We critically discuss the common belief that the thermal Casimir-Polder force can always be represented as a Matsubara sum, as it is true for the Casimir force. On the contrary, an exact treatment of the atom-field coupling reveals that for a ground-state atom, terms associated with virtual-photon absorption contribute to the force which are identified as a signature of non-equilibrium dynamics. Even the equilibrium force on a thermalized atom or molecule may be overestimated when using the ground-state polarizability instead of its thermal counterpart.
We study the nonequilibrium Casimir-Polder force on an atom prepared in an incoherent superposition of internal energy-eigenstates, which is placed in a magnetoelectric environment of nonuniform temperature. After solving the coupled atom--field dynamics within the framework of macroscopic quantum electrodynamics, we derive a general expression for the thermal Casimir-Polder force.
We propose a new method to measure Casimir-Polder force in an optical cavity by means of atomic excitations. We utilize a framework in which Unruh-DeWitt Hamiltonian mimics the full matter-field interaction and find a connection between the excitation rate of the two-level atom and the Casimir-Polder energy, allowing to map one onto the other. We argue that such a realization opens a route to study Casimir-Polder potentials through measurement of excited state's population in large, spatially compact ensembles of atoms.
We study the effect of two non-interacting impurity atoms near by a one-dimensional nanowire, which is modeled as a tight-binding hopping model. The virtual single-electron hopping between two impurities will induce an additional energy depending on the distance of two impurities, which gives a electronic Casimir-Polder effect. We find that the Casimir-Polder force between the two impurities decreases with the impurity-impurity distance exponentially. And the effects of nanowire and finite temperature on the Casimir-Polder force are also discussed in detail, respectively.
We consider the three-body Casimir-Polder interaction between three atoms during their dynamical self-dressing. We show that the time-dependent three-body Casimir-Polder interaction energy displays nonlocal features related to quantum properties of the electromagnetic field and to the nonlocality of spatial field correlations. We discuss the measurability of this intriguing phenomenon and its relation with the usual concept of stationary three-body forces.
We consider vacuum fluctuations of the quantum electromagnetic field in the presence of an infinite and perfectly conducting plate. We evaluate how the change of vacuum fluctuations due to the plate modifies the Casimir-Polder potential between two atoms placed near the plate. We use two different methods to evaluate the Casimir-Polder potential in the presence of the plate. They also give new insights on the role of boundary conditions in the Casimir-Polder interatomic potential, as well as indications for possible generalizations to more complicated boundary conditions.
We show that the Casimir-Polder interaction may induce coherent oscillations between degenerate atomic states. We illustrate this effect by computing the Casimir-Polder induced Rabi frequency on a $^{87}$Rb atom as it interacts with a reflecting surface. The atom oscillates between two Zeeman sublevels of its ground state undergoing a periodic exchange of angular momentum with the vacuum photons.
The three-body Casimir-Polder potential between one excited and two ground-state atoms is evaluated. A physical model based on the dressed field correlations of vacuum fluctuations is used, generalizing a model previously introduced for three ground-state atoms. Although the three-body potential with one excited atom is already known in the literature, our model gives new insights on the nature of non-additive Casimir-Polder forces with one or more excited atoms.
Making use of the quantum correlators associated with the Maxwell field vacuum distorted by the presence of plane parallel material surfaces we derive the Casimir-Polder interaction in the presence of plane parallel conducting walls and in the presence of a conducting wall and a magnetically permeable one.
A time-dependent Casimir-Polder force is shown to arise during the time evolution of a partially dressed two-level atom. The partially dressed atom is obtained by a rapid change of an atomic parameter such as its transition frequency, due to the action of some external agent. The electromagnetic field fluctuations around the atom, averaged over the solid angle for simplicity, are calculated as a function of time, and it is shown that the interaction energy with a second atom yields a dynamical Casimir-Polder potential between the two atoms.
