arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1012.5426cond-mat.mes-hall
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多重折叠石墨烯

Multiply Folded Graphene

Kwanpyo Kim, Zonghoon Lee, Brad Malone, Kevin T. Chan, Benjamín Alemán, William Regan, Will Gannett, M. F. Crommie, Marvin. L. Cohen, A. Zettl

摘要:

数千年来,纸、兽皮和编织织物的折叠一直被用来增强固有的平面二维材料的清晰度、曲率和视觉吸引力。对于石墨烯,一种理想的二维材料,折叠可能会将其转变为具有新的独特性质的复杂形状。在这里,我们提出了实验结果,即石墨烯中存在折叠结构(称为grafold),并且可以通过在石墨烯合成或转移过程中引入各向异性表面曲率来控制它们的形成。利用赝势-密度泛函理论计算,我们还表明双折叠改变了石墨烯的电子能带结构。此外,我们证明了插入C60到grafolds。嵌入或功能化的化学反应性折叠进一步扩大了grafold的机械,化学,光学和电子的多样性。

英文摘要:

The folding of paper, hide, and woven fabric has been used for millennia to achieve enhanced articulation, curvature, and visual appeal for intrinsically flat, two-dimensional materials. For graphene, an ideal two-dimensional material, folding may transform it to complex shapes with new and distinct properties. Here, we present experimental results that folded structures in graphene, termed grafold, exist, and their formations can be controlled by introducing anisotropic surface curvature during graphene synthesis or transfer processes. Using pseudopotential-density functional theory calculations, we also show that double folding modifies the electronic band structure of graphene. Furthermore, we demonstrate the intercalation of C60 into the grafolds. Intercalation or functionalization of the chemically reactive folds further expands grafold's mechanical, chemical, optical, and electronic diversity.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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