It is demonstrated that the transition temperature (Tc) of high-Tc superconductors is determined by their layered crystal structure, bond lengths, valency properties of the ions, and Coulomb coupling between electronic bands in adjacent, spatially separated layers. Analysis of 31 high-Tc materials (cuprates, ruthenates, rutheno-cuprates, iron pnictides, organics) yields the universal relationship for optimal compounds, kBTc0 = β/\ellζ, where \ell is related to the mean spacing between interacting charges in the layers, ζ is the distance between interacting electronic layers, β is a universal constant and Tc0 is the optimal transition temperature (determined to within an uncertainty of +/- 1.4 K by this relationship). Non-optimum compounds, in which sample degradation is evident, e.g. by broadened superconducting transitions and diminished Meissner fractions, typically exhibit reduced Tc < Tc0. It is shown that Tc0 may be obtained from an average of Coulomb interaction forces between the two layers.
A long-standing problem of observing Room Temperature Superconductivity is finally solved by a novel approach. Instead of increasing the critical temperature Tc of a superconductor, the temperature of the room was decreased to an appropriate Tc value. We consider this approach more promising for obtaining a large number of materials possessing Room Temperature Superconductivity in the near future.
The discovery of charge-density-wave order in the high-temperature superconductor YBa$_2$Cu$_3$O$_{6+y}$ places charge order centre stage with superconductivity, suggesting they they are intertwined rather than competing.
The long-sought goal of room-temperature superconductivity has reportedly recently been realized in a carbonaceous sulfur hydride compound under high pressure, as reported by Snider et al. [1]. The evidence presented in that paper is stronger than in other similar recent reports of high temperature superconductivity in hydrides under high pressure [2-7], and has been received with universal acclaim [8-10]. Here we point out that features of the experimental data shown in Ref. [1] indicate that the phenomenon observed in that material is not superconductivity. This observation calls into questi…
We show that the topologically protected flat band emerging on a surface of a nodal fermionic system promotes the surface superconductivity due to an infinitely large density of states associated with the flat band. The critical temperature depends linearly on the pairing interaction and can be thus considerably higher than the exponentially small bulk critical temperature. We discuss an example of surface superconductivity in multilayered graphene with rhombohedral stacking.
We study the origin of broadening of superconducting transition in sputtered Nb films. From simultaneous tunneling and transport measurements we conclude that the upper critical field Hc2 always corresponds to the bottom of transition R~0, while the top R~Rn occurs close to the critical field for destruction of surface superconductivity Hc3 ~ 1.7 Hc2. The two-dimensional nature of superconductivity at H>Hc2 is confirmed by cusp-like angular dependence of magnetoresistance. Our data indicates that surface superconductivity is remarkably robust even in disordered polycrystalline films and, surpr…
The structural evolution and superconductivity of a 122-type solid solution Sr1-xBaxNi2P2 were studied. We found that an orthorhombic-tetragonal structural phase transition takes place at x = 0.5, and is characterized by the P-P dimers breaking. The superconducting transition temperature exhibited its highest value of 2.85 K at x = 0.4.
The new superconductivity theory that attributes the $U(1)$ superconductivity phase to a Berry phase arising from many-body wave functions is applied to the circuit quantization for superconducting qubits. The phase-charge duality required for the occurrence of superconductivity in the standard theory becomes irrelevant in the new theory, and the absence of a dissipative quantum phase transition in Josephson junctions is explained. It is shown that a charge-decaying term leads to the compact phase description, and the appearance of Shapiro steps is explained without introducing normal current.
Defects in the atomic lattice of solids are sometimes desired. For example, atomic vacancies, single ones or more elaborated defective structures, can generate localized magnetic moments in a non magnetic crystalline lattice. Increasing their density to a few percent magnetic order can appear. Furthermore, certain two dimensional interfaces can give rise to localized superconductivity with a broad range of critical temperatures. Old and new experimental facts emphasize the need to join efforts to start using systematically "ordered defects" in solids to achieve room temperature superconductivi…
Cuprate high temperature superconductors consist of two quasi-two-dimensional (2D) substructures: CuO2 superconducting layers and charge reservoir layers. The superconductivity is realized by charge transfer from the charge reservoir layers into the superconducting layers without chemical dopants and defects being introduced into the latter, similar to modulation-doping in semiconductor superlattices of AlGaAs/GaAs. Inspired by this scheme, we have been searching for high temperature superconductivity in ultrathin films of superconductors epitaxially grown on semiconductor/oxide substrates sin…
One approach to discovering topological superconductor is establishing superconductivity based on well-identified topological insulators. However, the coexistence of superconductivity and topological state is always arcane. In this paper, we report how pressure tunes the crystal structure, electronic structure, and superconductivity in topological insulator Bi2Te2.1Se0.9. The first pressure-induced structure transition start from 8.4 GPa, followed by the structure sequence of R-3m - C2/m - C2/c - Im-3m up to 37 GPa. Superconductivity starts to present at 2.4 GPa with the Tc around 6.6 K. Moreo…
We report the observation of an exceptionally large room-temperature electrical conductivity in silver and aluminum layers deposited on a lead zirconate titanate (PZT) substrate. The surface resistance of the silver-coated samples also shows a sharp change near 313 K. The results are strongly suggestive of a superconductive interfacial layer, and have been interpreted in the framework of Bose-Einstein condensation of bipolarons as the suggested mechanism for high-temperature superconductivity in cuprates.