We develop a dynamical approach to study the Casimir-Polder force between a initially bare molecule and a magnetodielectric body at finite temperature. Switching on the interaction between the molecule and the field at a particular time, we study the resulting temporal evolution of the Casimir-Polder interaction. The dynamical self-dressing of the molecule and its population-induced dynamics are accounted for and discussed. In particular, we find that the Casimir-Polder force between a chiral molecule and a perfect mirror oscillates in time with a frequency related to the molecular transition …
We consider the Casimir-Polder interaction between two atoms, one in the ground state and the other in its excited state. The interaction is time-dependent for this system, because of the dynamical self-dressing and the spontaneous decay of the excited atom. We calculate the dynamical Casimir-Polder potential between the two atoms using an effective Hamiltonian approach. The results obtained and their physical meaning are discussed and compared with previous results based on a time-independent approach which uses a non-normalizable dressed state for the excited atom.
We propose a method to probe dispersive atom-surface interactions by measuring via two-photon Bragg spectroscopy the dynamic structure factor of a Bose-Einstein condensate above corrugated surfaces. This method takes advantage of the condensate coherence to reveal the spatial Fourier components of the lateral Casimir-Polder interaction energy.
An ultracold atom above a horizontal mirror experiences quantum reflection from the attractive Casimir-Polder interaction, which holds it against gravity and leads to quantum levitation states. We analyze this system by using a Liouville transformation of the Schrödinger equation and a Langer coordinate adapted to problems with a classical turning point. Reflection on the Casimir-Polder attractive well is replaced by reflection on a repulsive wall and the problem is then viewed as an ultracold atom trapped inside a cavity with gravity and Casimir-Polder potentials acting respectively as top an…
We use a derivative expansion for gently curved surfaces to compute the leading and the next-to-leading curvature corrections to the Casimir-Polder interaction between a polarizable small particle and a non-planar surface. While our methods apply to any homogeneous and isotropic surface, explicit results are presented here for perfect conductors. We show that the derivative expansion of the Casimir-Polder potential follows from a resummation of its perturbative series, for small in-plane momenta. We consider the retarded, non-retarded and classical high temperature limits.
Using a recently developed theory of the Casimir force (Raabe C and Welsch D-G 2005 Phys. Rev. A 71 013814), we calculate the force that acts on a plate in front of a planar wall and the force that acts on the plate in the case where the plate is part of matter that fills the space in front of the wall. We show that in the limit of a dielectric plate whose permittivity is close to unity, the force obtained in the former case reduces to the ordinary, i.e., unscreened Casimir-Polder force acting on isolated atoms. In the latter case, the theory yields the Casimir-Polder force that is screened by…
Within leading-order perturbation theory, the Casimir-Polder potential of a ground-state atom placed within an arbitrary arrangement of dispersing and absorbing linear bodies can be expressed in terms of the polarizability of the atom and the scattering Green tensor of the body-assisted electromagnetic field. Based on a Born series of the Green tensor, a systematic expansion of the Casimir-Polder potential in powers of the susceptibilities of the bodies is presented. The Born expansion is used to show how and under which conditions the Casimir-Polder force can be related to microscopic many-at…
We develop a new theory for Casimir-Lifshitz and Casimir-Polder interactions with semiconductor surfaces that takes into account charge drift in the bulk material. The corresponding frequency-dependent dispersion relations describe a crossover between Lifshitz results for dielectrics and for good conductors. In the quasi-static limit, our calculated reflection amplitudes coincide with those recently computed to account for Debye screening in the thermal Lifshitz force with conducting surfaces with small density of carriers.
We find the low-temperature behavior of the Casimir-Polder free energy for a polarizable and magnetizable atom interacting with a plate made of ferromagnetic dielectric material. It is shown that the corresponding Casimir-Polder entropy goes to zero with vanishing temperature, i.e., the Nernst heat theorem is satisfied, if the dc conductivity of the plate material is disregarded in calculations. If the dc conductivity is taken into account, the Nernst theorem is violated. These results are discussed in light of recent experiments.
We investigate the magnetic dipole coupling between a metallic surface and an atom in a thermal state, ground state and excited hyperine state. This interaction results in a repulsive correction and - unlike the electrical dipole contribution - depends sensitively on the Ohmic dissipation in the material.
