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arXiv 1201.4335cond-mat.dis-nncond-mat.stat-mech
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偏析复合材料中的隧道和逾渗输运状态

Tunneling and percolation transport regimes in segregated composites

B. Nigro, C. Grimaldi, P. Ryser

摘要:

本文研究了隔离导体-绝缘体复合材料中的电子输运问题。在隔离导体-绝缘体复合材料中,导电粒子通过隧穿电导相互连接,从而形成一个整体的隧穿连接电阻网络。隔离是由大绝缘颗粒的存在下,禁止小得多的导电填料均匀地占据复合材料的三维体积诱导。通过考虑导电相的胶体状和颗粒状分散体,分别用连续体和晶格中的分散体建模,我们用蒙特卡罗模拟评估了偏析对复合电导率σ的影响,并表明应用于隧道网络的有效介质理论准确地再现了蒙特卡罗结果。该理论阐明了在连续介质中偏析的主要作用是减小平均粒子间距离,导致电导率的强烈增强。在晶格偏析的情况下,电导率的增强,而不是由第一和超越第一近邻的渗流阈值的降低。我们的研究结果推广到隔离复合材料的隧道为基础的描述之前介绍的均质无序系统的逾渗和跳跃制度。

英文摘要:

We consider the problem of electron transport in segregated conductor-insulator composites in which the conducting particles are connected to all others via tunneling conductances, thus forming a global tunnelingconnected resistor network. Segregation is induced by the presence of large insulating particles, which forbid the much smaller conducting fillers from occupying uniformly the three-dimensional volume of the composite. By considering both colloidal-like and granular-like dispersions of the conducting phase, modeled respectively by dispersions in the continuum and in the lattice, we evaluate by Monte Carlo simulations the effect of segregation on the composite conductivity σ, and show that an effective-medium theory applied to the tunneling network reproduces accurately the Monte Carlo results. The theory clarifies that the main effect of segregation in the continuum is that of reducing the mean interparticle distances, leading to a strong enhancement of the conductivity. In the lattice-segregation case the conductivity enhancement is instead given by the lowering of the percolation thresholds for first and beyond-first nearest neighbors. Our results generalize to segregated composites the tunneling-based description of both the percolation and hopping regimes introduced previously for homogeneous disordered systems.

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