We analyze a possible superconductivity in the hole-doped system of layered hydrogenized graphene by taking into account thermal fluctuations of the order parameter. In particular, we demonstrate that in the one-layer case the values of the high mean-field (MF) critical temperature $T_{c}^{MF}\sim 80-90K$, predicted recently by Savini et al \cite{Savini}, do not alter significantly due to the fluctuations, and the Berezinskii-Kosterlitz-Thouless (BKT) critical temperature of the vortex superconductivity is almost the same as the MF temperature at doping 0.01-0.1. We show that in the case of mu…
The influence of recently discovered topological transition between type I and type II Weyl semi-metals on superconductivity is considered. A set of Gorkov equations for weak superconductivity in Weyl semi-metal under topological phase transition is derived and solved. The critical temperature and superconducting gap both have spike in the point the transition point as function of the tilt parameter of the Dirac cone determined in turn by the material parameters like pressure. The spectrum of superconducting excitations is different in two phases: the sharp cone pinnacle is characteristic for …
We have studied the magnetic response of two bulk highly oriented pyrolytic graphite (HOPG) samples with different internal microstructure. For the sample with well defined interfaces, parallel to the graphene layers, the temperature and magnetic field hysteresis are similar to those found recently in water-treated graphite powders. The observed behavior indicates the existence of granular superconductivity above room temperature in agreement with previous reports in other graphite samples. The granular superconductivity behavior is observed only for fields normal to the embedded interfaces, w…
Since the discovery of superconductivity at 200 K in H3S [1] similar or higher transition temperatures, Tcs, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved by different methods, including electrical resistance, magnetic susceptibility, optical infrared, and nuclear resonant scattering measurements. The crystal structures of superconducting phases were determined by X-ray diffraction. Numerous electrical transport measurements demonstrate the typical behaviour of a conventional phonon-mediated superconductor: ze…
We report superconductivity induced in films of the non-superconducting, antiferromagnetic parent material FeTe by low temperature oxygen incorporation in a reversible manner. X-ray absorption shows that oxygen doping changes the nominal Fe valence state from 2+ in the non-superconducting state to mainly 3+ in the superconducting state. Thus superconductivity in O doped FeTe occurs in a quite different charge and strain state than the more common FeTe$_{1-x}$Se$_x$. This work also suggests a convenient path for conducting doping experiments in-situ with many measurement techniques.
Results are presented for the temperature and frequency dependence of the real and imaginary parts of the diagonal self energy for a d-wave superconductor. An Eliashberg analysis, which has been successful in recent fitting of superconductor-insulator-superconductor tunnel junction conductances for BiSrCaCuO (Bi-2212), is extended to finite temperatures. The effect of the temperature dependence of the 40 meV spin resonance mode, measured in inelastic neutron scattering (INS) in Bi-2212, on the finite temperature self energies is investigated.
Layered transition-metal tellurides have attracted considerable attention because of their rich physics; for example, tungsten ditelluride WTe2 exhibits extremely large magnetoresistance; the tritelluride ZrTe3 shows a charge density wave transition at low temperature; and the pentatelluride ZrTe5 displays an enigmatic resistivity anomaly and large thermoelectric power. Recently some transition-metal tellurides are predicted to be quantum spin Hall insulators (e.g. ZrTe5 and HfTe5) or Weyl semimetals (e.g. WTe2 and MoTe2) and were subjected to intensive investigations. Here, we report on the d…
Using a prototype model for proximity induced superconductivity on a bilayer square lattice, we show that interlayer tunneling can drive change in topology of the Bogoliubov quasiparticle bands. Starting with topologically trivial superconductors, transitions to a non-trivial $p_x + {\rm i} p_y$ state and back to another trivial state are discovered. We characterize these phases in terms of edge-state spectra and Chern indices. We show that these transitions can also be controlled by experimentally viable control parameters, the bandwidth of the metallic layer and the gate potential. Insights …
The temperature dependence of the ac susceptibility for single-crystalline Fe1.02Se has been measured at high pressures to 6.7 GPa. The superconducting transition temperature Tc displays a large increase from 7 K to 30 K in the two-phase region at 0.5 - 1 GPa. Further increase in pressure results in the decrease of Tc. The destruction of superconductivity near 7 GPa is presumably related to a structural transition from orthorhombic to hexagonal. .