We investigate how the combination of nonequilibrium effects and material properties impacts on the Casimir-Polder interaction between an atom and a surface. By addressing systems with temperature inhomogeneities and laser interactions, we show that nonmonotonous energetic landscapes can be produced where barriers and minima appear. Our treatment provides a self-consistent quantum theoretical framework for investigating the properties of a class of nonequilibrium atom-surface interactions.
We investigate theoretically the Casimir-Polder potential of an atom which is driven by a laser field close to a surface. This problem is addressed in the framework of macroscopic quantum electrodynamics using the Green's tensor formalism and we distinguish between two different approaches, a perturbative ansatz and a method based on Bloch equations. We apply our results to a concrete example, namely an atom close to a perfectly conducting mirror, and create a scenario where the tunable Casimir-Polder potential becomes similar to the respective potential of an undriven atom due to fluctuating …
We study the resonant Casimir--Polder potential of an excited atom near a half space containing magneto-electric meta-material of various kinds on the basis of macroscopic quantum electrodynamics. Analytical results are obtained in the nonretarded and retarded distance regimes and numerical examples are given. We compare our findings with the potential of an excited atom near a left-handed superlens.
The problem of nonlocality in the dynamical three-body Casimir-Polder interaction between an initially excited and two ground-state atoms is considered. It is shown that the nonlocal spatial correlations of the field emitted by the excited atom during the initial part of its spontaneous decay may become manifest in the three-body interaction. The observability of this new phenomenon is discussed.
Atom-surface forces using excited states have a host of compelling applications, including repulsive and lateral forces. However, such states can be fragile and difficult to prepare. Here we report an explicit normal-mode based calculation of the Casimir-Polder potential between a ground-state atom and a non-dispersive surface in the presence of an external quantised field. The potential we derive shares some features with that of excited-state Casimir-Polder forces even though we consider a ground-state atom. Our work provides a physically transparent and intuitive picture of driven Casimir-P…
We consider the quantum fluctuations of the Casimir-Polder force between a neutral atom and a perfectly conducting wall in the ground state of the system. In order to obtain the atom-wall force fluctuation we first define an operator directly associated to the force experienced by the atom considered as a polarizable body in an electromagnetic field, and we use a time-averaged force operator in order to avoid ultraviolet divergences appearing in the fluctuation of the force. This time-averaged force operator takes into account that any measurement involves a finite time. We also calculate the …
In this paper we calculate the Casimir-Polder force density (force per unit area acting on the elements of the surface) on a metallic plate placed in front of a neutral atom. To obtain the force density we use the quantum operator associated to the electromagnetic stress tensor. We explicitly show that the integral of this force density over the plate reproduces the total force acting on the plate. This result shows that, although the force is obtained as a sum of surface element-atom contributions, the stress-tensor method includes also nonadditive components of Casimir-Polder forces in the e…
We study the Casimir-Polder interaction at finite temperatures between a polarizable small, anisotropic particle and a non-planar surface using a derivative expansion. We obtain the leading and the next-to-leading curvature corrections to the interaction for low and high temperatures. Explicit results are provided for the retarded limit in the presence of a perfectly conducting surface.
We consider the out-of-thermal-equilibrium Casimir-Polder interaction between atoms of He$^*$, Na, Cs, and Rb and a cavity wall made of sapphire coated with a vanadium dioxide film which undergoes the dielectric-to-metal phase transition with increasing wall temperature. Numerical computations of the Casimir-Polder force and its gradient as the functions of atom-wall separation and wall temperature are made when the latter exceeds the temperature of the environment. The obtained results are compared with those in experiment on measuring the gradient of the Casimir-Polder force between $^{87}$R…
We show that the claims expressed in the Comment arXiv:0810.3244v1 by R.S. Decca et al against our paper, D.A.R. Dalvit and S.K. Lamoreaux, Phys. Rev. Lett. {\bf 101}, 163203 (2008), are wrong and manifestly inconsistent with basic principles of statistical physics.
