We propose a method of controlling two-atom interaction using both magnetic and laser fields. We analyse the role of quantum interference between magnetic and optical Feshbach resonances in controlling cold collision. In particular, we demonstrate that this method allows us to suppress inelastic and enhance elastic scattering cross sections. Quantum interference is shown to modify significantly the threshold behaviour and resonant interaction of ultracold atoms. Furthermore, we show that it is possible to manipulate not only the spherically symmetric s-wave interaction but also the anisotropic higher partial-wave interactions which are particularly important for high temperature superfluid or superconducting phases of matter.
Magnetically tunable Feshbach resonances for polar paramagnetic ground-state diatomics are too narrow to allow for magnetoassociation starting from trapped, ultracold atoms. We show that non-resonant light can be used to engineer the Feshbach resonances in their position and width. For non-resonant field strengths of the order of $10^9\,$W/cm$^2$, we find the width to be increased by three orders of magnitude, reaching a few Gauss. This opens the way for producing ultracold molecules with sizeable electric and magnetic dipole moments and thus for many-body quantum simulations with such particl…
We demonstrate control of the collapse and expansion of an 88Sr Bose-Einstein condensate using an optical Feshbach resonance (OFR) near the 1S0-3P1 intercombination transition at 689 nm. Significant changes in dynamics are caused by modifications of scattering length by up to +- ?10a_bg, where the background scattering length of 88Sr is a_bg = -2a0 (1a0 = 0.053 nm). Changes in scattering length are monitored through changes in the size of the condensate after a time-of-flight measurement. Because the background scattering length is close to zero, blue detuning of the OFR laser with respect to …
We theoretically study the dynamics of a trapped ion that is immersed in an ultracold gas of weakly bound atomic dimers created by a Feshbach resonance. Using quasi-classical simulations, we find a crossover from dimer dissociation to molecular ion formation depending on the binding energy of the dimers. The location of the crossover strongly depends on the collision energy and the time-dependent fields of the Paul trap. Deeply bound dimers lead to fast molecular ion formation, with rates approaching the Langevin collision rate $Γ'_\text{L}\approx4.8\times10^{-9}\,$cm$^3$s$^{-1}$. The kinetic …
This paper reviews current experimental and theoretical progress in the study of dipolar quantum gases of ground and meta-stable atoms with a large magnetic moment. We emphasize the anisotropic nature of Feshbach resonances due to coupling to fast-rotating resonant molecular states in ultracold s-wave collisions between magnetic atoms in external magnetic fields. The dramatic differences in the distribution of resonances of magnetic $^7$S$_3$ chromium and magnetic lanthanide atoms with a submerged 4f shell and non-zero electron angular momentum is analyzed. We focus on Dysprosium and Erbium as…
It is demonstrated that elastic collisions of ultracold atoms forming a heteronuclear collision complex can be manipulated by laboratory practicable dc electric fields. The mechanism of electric field control is based on the interaction of the instantaneous dipole moment of the collision pair with external electric fields. It is shown that this interaction is dramatically enhanced in the presence of a p-wave shape or Feshbach scattering resonance near the collision threshold, which leads to novel electric-field-induced Feshbach resonances.
We study enhanced magneto-association of atoms into weakly-bound molecules near a Feshbach resonance using a quench preparatory stage. In anticipation of experiments with NASA's Cold Atom Laboratory aboard the International Space Station, we assume as a baseline a dual-species ($^{87}$Rb and $^{41}$K) gas in a parameter regime enabled by a microgravity environment. This includes subnanokelvin temperatures and dual-species gases at densities as low as 10$^8$/cm$^3$. Our studies indicate that, in such a regime, traditional magneto-association schemes are inefficient due to the weak coupling betw…
We present expressions demonstrating that collisional decoherence of ultracold atoms or molecules in a coherent superposition of non-degenerate quantum states is suppressed when both the real and imaginary parts of the scattering lengths for the states in the coherent superposition are equal. We show that the rate of collisional decoherence can be enhanced or suppressed by varying an external magnetic field near a Feshbach resonance. For some resonances, the suppression is very dramatic. We propose a method for measuring the scattering length of ultracold particles in excited quantum states ex…
We investigate the possibility of forming Li+Yb ultracold molecules by magnetoassociation in mixtures of ultracold atoms. We find that magnetically tunable Feshbach resonances exist, but are extremely narrow for even-mass ytterbium isotopes, which all have zero spin. For odd-mass Yb isotopes, however, there is a new mechanism due to hyperfine coupling between the electron spin and the Yb nuclear magnetic moment. This mechanism produces Feshbach resonances for fermionic Yb isotopes that can be more than 2 orders of magnitude larger than for the bosonic counterparts.
