When a non-integrable system evolves out of equilibrium for a long time, local observables are expected to attain stationary expectation values, independent of the details of the initial state. However, intriguing experimental results with ultracold gases have shown no thermalization in non-integrable settings, triggering an intense theoretical effort to decide the question. Here we show that the phenomenology of thermalization in a quantum system is much richer than its classical counterpart. Using a new numerical technique, we identify two distinct thermalization regimes, strong and weak, occurring for different initial states. Strong thermalization, intrinsically quantum, happens when instantaneous local expectation values converge to the thermal ones. Weak thermalization, well-known in classical systems, happens when local expectation values converge to the thermal ones only after time averaging. Remarkably, we find a third group of states showing no thermalization, neither strong nor weak, to the time scales one can reliably simulate.
Eigenstate thermalization is widely accepted as the mechanism behind thermalization in generic isolated quantum systems. Using the example of a single magnetic defect embedded in the integrable spin-1/2 $XXZ$ chain, we show that locally perturbing an integrable system can give rise to eigenstate thermalization. Unique to such setups is the fact that thermodynamic and transport properties of the unperturbed integrable chain emerge in properties of the eigenstates of the perturbed (nonintegrable) one. Specifically, we show that the diagonal matrix elements of observables in the perturbed eigenst…
We study the characteristics of thermalizing and non-thermalizing operators in integrable theories as we turn on a non-integrable deformation. Specifically, we show that $σ^z$, an operator that thermalizes in the integrable transverse field Ising model, has mean matrix elements that resemble ETH, but with fluctuations around the mean that are sharply suppressed. This suppression rapidly dwindles as the Ising model becomes non-integrable by the turning on of a longitudinal field. We also construct a non-thermalizing operator in the integrable regime, which slowly approaches the ETH form as the …
Integrable systems do not obey the strong eigenstate thermalization hypothesis (ETH), which has been proposed as a mechanism of thermalization in isolated quantum systems. It has been suggested that an integrable system reaches a steady state described by a generalized Gibbs ensemble (GGE) instead of thermal equilibrium. We prove that a generalized version of the strong ETH holds for noninteracting integrable systems with translation invariance. Our generalized ETH states that any pair of energy eigenstates with similar values of local conserved quantities looks similar with respect to local o…
Free or integrable theories are usually considered to be too constrained to thermalize. For example, the retarded two-point function of a free field, even in a thermal state, does not decay to zero at long times. On the other hand, the magnetic susceptibility of the critical transverse field Ising is known to thermalize, even though that theory can be mapped by a Jordan-Wigner transformation to that of free fermions. We reconcile these two statements by clarifying under which conditions conserved charges can prevent relaxation at the level of linear response and how such obstruction can be ove…
Using numerically exact methods we examine the Fermi-Hubbard model on arbitrary cluster topology. We focus on the question which systems eventually equilibrate or even thermalize after an interaction quench when initially prepared in a state highly entangled between system and bath. We find that constants of motion in integrable clusters prevent equilibration to the thermal state. We discuss the size of fluctuations during equilibration and thermalization and the influence of integrability. The influence of real space topology and in particular of infinite-range graphs on equilibration and the…
Isolated quantum many-body systems with integrable dynamics generically do not thermalize when taken far from equilibrium. As one perturbs such systems away from the integrable point, thermalization sets in, but the nature of the crossover from integrable to thermalizing behavior is an unresolved and actively discussed question. We explore this question by studying the dynamics of the momentum distribution function in a dipolar quantum Newton's cradle consisting of highly magnetic dysprosium atoms. This is accomplished by creating the first one-dimensional Bose gas with strong magnetic dipole-…
We investigate equilibration and generalized thermalization of the quantum Harmonic chain under local quantum quench. The quench action we consider is connecting two disjoint harmonic chains of different sizes and the system jumps between two integrable settings. We verify the validity of the Generalized Gibbs Ensemble description for this infinite dimensional Hilbert space system and also identify equilibration between the subsystems as in classical systems. Using Bogoliubov transformations, we show that the eigenstates of the system prior to the quench evolve towards the Gibbs Generalized En…
We study the off-diagonal matrix elements of observables that break the translational symmetry of a spin-chain Hamiltonian, and as such connect energy eigenstates from different total quasimomentum sectors. We consider quantum-chaotic and interacting integrable points of the Hamiltonian, and focus on average energies at the center of the spectrum. In the quantum-chaotic model, we find that there is eigenstate thermalization; specifically, the matrix elements are Gaussian distributed with a variance that is a smooth function of $ω=E_α-E_β$ ({$E_α$} are the eigenenergies) and scales as $1/D$ ($D…
We establish a link between unitary relaxation dynamics after a quench in closed many-body systems and the entanglement in the energy eigenbasis. We find that even if reduced states equilibrate, they can have memory on the initial conditions even in certain models that are far from integrable. We show that in such situations the equilibrium states are still described by a maximum entropy or generalized Gibbs ensemble, regardless of whether a model is integrable or not, thereby contributing to a recent debate. In addition, we discuss individual aspects of the thermalization process, comment on …
We study the quantum dynamics of a simple translation invariant, center-of-mass (CoM) preserving model of interacting fermions in one dimension (1D), which arises in multiple experimentally realizable contexts. We show that this model naturally displays the phenomenology associated with fractonic systems, wherein single charges can only move by emitting dipoles. This allows us to demonstrate the rich Krylov fractured structure of this model, whose Hilbert space shatters into exponentially many dynamically disconnected subspaces. Focusing on exponentially large Krylov subspaces, we show that th…