We have considered the interaction of a pair of spatially separated two-level atoms with the electromagnetic field in its vacuum state and we have analyzed the amount of entanglement induced between the two atoms by the non local field fluctuations. This has allowed us to characterize the quantum nature of the non local correlations of the electromagnetic field vacuum state as well as to link the induced quantum entanglement with Casimir-Polder potentials.
We study the influence of thermal Casimir-Polder forces on the near-surface trapping of cold polar molecules, with emphasis on LiH and YbF near an Au surface at room temperature. We show that for a molecule initially prepared in its electronic and rovibrational ground state, the Casimir-Polder force oscillates with the molecule-wall separation. The non-resonant force contribution and the evanescent part of the resonant force contribution almost exactly cancel at high temperature which results in a saturation of the (attractive) force in this limit. A dynamical calculation reveals how the spati…
We evaluate the Casimir-Polder potential between two atoms in the presence of an infinite perfectly conducting plate and at nonzero temperature. In order to calculate the potential, we use a method based on equal-time spatial correlations of the electric field, already used to evaluate the effect of boundary conditions on interatomic potentials. This method gives also a transparent physical picture of the role of a finite temperature and boundary conditions on the Casimir-Polder potential. We obtain an analytical expression of the potential both in the near and far zones, and consider several …
In this paper we review different aspects of the dynamical Casimir- Polder potential between a neutral atom and a perfectly conducting plate under nonequilibrium conditions. In order to calculate the time evolution of the atom-wall Casimir-Polder potential, we solve the Heisenberg equations describing the dynamics of the coupled system using an iterative technique. Different nonequilibrium initial states are considered, such as bare and partially dressed states. The partially dressed states considered are obtained by a sudden change of a physical parameter of the atom or of its position relati…
The time-dependent Casimir-Polder force arising during the time evolution of an initially bare two-level atom, interacting with the radiation field and placed near a perfectly conducting wall, is considered. Initially the electromagnetic field is supposed to be in the vacuum state and the atom in its ground state. The analytical expression of the force as a function of time and atom-wall distance, is evaluated from the the time-dependent atom-field interaction energy. Physical features and limits of validity of the results are discussed in detail.
Recently D. A. R. Dalvit and S. K. Lamoreaux arXiv:0805.1676 [Phys. Rev. Lett. v.101, 163203 (2008)] suggested the modification of the reflection coefficients in the Lifshitz theory taking into account the screening effects and diffusion currents. We demonstrate that the suggested modification is thermodynamically and experimentally inconsistent.
An atom irradiated by an off-resonant laser field near a surface is expected to experience the sum of two fundamental potentials, the optical potential of the laser field and the Casimir--Polder potential of the surface. Here, we report a new non-additive potential, namely the laser-induced Casimir--Polder potential, which arises from a correlated coupling of the atom with both the laser and the quantum vacuum. We apply this result to an experimentally realizable scenario of an atomic mirror with an evanescent laser beam leaking out of a surface. We show that the non-additive term is significa…
We study the effective range expansion of scattering on a real Casimir-Polder potential. We use Liouville transformations which transform the potential landscape while preserving the reflection and transmission amplitudes. We decompose the scattering calculation in two more elementary problems, one for the homogeneous 1/z^4 potential and the other one for the correction to this idealization. We use the symmetries of the transformed problem and the properties of the scattering matrices to derive an improved effective range expansion leading to a more accurate expansion of scattering amplitudes …
We study the spontaneous emission of an excited atom close to an optical nanofiber and the resulting scattering forces. For a suitably chosen orientation of the atomic dipole, the spontaneous emission pattern becomes asymmetric and a resonant Casimir--Polder force parallel to the fiber axis arises. For a simple model case, we show that the such a lateral force is due to the interaction of the circularly oscillating atomic dipole moment with its image inside the material. With the Casimir--Polder energy being constant in the lateral direction, the predicted lateral force does not derive from a …
