We consider the system of Maxwell-Stefan equations which describe multicomponent diffusive fluxes in non-dilute solutions or gas mixtures. We apply the Perron-Frobenius theorem to the irreducible and quasi-positive matrix which governs the flux-force relations and are able to show normal ellipticity of the associated multicomponent diffusion operator. This provides local-in-time wellposedness of the Maxwell-Stefan multicomponent diffusion system in the isobaric, isothermal case.
Maxwell-Stefan systems describing the dynamics of the molar concentrations of a gas mixture with an arbitrary number of components are analyzed in a bounded domain under isobaric, isothermal conditions. The systems consist of mass balance equations and equations for the chemical potentials, depending on the relative velocities, supplemented with initial and homogeneous Neumann boundary conditions. Global-in-time existence of bounded weak solutions to the quasilinear parabolic system and their exponential decay to the homogeneous steady state are proved. The mathematical difficulties are due to…
We introduce a Darcy-scale model to describe compressible multi-component flow in a fully saturated porous medium. In order to capture cross-diffusive effects between the different species correctly, we make use of the Maxwell--Stefan theory in a thermodynamically consistent way. For inviscid flow the model turns out to be a nonlinear system of hyperbolic balance laws. We show that the dissipative structure of the Maxwell-Stefan operator permits to guarantee the existence of global classical solutions for initial data close to equilibria. Furthermore it is proven by relative entropy techniques…
In this article we deduce a mathematical model of Maxwell-Stefan type for a reactive mixture of polyatomic gases with a continuous structure of internal energy. The equations of the model are derived in the diffusive limit of a kinetic system of Boltzmann equations for the considered mixture, in the general non-isothermal setting. The asymptotic analysis of the kinetic system is performed under a reactive-diffusive scaling for which mechanical collisions are dominant with respect to chemical reactions. The resulting system couples the Maxwell-Stefan equations for the diffusive fluxes with the …
Multi-species Boltzmann equations for gaseous mixtures, with analytic cross sections and under Grad's angular cutoff assumption, are considered under diffusive scaling. In the limit, we formally obtain an explicit expression for the binary diffusion coefficients in the Maxwell-Stefan equations.
The Navier-Stokes-Maxwell-Stefan system describes the dynamics of an incompressible gaseous mixture in isothermal condition. In this paper we set up an artificial compressibility type approximation. In particular we focus on the existence of solution for the approximated system and the convergence to the incompressible case. The existence of the approximating system is proved by means of semidiscretization in time and by estimating the fractional time derivative.
The weak-strong uniqueness for Maxwell--Stefan systems and some generalized systems is proved. The corresponding parabolic cross-diffusion equations are considered in a bounded domain with no-flux boundary conditions. The key points of the proofs are various inequalities for the relative entropy associated to the systems and the analysis of the spectrum of a quadratic form capturing the frictional dissipation. The latter task is complicated by the singular nature of the diffusion matrix. This difficulty is addressed by proving its positive definiteness on a subspace and using the Bott--Duffin …
A mathematical model is proposed where the classical Maxwell-Stefan diffusion model for gas mixtures is coupled to an advection-type equation for the temperature of the physical system. This coupled system is derived from first principles in the sense that the starting point of our analysis is a system of Boltzmann equations for gaseous mixtures. We perform an asymptotic analysis on the Boltzmann model under diffuse scaling to arrive at the proposed coupled system.
The incompressible Navier-Stokes equations coupled to the Maxwell-Stefan relations for the molar fluxes are analyzed in bounded domains with no-flux boundary conditions. The system models the dynamics of a multicomponent gaseous mixture under isothermal conditions. The global-in-time existence of bounded weak solutions to the strongly coupled model and their exponential decay to the homogeneous steady state are proved. The mathematical difficulties are due to the singular Maxwell-Stefan diffusion matrix, the cross-diffusion terms, and the Navier-Stokes coupling. The key idea of the proof is th…
We study a kinetic model for non-reactive mixtures of monatomic gases with hard-sphere cross-sections under isothermal condition. By considering a diffusive scaling of the kinetic model and using the method of moments, we formally obtain from the continuity and momentum balance equations of the species, in the limit as the scaling parameter goes to zero, the Maxwell-Stefan diffusion equations, with an explicit expression for the diffusion coefficients.
In this study we apply the maximum entropy principle to derive the properly scaled velocity distribution function of Boltzmann equations for mixtures, which leads to a non-isothermal Maxwell-Stefan diffusion model. We also analyze the entropy balance law and derive the kinetic entropy production from the scaled distribution function.
A Maxwell-Stefan system for fluid mixtures with driving forces depending on Cahn-Hilliard-type chemical potentials is analyzed. The corresponding parabolic cross-diffusion equations contain fourth-order derivatives and are considered in a bounded domain with no-flux boundary conditions. The main difficulty of the analysis is the degeneracy of the diffusion matrix, which is overcome by proving the positive definiteness of the matrix on a subspace and using the Bott--Duffin matrix inverse. The global existence of weak solutions and a weak-strong uniqueness property are shown by a careful combina…
We consider combustion problems in the presence of complex chemistry and nonlinear diffusion laws leading to fully nonlinear multispecies reaction-diffusion equations. We establish results of existence of solution and maximum principle, i.e. positivity of the mass fractions, which rely on specific properties of the models. The nonlinear diffusion coefficients are obtained by resolution of the so-called Stefan-Maxwell equations.
