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arXiv 1111.1186cond-mat.mtrl-sci
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正交自旋排列作为Ba3Cu3In4O12中三维Shastry-Sutherland网络的可能基态

Orthogonal spin arrangement as possible ground state of three - dimensional Shastry - Sutherland network in Ba3Cu3In4O12

O. S. Volkova, I. S. Maslova, R. Klingeler, M. Abdel-Hafiez, A. U. B. Wolter, B. Buechner, A. N. Vasiliev

摘要:

Ba_3Cu_3In_4O_(12)代表磁子系统的独特拓扑结构。它由90个\Box $^b$相对于彼此旋转的“纸链”柱组成,所述“纸链”柱由顶点共享的CuIO 4和CuIIO 4平面单元制成。铜离子的整体图案是三维Shastry-Sutherland网络。在高温下,磁化率遵循居里-外斯定律,外斯温度为正,表明强的铁磁耦合优势。然而,在低温下,这种化合物达到反铁磁有序状态,并经历了非平凡的连续两个自旋翻转和两个自旋翻转过渡达到完全饱和,在适度的磁场。在这里,我们表明,可能的基态在Ba_3Cu_3 In_4 O_(1/2)可以是三维正交排列的Cu ~(2+)(S = 1/2)的磁矩形成三个几乎独立的反铁磁子系统。在这种安排中,有利于各向异性交换相互作用,量子涨落提供三个相互正交的磁子系统之间的耦合,导致令人印象深刻的“无序有序”效应。

英文摘要:

The Ba3Cu3In4O12 stands for unique topology of the magnetic subsystem. It consists of rotated by 90\Box$^b$ relative to each other "paper-chain" columns made of vertex-sharing CuIO4 and CuIIO4 planar units. The overall pattern of the copper ions is that of a three-dimensional Shastry-Sutherland network. At high temperatures, the magnetic susceptibility follows the Curie-Weiss law with positive Weiss temperature indicating strong predominance of ferromagnetic coupling. At low temperatures, however, this compound reaches the antiferromagnetically ordered state and experiences non-trivial succession of two spin-flop and two spin-flip transitions reaching full saturation in modest magnetic fields. Here we show that the possible ground state in Ba3Cu3In4O12 can be three-dimensional orthogonal arrangement of the Cu2+ (S = 1/2) magnetic moments forming three virtually independent antiferromagnetic subsystems. In this arrangement, favored by anisotropic exchange interactions, the quantum fluctuations provide the coupling between three mutually orthogonal magnetic subsystems resulting in an impressive "order by disorder" effect.

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