We investigate the time-dependent Casimir-Polder potential of a polarizable two-level atom placed near a surface of arbitrary material, after a sudden change in the parameters of the system. Different initial conditions are taken into account. For an initially bare ground-state atom, the time-dependent Casimir-Polder energy reveals how the atom is "being dressed" by virtual, matter-assisted photons. We also study the transient behavior of the Casimir-Polder interaction between the atom and the surface starting from a partially dressed state, after an externally induced change in the atomic lev…
We consider Casimir-Polder and Casimir forces with finite dissipation by coupling heat baths to the dipoles introducing, this way, dissipation from 'first principles'. We derive a representation of the free energy as an integral over real frequencies, which can be viewd as an generalization of the 'remarkable formula' introduced by Ford et. al. 1985. For instance, we obtain a nonperturbative representation for the atom-atom and atom-wall interactions. We investigate several limiting cases. From the limit $T\to0$ we show that the third law of thermodynamics cannot be violated within the given a…
We consider two three-dimensional isotropic harmonic oscillators interacting with the quantum electromagnetic field in the Coulomb gauge and within dipole approximation. Using a Bogoliubov-like transformation, we can obtain transformed operators such that the Hamiltonian of the system, when expressed in terms of these operators, assumes a diagonal form. We are also able to obtain an expression for the energy shift of the ground state, which is valid at all orders in the coupling constant. From this energy shift the nonperturbative Casimir-Polder potential energy between the two oscillators can…
We calculate the Casimir-Polder intermolecular potential using an effective Hamiltonian recently introduced. We show that the potential can be expressed in terms of the dynamical polarizabilities of the two atoms and the equal-time spatial correlation of the electric field in the vacuum state. This gives support to an interesting physical model recently proposed in the literature, where the potential is obtained from the classical interaction between the instantaneous atomic dipoles induced and correlated by the vacuum fluctuations. Also, the results obtained suggest a more general validity of…
A general theory of the Casimir-Polder interaction of single atoms with dispersing and absorbing magnetodielectric bodies is presented, which is based on QED in linear, causal media. Both ground-state and excited atoms are considered. Whereas the Casimir-Polder force acting on a ground-state atom can conveniently be derived from a perturbative calculation of the atom-field coupling energy, an atom in an excited state is subject to transient force components that can only be fully understood by a dynamical treatment based on the body-assisted vacuum Lorentz force. The results show that the Casi…
We study the time evolution of the Casimir-Polder force acting on a neutral atom in front of a perfectly conducting plate, when the system starts its unitary evolution from a partially dressed state. We solve the Heisenberg equations for both atomic and field quantum operators, exploiting a series expansion with respect to the electric charge and an iterative technique. After discussing the behaviour of the time-dependent force on an initially partially-dressed atom, we analyze a possible experimental scheme to prepare the partially dressed state and the observability of this new dynamical eff…
We demonstrate under which conditions a violation of the charge-parity (CP) symmetry in molecules will manifest itself in the Casimir-Polder interaction of these with a magnetodielectric surface. Charge-parity violation induces a specific electric-magnetic cross-polarisability in a molecule that is not chiral, but time-reversal (T) symmetry violating. As we show, a detection of such an effect via the Casimir-Polder potential requires a material medium that is also sensitive to time-reversal, i.e., it must exhibit a non-reciprocal electromagnetic response. As simple examples of such media we co…
We establish a general relation between dispersion forces. First, based on QED in causal media, leading-order perturbation theory is used to express both the single-atom Casimir-Polder and the two-atom van der Waals potentials in terms of the atomic polarizabilities and the Green tensor for the body-assisted electromagnetic field. Endowed with this geometry-independent framework, we then employ the Born expansion of the Green tensor together with the Clausius-Mosotti relation to prove that the macroscopic Casimir-Polder potential of an atom in the presence of dielectric bodies is due to an inf…
The transient Casimir-Polder force on a two-level atom introduced into a three-dimensional, inhomogeneous, generally non-reciprocal environment is evaluated using non-Markovian Weisskopf-Wigner theory in the strong and weak coupling regimes. Ground-state and excited atoms are considered as two separate initial-value problems, and both the short-time and long-time atomic population and force are evaluated. The results are compared with various Markov approximation of the Weisskopf-Wigner theory, and with previous Markov results from the Heisenberg picture.
