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arXiv 1107.0962cond-mat.supr-concond-mat.mtrl-scicond-mat.str-el
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共取代对BaFe2As2超导化合物中Fe价态的影响:硬X射线吸收谱研究

Co-substitution effects on the Fe-valence in the BaFe2As2 superconducting compound: A study of hard x-ray absorption spectroscopy

E. M. Bittar, C. Adriano, T. M. Garitezi, P. F. S. Rosa, L. Mendonça-Ferreira, F. Garcia, G. de M. Azevedo, P. G. Pagliuso, E. Granado

摘要:

研究了BaFe_(2-x)Co_xAs_2超导体的Fe K X射线吸收近边结构(XANES)。没有明显的改变,在形状或能量的位置,观察到这一边缘与Co替代。这一结果提供了实验支持,以前的从头计算中,额外的Co电子集中在替代网站,并没有改变的Fe离子的电子占据。超导电性可能是由于取代原子引起的成键修饰而出现的,取代原子通过减少Fe局部矩和/或增加伴随的正交畸变的弹性能惩罚来削弱自旋密度波基态。

英文摘要:

The Fe K X-ray absorption near edge structure (XANES) of BaFe2-xCoxAs2 superconductors was investigated. No appreciable alteration in shape or energy position of this edge was observed with Co substitution. This result provides experimental support to previous ab initio calculations in which the extra Co electron is concentrated at the substitute site and do not change the electronic occupation of the Fe ions. Superconductivity may emerge due to bonding modifications induced by the substitute atom that weakens the spin-density-wave ground state by reducing the Fe local moments and/or increasing the elastic energy penalty of the accompanying orthorhombic distortion.

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