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arXiv 0912.4889cond-mat.supr-concond-mat.mtrl-sci
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高硼化物和氧分布不均匀性对未掺杂和掺杂二硼化镁临界电流密度的影响

Effect of higher borides and inhomogeneity of oxygen distribution on critical current density of undoped and doped magnesium diboride

T. A. Prikhna, W. Gawalek, V. M. Tkach, N. I. Danilenko, Ya M. Savchuk, S. N. Dub, V. E. Moshchil, A. V. Kozyrev, N. V. Sergienko, M. Wendt, V. S. Melnikov, J. … 展开作者

T. A. Prikhna, W. Gawalek, V. M. Tkach, N. I. Danilenko, Ya M. Savchuk, S. N. Dub, V. E. Moshchil, A. V. Kozyrev, N. V. Sergienko, M. Wendt, V. S. Melnikov, J. Dellith, H Weber, M Eisterer, Ch Schmidt, T Habisreuther, D Litzkendorf, J Vajda, A. P. Shapovalov, V. Sokolovsky, P. A. Nagorny, V. B. Sverdun, J. Kosa, F. Karau, A. V. Starostina

摘要:

研究了Ti、Ta、SiC掺杂对高压合成材料(2GPa)中MgB_2基体中影响钉扎的结构不均匀性:高硼化物(MgB_(12))和富氧Mg-B-O夹杂物的数量和分布的影响,并提出了一种不同于一般公认的掺杂效应提高jc的机理。接近理论致密的SiC掺杂材料表现出jc= 1000000 A/sq。cm,20K时Hirr = 8.5T。分别在10、20和25 K下在高于9、6和4 T的场中的最高jc由在2 GPa、600 oC下由Mg和B在没有添加剂的情况下合成的材料证明(在20 K下jc= 100 A/sq。cm)。以Mg:B = 1:20为原料合成了镁硼复合材料。最高jc(60000 A/sq. cm,在20 K零场,Hirr= 5 T)和SC相的量(95.3倍的屏蔽分数),Tc为37 K的材料具有近MgB 12组成的基质证明。具有MgB 12基质的材料具有MgB 2基质的两倍的显微硬度(在4.9 N的载荷下分别为25 GPa和13.08 GPa)。

英文摘要:

The effect of doping with Ti, Ta, SiC in complex with synthesis temperature on the amount and distribution of structural inhomogeneities in MgB2 matrix of high-pressuresynthesized-materials (2 GPa) which can influence pining: higher borides (MgB12) and oxygen-enriched Mg-B-O inclusions, was established and a mechanism of doping effect on jc increase different from the generally accepted was proposed. Near theoretically dense SiC-doped material exhibited jc= 1000000 A/sq. cm in 1T field and Hirr =8.5 T at 20 K. The highest jc in fields above 9, 6, and 4 T at 10, 20, and 25 K, respectively, was demonstrated by materials synthesized at 2 GPa, 600 oC from Mg and B without additions (at 20 K jc= 100 A/sq. cm in 10 T field). Materials synthesized from Mg and B taken up to 1:20 ratio were superconductive. The highest jc (60000 A/sq. cm at 20 K in zero field, Hirr= 5 T) and the amount of SC phase (95.3 percents of shielding fraction), Tc being 37 K were demonstrated by materials having near MgB12 composition of the matrix. The materials with MgB12 matrix had a doubled microhardness of that with MgB2 matrix (25 GPa and 13.08 GPa, at a load of 4.9 N, respectively).

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