Here I extend my last work about the origin of the pseudo-gaps in underdoped cuprates (arXiv: cond-mat. 1011.3206), to include the mechanism of superconductivity. This is done by adapting the formalism of the double correlations in systems with nested Fermi surfaces to the semi one dimensional system of strings of holes. It is proposed that magnetic interaction is crucial for the establishment of the pseudogap and the high temperature superconductivity. It is shown that superconductivity disturbs the completeness of the strings of holes, and creates fluctuations in their shapes. This, in turn,…
The cuprates and iron-based high-temperature superconductors share many common features: layered strongly anisotropic crystal structure, strong electronic correlations, interplay between different types of electronic ordering, the intrinsic spatial inhomogeneity due to doping. The understanding of complex interplay between these factors is crucial for a directed search of new high-temperature superconductors. Here we show the appearance of inhomogeneous gossamer superconductivity in bulk FeSe compound at ambient pressure and at temperature 5 times higher than its zero-resistance $T_c$. This di…
With a generic model for the electron-phonon spectral density, two simple expressions are derived to estimate the transition temperature and gap-to-temperature ratio in conventional superconductors. They entail that on average the numerical value of the phonon exchange factor, $λ$, is limited to 2.67, so that room temperature superconductivity may be attained only with a Debye temperature of about 1800 K or higher, in materials that may or may not involve hydrogen. They also show that a Be-Pb alloy may become a superconductor at $\sim$44 K.
The discovery of intrinsic magnetism in atomically thin two-dimensional transition-metal trichalcogenides has attracted intense research interest due to the exotic properties of magnetism and potential applications in devices. Pressure has proven to be an effective tool to manipulate the crystal and electronic structures of the materials. Here, we report investigations on ferromagnetic van der Waals Cr2Si2Te6 via high-pressure synchrotron x-ray diffraction, electrical resistance, Hall resistance, and magnetoresistance measurements. Under compression, Cr2Si2Te6 simultaneously undergoes a struct…
Tetragonal beta-FeSe obtained by hydrothermal reaction is not superconducting and transforms to a triclinic structure at 60 K unlike superconducting FeSe from solid state synthesis, which becomes orthorhombic at 90 K. In contrast, tetragonal iron sulphide FeS from hydrothermal synthesis is superconducting at 4.8 K but undergoes no structural transition. Our results suggest that the absence of superconductivity in hydrothermally synthesized FeSe may be associated to the low-temperature structure with zigzag chains of iron atoms, which is different from the known orthorhombic Cmme structure of s…
We have shown that adiabatic electronic structure of superconducting phase of sulphur hydride at 200 GPa is unstable toward vibration motion of H-atoms. Theoretical study indicates that in coupling to H-vibrations, system undergoes transition from adiabatic into stabilised anti-adiabatic multi-gap superconducting state at temperature which can reach 203 K.