We study the validity of the eigenstate thermalization hypothesis (ETH) and its role for the occurrence of initial-state independent (ISI) equilibration in closed quantum many-body systems. Using the concept of dynamical typicality, we present an extensive numerical analysis of energy exchange in integrable and nonintegrable spin-1/2 systems of large size outside the range of exact diagonalization. In case of nonintegrable systems, our finite-size scaling shows that the ETH becomes valid in the thermodynamic limit and can serve as the underlying mechanism for ISI equilibration. In case of inte…
The generalized Gibbs ensemble (GGE) was introduced ten years ago to describe observables in isolated integrable quantum systems after equilibration. Since then, the GGE has been demonstrated to be a powerful tool to predict the outcome of the relaxation dynamics of few-body observables in a variety of integrable models, a process we call generalized thermalization. This review discusses several fundamental aspects of the GGE and generalized thermalization in integrable systems. In particular, we focus on questions such as: which observables equilibrate to the GGE predictions and who should pl…
We propose a new quantity called modulus fidelity to measure the closeness of two quantum pure states. Especially, we use it to investigate the closeness of eigenstates of quantum many-body systems. When the system is integrable, the modulus fidelity of neighbor eigenstates displays a large fluctuation. But the modulus fidelity is close to a constant when system becomes non-integrable with fluctuation reduced drastically. Average modulus fidelity of neighbor eigenstates increases with the increase of parameters that destroy the integrability, which also indicates the integrable-chaos transitio…
By developing a semi-classical analysis based on the Eigenstate Thermalization Hypothesis, we determine the long time behavior of a large spin evolving with a nonlinear Hamiltonian. Despite integrable classical dynamics, we find the Eigenstate Thermalization Hypothesis for the diagonal matrix elements of observables is satisfied in the majority of eigenstates, and thermalization of long time averaged observables is generic. The exception is a novel mechanism for the breakdown of thermalization based on an unstable fixed point in the classical dynamics. Using the semi-classical analysis we deri…
Quantum information scrambling under many-body dynamics is of fundamental interest. The tripartite mutual information can quantify the scrambling via its negative value. Here, we first study the quench dynamics of tripartite mutual information in a non-integrable Ising model where the strong and weak thermalization are observed with different initial states. We numerically show that the fastest scrambling can occur when the energy density of the chosen initial state possesses the maximum density of states. We then present an experimental protocol for observing weak and strong thermalization in…
We study dynamics of entanglement in the thermalization process of an isolated quantum many-body system. We propose a simple setup for measuring the propagation speed of entanglement entropy (EE) in numerical simulations and apply it to the integrable/non-integrable spin models in 1D - the transverse Ising (TI) model, the chaotic Ising (CI) model, and the extended chaotic Ising (ECI) model. We find that two distinct time-scales $t^\ast$ and $t_{\rm {diff}}$ arise in the dynamics of EE in the thermalization process: the former represents the time-scale for the saturation of EE and the latter ch…
In this work we analyze the simultaneous emergence of diffusive energy transport and local thermalization in a nonequilibrium one-dimensional quantum system, as a result of integrability breaking. Specifically, we discuss the local properties of the steady state induced by thermal boundary driving in a XXZ spin chain with staggered magnetic field. By means of efficient large-scale matrix product simulations of the equation of motion of the system, we calculate its steady state in the long-time limit.We start by discussing the energy transport supported by the system, finding it to be ballistic…
Generalized thermalization is a process that occurs in integrable systems in which unitary dynamics, e.g., following a quantum quench, results in states in which observables after equilibration are described by generalized Gibbs ensembles (GGEs). Here we discuss an emergent eigenstate construction that allows one to built emergent local Hamiltonians of which one eigenstate captures the entire generalized thermalization process following a global quantum quench. Specifically, we study the emergent eigenstate that describes the quantum dynamics of hard-core bosons in one dimension (1D) for which…
By calculating correlation functions for the Lieb-Liniger model based on the algebraic Bethe ansatz method, we conduct a finite-size scaling analysis of the eigenstate thermalization hypothesis (ETH) which is considered to be a possible mechanism of thermalization in isolated quantum systems. We find that the ETH in the weak sense holds in the thermodynamic limit even for an integrable system although it does not hold in the strong sense. Based on the result of the finite-size scaling analysis, we compare the contribution of the weak ETH to thermalization with that of yet another thermalizatio…
An isolated quantum many-body system in an initial pure state will come to thermal equilibrium if it satisfies the eigenstate thermalization hypothesis (ETH). We consider alternatives to ETH that have been proposed. We first show that von Neumann's quantum ergodic theorem relies on an assumption that is essentially equivalent to ETH. We also investigate whether, following a sudden quench, special classes of pure states can lead to thermal behavior in systems that do not obey ETH, namely, integrable systems. We find examples of this, but only for initial states that obeyed ETH before the quench…
We study thermalization in many-body quantum systems locally coupled to an external bath. It is shown that quantum chaotic systems do thermalize, that is, they exhibit relaxation to an invariant ergodic state which, in the bulk, is well approximated by the grand canonical state. Moreover, the resulting ergodic state in the bulk does not depend on the details of the baths. On the other hand, for integrable systems the invariant state does depend on the bath and is different from the grand canonical state.
