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arXiv 1007.4224cond-mat.dis-nncond-mat.mtrl-sci
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玻璃中间相特征动态长度尺度的直接证据

Direct evidence for a characteristic dynamic lengthscale in the intermediate phase of glasses

M. Micoulaut, M. Malki

摘要:

本文分析了xAgI-(1-x)AgPO $_3$快离子导电玻璃在柔性、中间(等静压刚性)和应力刚性相的交流电导率谱。重新标度的频率相关的频谱映射到时间相关的均方位移,其中一个典型的lengthscale表征的空间范围$\sqrt{\langle R^2(\infty)\rangle}$的非随机扩散路径计算。后者的数量作为碘化银组合物的函数进行了研究,它被发现显示在中间阶段的最大值,提供了第一个明确的证据,一个典型的长度尺度的动态性质时,系统成为均衡刚性,并进入中间阶段。

英文摘要:

AC conductivity spectra of xAgI-(1-x)AgPO$_3$ fast ion conducting glasses spanning the flexible, intermediate (isostatically rigid) and stressed rigid phases are analyzed. The rescaled frequency dependent spectra are mapped into time-dependent mean square displacements out of which a typical lengthscale characterizing the spatial extent $\sqrt{\langle R^2(\infty)\rangle}$ of non-random diffusion paths is computed. The latter quantity is studied as a function of AgI composition, it is found to display a maximum in the intermediate phase, providing the first clear evidence of a typical lengthscale of a dynamical nature when a system becomes isostatically rigid and enters the intermediate phase.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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