The demonstration of a quasi-two-dimensional electron gas (2DEG) and superconducting properties in LaAlO$_3$/SrTiO$_3$ heterostructures has stimulated intense research activity in recent ten years. The 2DEG has unique properties that are promising for applications in all-oxide electronic devices. The superconductivity in such heterostructures has been observed below 300 mK. For superconductivity applications it is desirable to have more wide temperature of the existence range and the ability to control superconductivity properties by external stimulus. Based on first-principles calculations an…
Superconductivity and topological quantum states are two frontier fields of research in modern condensed matter physics. The realization of superconductivity in topological materials is highly desired, however, superconductivity in such materials is typically limited to two- or three-dimensional materials and is far from being thoroughly investigated. In this work, we boost the electronic properties of the quasi-one-dimensional topological insulator bismuth iodide \b{eta}-Bi4I4 by applying high pressure. Superconductivity is observed in \b{eta}-Bi4I4 for pressures where the temperature depende…
Room temperature superconductivity has been the most prominent, highly ambitious, but still imaginable, acme of materials physics for half a century. The struggle toward this revolution was foreshadowed by a Victorian novelist and championed,unsuccessfully, by dogged physicists in the 1960s to 1980s who had a workable theory but uncompliant materials. Discovery of superconductivity of H$_3$S at 200 K in the 160-200 GPa pressure range has renewed anticipation of yet higher values of the critical temperature T$_c$. With the several reports of metalization of hydrogen, and theoretical extensions …
We investigate the role of specific phonon mode symmetries for the room temperature superconductivity in atomic hydrogen under large pressure. Using anisotropic Migdal-Eliashberg theory with ab initio input from density functional theory, we show that the $E_u$ phonon modes are the dominant driving force for obtaining such high critical temperatures. When going from 400 to 600 GPa, we find an increased transition temperature, however, the total electron-phonon coupling strength is counterintuitively reduced. Our analysis reveals that this is due to an enhanced contribution to the coupling stre…
Superconductivity at temperatures up to 190 K at high pressures has recently been observed in $H_2S$ and interpreted as conventional BCS-electron-phonon-driven superconductivity.\cite{h2s} Instead we propose that it is another example of the mechanism of hole superconductivity at work. Within this mechanism high temperature superconductivity arises when holes conduct through negatively charged anions in close proximity. We propose that electron transfer from $H$ to $S$ leads to conduction by holes in a nearly full band arising from direct overlap of $S^=$ $p$ orbitals in a planar structure. Th…
We report high temperature superconductivity in one unit-cell (1-UC) FeSe films grown on STO(110) substrate by molecular beam epitaxy. By in-situ scanning tunneling spectroscopy measurement, we observed a superconducting gap as large as 17 meV. Transport measurements on 1-UC FeSe/STO(110) capped with FeTe layers reveal superconductivity with an onset TC of 31.6 K and an upper critical magnetic field of 30.2 T. We also find that the TC can be further increased by an external electric field, but the effect is smaller than that on STO(001) substrate. The study points out the important roles of in…
Signatures of room-temperature superconductivity emerging in two-dimensional domains within the new Bi/Pb-based ceramic cuprate superconductors at ambient pressure
The tremendous efforts to unveil high temperature superconductivity (HTSC) have been devoted to the search of the mechanism underlying Cooper pairs which, however, remains a mysterious subject of vigorous debate, let alone many other mysteries like the pseudogap state, the peculiar Homes law, the unnegligible electron-phonon interaction, the stripe, the universal nodal Fermi velocity, etc. Most of subsequent works either bring in more controversies or swell the list of mysteries. Here I tentatively propose a whole new perspective on the basis of low-dimensional Bose-Einstein Condensation (LDBE…
Magnetic measurements have been carried out in the superconducting and normal states of the optimally doped nonmagnetic bismuthate superconductor Ba0.63K0.37BiO3. The magnetic data along with previous muSR, resistivity, and tunneling data consistently show that there is a large polaronic enhancement in the density of states and effective electron-phonon coupling constant. The first-principle calculation within the density-functional theory indicates a small electron-phonon coupling constant of about 0.3-0.4, which can only lead to about 1 K superconductivity within the conventional phonon-medi…
High temperature superconductivity is often found in the vicinity of antiferromagnetism. This is also true in LaFeAsO$_{1-x}$F$_{x}$ ($x \leq$ 0.2) and many other iron-based superconductors, which leads to proposals that superconductivity is mediated by fluctuations associated with the nearby magnetism. Here we report the discovery of a new superconductivity dome without low-energy magnetic fluctuations in LaFeAsO$_{1-x}$F$_{x}$ with 0.25$\leq x \leq$0.75, where the maximal critical temperature $T_c$ at $x_{opt}$ = 0.5$\sim$0.55 is even higher than that at $x \leq$ 0.2. By nuclear magnetic res…
The recently discovered FeAs-based superconductors are a new, promising set of materials for both technological as well as basic research. They offer transition temperatures as high as 55 K as well as essentially isotropic and extremely large upper, superconducting critical fields in excess of 40 T at 20 K. In addition they may well provide insight into exotic superconductivity that extends beyond just FeAs-based superconductivity, perhaps even shedding light on the still perplexing CuO-based high-Tc materials. Whereas superconductivity can be induced in the RFeAsO (R = rare earth) and AEFe2As…
Large diameter single-wall boron nanotubes (SWBNT) produced by 2%Mg-mesoporous Al2O3 catalysis show diamagnetic transition at ~ 40 K and ~ 80 K, which is a serious indication for possible superconductivity (J.Phys.Chem.C113, (2009) 17661). Theoretical study which explains or disproves possibility of superconductivity in boron is so far absent, however. Here we apply first-principles formulation of nonadiabatic theory of electron-vibration interactions in study of band structure of boron nanotubes. The ab initio results show that electron-vibration coupling induces in SWBNT with diameter larger…