The recent discovery of quantum many-body scar states has revealed the possibility of having states with low entanglement that violate the eigenstate thermalization hypothesis in nonintegrable systems. Such states with low entanglement entropy are rare but naturally exist in the integrable system of free fermions. Here, we demonstrate analytically that these atypical states would be always eliminated when an arbitrary weak interaction is introduced between the fermions. In particular, we show that the probability of having a many-body scar state with entanglement entropy satisfying a sub-volum…
Deriving conditions under which a macroscopic system thermalizes directly from the underlying quantum many-body dynamics of its microscopic constituents is a long-standing challenge in theoretical physics. The well-known eigenstate thermalization hypothesis (ETH) is presumed to be a key mechanism, but has defied rigorous verification for generic systems thus far. A weaker variant (weak ETH), by contrast, is provably true for a large variety of systems, including even many integrable models, but its implications with respect to the problem of thermalization are still largely unexplored. Here we…
We investigate the relaxation dynamics of open non-integrable quantum many-body systems in the thermodynamic limit by using a tensor-network formalism. We simulate the Lindblad quantum master equation (LQME) of infinite systems by making use of the uniform matrix product operators (MPO) as the ansatz of their density matrices. Furthermore, we establish a method to measure the thermodynamic equivalence between two states described by the uniform MPOs. We numerically show that when an initial state of the LQME is a thermal Gibbs state, a time evolved state is always indistinguishable from a Gibb…
Non-integrability is often taken as a prerequisite for quantum thermalization. Still, a generally accepted definition of quantum integrability is lacking. With the basis in the driven Rabi model we discuss this careless usage of the term "integrability" in connection to quantum thermalization. The model would be classified as non-integrable according to the most commonly used definitions, for example, the only preserved quantity is the total energy. Despite this fact, a thorough analysis conjectures that the system will not thermalize. Thus, our findings suggest first of all (i) that care shou…
Even though foundations of the eigenstate thermalization hypothesis (ETH) are based on random matrix theory, physical Hamiltonians and observables substantially differ from random operators. One of the major challenges is to embed local integrals of motion (LIOMs) within the ETH. Here we focus on their impact on fluctuations and structure of the diagonal matrix elements of local observables. We first show that nonvanishing fluctuations entail the presence of LIOMs. Then we introduce a generic protocol to construct observables, subtracted by their projections on LIOMs as well as products of LIO…
Thermalization of isolated quantum systems has been studied intensively in recent years and significant progresses have been achieved. Here, we study thermalization of small quantum systems that interact with large chaotic environments under the consideration of Schrödinger evolution of composite systems, from the perspective of the zeroth law of thermodynamics. Namely, we consider a small quantum system that is brought into contact with a large environmental system; after they have relaxed, they are separated and their temperatures are studied. Our question is under what conditions the small …
Understanding how isolated quantum systems thermalize has recently gathered renewed interest almost 100 years after the first work by von Neumann, thanks to the experimental realizations of such systems. Experimental and numerical pieces of evidence imply that nonintegrability of the system plays an important role in thermalization. Nonintegrable systems that conserve energy alone are expected to be effectively described by the (micro)canonical ensemble due to the so-called eigenstate thermalization hypothesis (ETH) in the thermodynamic limit. In contrast, it is expected that stationary states…
We combine matrix product operator techniques with Chebyshev polynomial expansions and present a method that is able to explore spectral properties of quantum many-body Hamiltonians. In particular, we show how this method can be used to probe thermalization of large spin chains without explicitly simulating their time evolution, as well as to compute full and local densities of states. The performance is illustrated with the examples of the Ising and PXP spin chains. For the non-integrable Ising chain, our findings corroborate the presence of thermalization for several initial states, well bey…
Many phases of matter, including superconductors, fractional quantum Hall fluids and spin liquids, are described by gauge theories with constrained Hilbert spaces. However, thermalization and the applicability of quantum statistical mechanics has primarily been studied in unconstrained Hilbert spaces. In this article, we investigate whether constrained Hilbert spaces permit local thermalization. Specifically, we explore whether the eigenstate thermalization hypothesis (ETH) holds in a pinned Fibonacci anyon chain, which serves as a representative case study. We first establish that the constra…