We derive the fully retarded energy shift of a neutral atom in two different geometries useful for modelling etched microstructures. First we calculate the energy shift due to a reflecting cylindrical wire, and then we work out the energy shift due to a semi-infinite reflecting half-plane. We analyze the results for the wire in various limits of the wire radius and the distance of the atom from the wire, and obtain simple asymptotic expressions useful for estimates. For the half-plane we find an exact representation of the Casimir-Polder interaction in terms of a single, fast converging integr…
We show that the Casimir-Polder potential of a particle in an energy eigenstate at nonretarded distance from a well-conducting body of arbitrary shape is independent of the environment temperature. This is true even when the thermal photon numbers at the relevant atomic transition energies are large. A compact expression is obtained for the temperature-independent potential, which can greatly simplify calculations in nontrivial geometries for experimentally relevant systems such as Rydberg atoms and polar molecules. We give criteria for the validity of our temperature-independent result. They …
The Casimir-Polder and van der Waals interaction energy of an atom with infinitely thin sphere with finite conductivity is investigated in the framework of the hydrodynamic approach. We put the sphere into spherical cavity inside the infinite dielectric media, then calculate the energy of vacuum fluctuations in the context of the zeta-function approach. The energy for a single atom is obtained by rarefying media. The Casimir-Polder expression for an atom and plate is recovered in the limit of the infinite radius of the sphere. Assuming a finite radius of the sphere, the interaction energy of a…
The low-temperature behavior of the Casimir-Polder free energy and entropy for an atom near a dielectric plate are found on the basis of the Lifshitz theory. The obtained results are shown to be thermodynamically consistent if the dc conductivity of the plate material is disregarded. With inclusion of dc conductivity, both the standard Lifshitz theory (for all dielectrics) and its generalization taking into account screening effects (for a wide range of dielectrics) violate the Nernst heat theorem. The inclusion of the screening effects is also shown to be inconsistent with experimental data o…
In this paper we consider a quantum harmonic oscillator interacting with the electromagnetic radiation field in the presence of a boundary condition preserving the continuous spectrum of the field, such as an infinite perfectly conducting plate. Using an appropriate Bogoliubov-type transformation we can diagonalize exactly the Hamiltonian of our system in the continuum limit and obtain non-perturbative expressions for its ground-state energy. From the expressions found, the atom-wall Casimir-Polder interaction energy can be obtained, and well-know lowest-order results are recovered as a limiti…
We review recent results on the low-temperature behaviors of the Casimir-Polder and Casimir free energy an entropy for a polarizable atom interacting with a graphene sheet and for two graphene sheets, respectively. These results are discussed in the wide context of problems arising in the Lifshitz theory of van der Waals and Casimir forces when it is applied to metallic and dielectric bodies. After a brief treatment of different approaches to theoretical description of the electromagnetic response of graphene, we concentrate on the derivation of response function in the framework of thermal qu…
We calculate the Casimir-Polder frequency shift and decay rate for an atom in front of a nonreciprocal medium by using macroscopic quantum electrodynamics. The results are a generalization of the respective quantities for matter with broken time-reversal symmetry which does not fulfill the Lorentz reciprocity principle. As examples, we contrast the decay rates, the resonant and nonresonant frequency shifts of a perfectly conducting (reciprocal) mirror to those of a perfectly reflecting nonreciprocal mirror. We find different power laws for the distance dependence of all quantities in the retar…
On the basis of macroscopic quantum electrodynamics and point-scattering techniques, we derive a closed expression for the Casimir-Polder force between a ground-state atom and a small magnetodielectric sphere in an arbitrary environment. In order to allow for the presence of both bodies and media, local-field corrections are taken into account. Our results are compared with the known van der Waals force between two ground-state atoms. To continuously interpolate between the two extreme cases of a single atom and a macroscopic sphere, we also derive the force between an atom and a sphere of var…