The global-in-time existence of bounded weak solutions to the Maxwell-Stefan-Fourier equations in Fick-Onsager form is proved. The model consists of the mass balance equations for the partial mass densities and and the energy balance equation for the total energy. The diffusion and heat fluxes depend linearly on the gradients of the thermo-chemical potentials and the gradient of the temperature and include the Soret and Dufour effects. The cross-diffusion system exhibits an entropy structure, which originates from the thermodynamic modeling. The lack of positive definiteness of the diffusion m…
We investigate the diffusion asymptotics of the Boltzmann equation for gaseous mixtures, in the perturbative regime around a local Maxwellian vector whose fluid quantities solve a flux-incompressible Maxwell-Stefan system. Our framework is the torus and we consider hard-potential collision kernels with angular cutoff. As opposed to existing results about hydrodynamic limits in the mono-species case, the local Maxwellian we study here is not a local equilibrium of the mixture due to cross-interactions. By means of a hypocoercive formalism and introducing a suitable modified Sobolev norm, we bui…
We investigate a coupling between the compressible Navier-Stokes-Fourier system and the full Maxwell-Stefan equations. This model describes the motion of chemically reacting heat-conducting gaseous mixture. The viscosity coefficients are density-dependent functions vanishing on vacuum and the internal pressure depends on species concentrations. By several levels of approximation we prove the global-in-time existence of weak solutions on the three-dimensional torus.
After the pioneering work by Giovangigli on mathematics of multicomponent flows, several attempts were made to introduce global weak solutions for the PDEs describing the dynamics of fluid mixtures. While the incompressible case with constant density was enlighted well enough due to results by Chen and Jüngel (isothermal case), or Marion and Temam, some open questions remain for the weak solution theory of gas mixtures with their corresponding equations of mixed parabolic-hyperbolic type. For instance, Mucha, Pokorny and Zatorska showed the possibility to stabilise the hyperbolic component by …
Recently, the authors proved [2] that the Maxwell-Stefan system with an incompressibility-like condition on the total flux can be rigorously derived from the multi-species Boltzmann equation. Similar cross-diffusion models have been widely investigated, but the particular case of a perturbative incompressible setting around a non constant equilibrium state of the mixture (needed in [2]) seems absent of the literature. We thus establish a quantitative perturbative Cauchy theory in Sobolev spaces for it. More precisely, by reducing the analysis of the Maxwell-Stefan system to the study of a quas…
The mass-based Maxwell-Stefan approach to one-phase multicomponent reactive mixtures is mathematically analyzed. It is shown that the resulting quasilinear, strongly coupled reaction-diffusion system is locally well-posed in an $L_p$-setting and generates a local semiflow on its natural state space. Solutions regularize instantly and become strictly positive if their initial components are all nonnegative and nontrivial. For a class of reversible mass-action kinetics, the positive equilibria are identified: these are precisely the constant chemical equilibria of the system, which may form a ma…
The large-time asymptotics of weak solutions to Maxwell--Stefan diffusion systems for chemically reacting fluids with different molar masses and reversible reactions are investigated. The diffusion matrix of the system is generally neither symmetric nor positive definite, but the equations admit a formal gradient-flow structure which provides entropy (free energy) estimates. The main result is the exponential decay to the unique equilibrium with a rate that is constructive up to a finite-dimensional inequality. The key elements of the proof are the existence of a unique detailed-balanced equil…
In this paper, we present a splitting algorithm to solve multicomponent transport models. These models are related to plasma simulations, in which we consider the local thermodynamic equilibrium and weakly ionised plasma-mixture models that are used for medical and technical applications in etching processes. These multi-component transport-mixture models can be derived by approximately solving a linearised multi-component Boltzmann equation with an approximation of the collision terms in the mass, momentum and energy equations. The model-equations are nonlinear partial differential equations …
In this chapter of the book entitled, "Extending the Theory of Composites to Other Areas of Science" [edited by Graeme W. Milton, 2016] we derive the analyticity properties of the electromagnetic Dirichlet-to-Neumann map for the time-harmonic Maxwell's equations for passive linear multicomponent media. Moreover, we discuss the connection of this map to Herglotz functions for isotropic and anisotropic multicomponent composites.
We consider a system of partial differential equations describing mass transport in a multicomponent isothermal compressible fluid. The diffusion fluxes obey the Fick-Onsager or Maxwell-Stefan closure approach. Mechanical forces result into one single convective mixture velocity, the barycentric one, which obeys the Navier-Stokes equations. The thermodynamic pressure is defined by the Gibbs-Duhem equation. Chemical potentials and pressure are derived from a thermodynamic potential, the Helmholtz free energy, with a bulk density allowed to be a general convex function of the mass densities of t…
Our study of abstract quasi-linear parabolic problems in time-weighted L_p-spaces, begun in [17], is extended in this paper to include singular lower order terms, while keeping low initial regularity. The results are applied to reaction-diffusion problems, including Maxwell-Stefan diffusion, and to geometric evolution equations like the surface-diffusion flow or the Willmore flow. The method presented here will be applicable to other parabolic systems, including free boundary problems.
The uniqueness of bounded weak solutions to strongly coupled parabolic equations in a bounded domain with no-flux boundary conditions is shown. The equations include cross-diffusion and drift terms and are coupled selfconsistently to the Poisson equation. The model class contains special cases of the Maxwell-Stefan equations for gas mixtures, generalized Shigesada-Kawasaki-Teramoto equations for population dynamics, and volume-filling models for ion transport. The uniqueness proof is based on a combination of the $H^{-1}$ technique and the entropy method of Gajewski.