We show that after a quantum quench of the parameter controlling the number of particles in a Fermi-Hubbard model on scale free graphs, the distribution of energy modes follows a power law dependent on the quenched parameter and the connectivity of the graph. This paper contributes to the literature of quantum quenches on lattices, in which, for many integrable lattice models the distribution of modes after a quench thermalizes to a Generalized Gibbs Ensemble; this paper provides another example of distribution which can arise after relaxation. We argue that the main role is played by the symm…
We consider quantum quenches in integrable models. We argue that the behaviour of local observables at late times after the quench is given by their expectation values with respect to a single representative Hamiltonian eigenstate. This can be viewed as a generalization of the eigenstate thermalization hypothesis to quantum integrable models. We present a method for constructing this representative state by means of a generalized Thermodynamic Bethe Ansatz (GTBA). Going further, we introduce a framework for calculating the time dependence of local observables as they evolve towards their stati…
We study how the proximity to an integrable point or to localization as one approaches the atomic limit, as well as the mixing of symmetries in the chaotic domain, may affect the onset of thermalization in finite one-dimensional systems. We consider systems of hard-core bosons at half-filling with nearest neighbor hopping and interaction, and next-nearest neighbor interaction. The latter breaks integrability and induces a ground-state superfluid to insulator transition. By full exact diagonalization, we study chaos indicators and few-body observables. We show that when different symmetry secto…
The eigenstate thermalization hypothesis (ETH) attempts to bridge the gap between quantum mechanical and statistical mechanical descriptions of isolated quantum systems. Here, we define unbiased measures for how well the ETH works in various regimes, by mapping general interacting quantum systems on regular lattices onto a single particle living on a high-dimensional graph. By numerically analyzing deviations from ETH behavior in the non-integrable Ising model, we propose a quantity that we call the $n$-$weight$ to democratically characterize the average deviations for all operators residing o…
We consider a system of two coupled oscillators one of which is driven parametrically and investigate both classical and quantum dynamics within Floquet description. Characteristic changes in the time evolution of the quantum fluctuations are observed for dynamically stable and unstable regions. Dynamical instability generated by the parametrically driven oscillator leads to infinite temperature thermalization of the undriven oscillator which is evident from the equi-partitioning of energy, reduced density matrix and saturation of entanglement entropy. We also confirm that the classical Lyapun…
We study the quantum relaxation of the two-dimensional transverse-field Ising model after global quenches with a real-time variational Monte Carlo method and address the question whether this non-integrable, two-dimensional system thermalizes or not. We consider both interaction quenches in the paramagnetic phase and field quenches in the ferromagnetic phase and compare the time-averaged probability distributions of non-conserved quantities like magnetization and correlation functions to the thermal distributions according to the canonical Gibbs ensemble obtained with quantum Monte Carlo simul…
We analyze a simple model of quantum dynamics, which is a discrete-time deterministic version of the Frederickson-Andersen model. We argue that this model is integrable, with a quasiparticle description related to the classical hard-rod gas. Despite the integrability of the model, commutators of physical operators grow as in generic chaotic models, with a diffusively broadening front, and local operators obey the eigenstate thermalization hypothesis (ETH). However, large subsystems violate ETH; as a function of subsystem size, eigenstate entanglement first increases linearly and then saturates…
We study the heat statistics of a multi-level $N$-dimensional quantum system monitored by a sequence of projective measurements. The late-time, asymptotic properties of the heat characteristic function are analyzed in the thermodynamic limit of a high, ideally infinite, number $M$ of measurements $(M \to \infty)$. In this context, the conditions allowing for an Infinite-Temperature Thermalization (ITT), induced by the repeated monitoring of the quantum system, are discussed. We show that ITT is identified by the fixed point of a symmetric random matrix that models the stochastic process origin…
We study the out-of-equilibrium dynamics of the quantum cellular automaton known as "Rule 54". For a class of low-entangled initial states, we provide an analytic description of the effect of the global evolution on finite subsystems in terms of simple quantum channels, which gives access to the full thermalization dynamics at the microscopic level. As an example, we provide analytic formulae for the evolution of local observables and Rényi entropies. We show that, in contrast to other known examples of exactly solvable quantum circuits, Rule 54 does not behave as a simple Markovian bath on it…
