of the (attractive) force in this limit. A dynamical calculation reveals how the spati…
The Casimir and Casimir-Polder interactions are investigated in a stack of equally spaced graphene layers. The optical response of the individual graphene is taken into account using gauge invariant components of the polarization tensor extended to the whole complex frequency plane. The planar symmetry for the electromagnetic boundary conditions is further used to obtain explicit forms for the Casimir energy stored in the stack and the Casimir-Polder energy between an atom above the stack. Our calculations show that these fluctuation induced interactions experience strong thermal effects due t…
In this paper we review different aspects of the dynamical Casimir- Polder potential between a neutral atom and a perfectly conducting plate under nonequilibrium conditions. In order to calculate the time evolution of the atom-wall Casimir-Polder potential, we solve the Heisenberg equations describing the dynamics of the coupled system using an iterative technique. Different nonequilibrium initial states are considered, such as bare and partially dressed states. The partially dressed states considered are obtained by a sudden change of a physical parameter of the atom or of its position relati…
The chiral component of the Casimir-Polder potential is derived within the framework of macroscopic quantum electrodynamics. It is shown to exist only if the particle and the medium are both chiral. Furthermore, the chiral component of the Casimir-Polder potential can be attractive or repulsive, depending on the chirality of the molecule and the medium. The theory is applied to a cavity geometry in the non-retarded limit with the intention of enantiomer separation. For a ground state molecule the chiral component is dominated by the electric component and thus no explicit separation will happe…
An atom irradiated by an off-resonant laser field near a surface is expected to experience the sum of two fundamental potentials, the optical potential of the laser field and the Casimir--Polder potential of the surface. Here, we report a new non-additive potential, namely the laser-induced Casimir--Polder potential, which arises from a correlated coupling of the atom with both the laser and the quantum vacuum. We apply this result to an experimentally realizable scenario of an atomic mirror with an evanescent laser beam leaking out of a surface. We show that the non-additive term is significa…
A novel formalism for the evaluation of the Casimir-Polder potential in an arbitrary gauge of vector potentials is introduced. The ground state energy of a neutral atom in the presence of an infinite two-dimensional plane with Chern-Simons interaction is derived at zero temperature. The essential feature of the result is its dependence on the antisymmetric part of a dipole moment correlation function.
We discuss the scalar analogue of the Casimir-Polder force between a sphere and a uniaxially corrugated surface with Dirichlet boundary conditions. Presenting a formulation that is nonperturbative in the height profile of the surface, we give explicit numerical results for a sinuosoidal corrugation profile.
We study the effective range expansion of scattering on a real Casimir-Polder potential. We use Liouville transformations which transform the potential landscape while preserving the reflection and transmission amplitudes. We decompose the scattering calculation in two more elementary problems, one for the homogeneous 1/z^4 potential and the other one for the correction to this idealization. We use the symmetries of the transformed problem and the properties of the scattering matrices to derive an improved effective range expansion leading to a more accurate expansion of scattering amplitudes …
We explore the statistical properties of the Casimir-Polder potential between a dielectric sphere and a three-dimensional heterogeneous medium, by means of extensive numerical simulations based on the scattering theory of Casimir forces. The simulations allow us to confirm recent predictions for the mean and standard deviation of the Casimir potential, and give us access to its full distribution function in the limit of a dilute distribution of heterogeneities. These predictions are compared with a simple statistical model based on a pairwise summation of the individual contributions of the co…
It has been increasingly becoming clear that Casimir and Casimir-Polder entropies may be negative in certain regions of temperature and separation. In fact, the occurrence of negative entropy seems to be a nearly ubiquitous phenomenon. This is most highlighted in the quantum vacuum interaction of a nanoparticle with a conducting plate or between two nanoparticles. It has been argued that this phenomenon does not violate physical intuition, since the total entropy, including the self-entropies of the plate and the nanoparticle, should be positive. New calculations, in fact, seem to bear this ou…
Casimir-Polder interactions are considered in an inhomogeneous, dispersive background. We consider both the interaction between a polarizable atom and a perfectly conducting wall, and between such an atom and a plane interface between two different inhomogeneous dielectric media. Renormalization is achieved by subtracting the interaction with the local inhomogeneous medium by itself. The results are expressed in general form, and generalize the Dzyaloshinskii-Lifshitz-Pitaevskii interaction between a spatially homogeneous dielectric interface and a polarizable atom.
We study the spontaneous emission of an excited atom close to an optical nanofiber and the resulting scattering forces. For a suitably chosen orientation of the atomic dipole, the spontaneous emission pattern becomes asymmetric and a resonant Casimir--Polder force parallel to the fiber axis arises. For a simple model case, we show that the such a lateral force is due to the interaction of the circularly oscillating atomic dipole moment with its image inside the material. With the Casimir--Polder energy being constant in the lateral direction, the predicted lateral force does not derive from a …
We investigate the time-dependent Casimir-Polder potential of a polarizable two-level atom placed near a surface of arbitrary material, after a sudden change in the parameters of the system. Different initial conditions are taken into account. For an initially bare ground-state atom, the time-dependent Casimir-Polder energy reveals how the atom is "being dressed" by virtual, matter-assisted photons. We also study the transient behavior of the Casimir-Polder interaction between the atom and the surface starting from a partially dressed state, after an externally induced change in the atomic lev…
We consider Casimir-Polder and Casimir forces with finite dissipation by coupling heat baths to the dipoles introducing, this way, dissipation from 'first principles'. We derive a representation of the free energy as an integral over real frequencies, which can be viewd as an generalization of the 'remarkable formula' introduced by Ford et. al. 1985. For instance, we obtain a nonperturbative representation for the atom-atom and atom-wall interactions. We investigate several limiting cases. From the limit $T\to0$ we show that the third law of thermodynamics cannot be violated within the given a…