We have investigated magnetically tunable Feshbach resonances in ultracold collisions of Rb with Yb in its metastable $^3$P$_2$ and $^3$P$_0$ states, using coupled-channel scattering and bound-state calculations. For the $^3$P$_2$ state, we find sharp resonances when both atoms are in their lowest Zeeman sublevels. However, these resonances are decayed by inelastic processes that produce Yb atoms in $^3$P$_1$ and $^3$P$_0$ states. The molecules that might be produced by magnetoassociation at the $^3$P$_2$ thresholds can decay by similar pathways and would have lifetimes no more than a few micr…
We show an all-optical method of making 7Li condensate using tunability of the scattering length in the proximity of a Feshbach resonance. We report the observation of two new Feshbach resonances on |F = 1;mF = 0> state. The narrow (broad) resonance of 7 G (34 G) width is detected at 831 +- 4 G (884 +4 -13 G). Position of the scattering length zero crossing between the resonances is found at 836 +- 4 G. The broad resonance is shown to be favorable for run away evaporation which we perform in a crossed-beam optical dipole trap. Starting directly form the phase space density of a magneto-optical…
We investigate magnetically tunable Feshbach resonances in ultracold collisions between ground-state Yb and Cs atoms, using coupled-channel calculations based on an interaction potential recently determined from photoassociation spectroscopy. We predict resonance positions and widths for all stable isotopes of Yb, together with resonance decay parameters where appropriate. The resonance patterns are richer and more complicated for fermionic Yb than for spin-zero isotopes, because there are additional level splittings and couplings due to scalar and tensorial Yb hyperfine interactions. We exami…
We report the creation of ultracold bosonic $^{23}$Na$^{87}$Rb Feshbach molecules via magneto-association. By ramping the magnetic field across an interspecies Feshbach resonance, at least 4000 molecules can be produced out of the near degenerate ultracold mixture. Fast loss due to inelastic atom-molecule collisions is observed, which limits the pure molecule number, after residual atoms removal, to 1700. The pure molecule sample can live for 21.8(8) ms in the optical trap, long enough for future molecular spectroscopy studies toward coherently transferring to the singlet ro-vibrational ground…
We investigate magnetoassociation of ultracold Feshbach molecules from a Bose- Einstein condensate of Cs atoms and explore the spectrum of weakly bound molecular states close to the atomic threshold. By exploiting the variation of magnetic field experienced by a molecular cloud falling in the presence of a magnetic field gradient, we demonstrate the repeated output coupling of molecules from a single atomic cloud using a Feshbach resonance at 19.89 G. Using this method we are able to produce up to 24 separate pulses of molecules from a single atomic condensate, with a molecular pulse created e…
We consider the possibilities for producing ultracold mixtures of K and Cs and forming KCs molecules by magnetoassociation. We carry out coupled-channel calculations of the interspecies scattering length for $^{39}$KCs, $^{41}$KCs and $^{40}$KCs and characterize Feshbach resonances due to s-wave and d-wave bound states, with widths ranging from below 1 nG to 5 G. We also calculate the corresponding bound-state energies as a function of magnetic field. We give a general discussion of the combinations of intraspecies and interspecies scattering lengths needed to form low-temperature atomic mixtu…
We explore the feasibility of producing ultracold diatomic molecules with nonzero electric and magnetic dipole moments by magnetically associating two atoms, one with zero electron spin and one with nonzero spin. Feshbach resonances arise through the dependence of the hyperfine coupling on internuclear distance. We survey the Feshbach resonances in diatomic systems combining the nine stable alkali-metal isotopes with those of Yb, focussing on the illustrative examples of RbYb and CsYb. We show that the resonance widths may expressed as a product of physically comprehensible terms in the framew…
We investigate the prospects of controlling charge-exchange in ultracold collisions of heteroisotopic combinations of atoms and ions of the same element. The treatment, readily applicable to alkali or alkanine-earth metals, is illustrated in the process $^9$Be$^{+}$ + $^{10}$Be $\leftrightarrow$ $^{9}$Be + $^{10}$Be$^{+}$, which exhibits favorable electronic, nuclear, and hyperfine structure. Feshbach resonances are obtained from quantum scattering calculations in a standard coupled-channel formalism with non-BO terms originating from the nuclear kinetic operator. Near a narrow resonance predi…
Magnetic Feshbach resonances are an invaluable tool for controlling ultracold atoms and molecules. They can be used to tune atomic interactions and have been used extensively to explore few- and many-body phenomena. They can also be used for magnetoassociation, in which pairs of atoms are converted into molecules by ramping an applied magnetic field across a resonance. Pairs of open-shell atoms, such as the alkalis, chromium, and some lanthanides, exhibit broad resonances because the corresponding molecule has multiple electronic states. However, molecules formed between alkali and closed-shel…
We produce Bose-Einstein condensates of $^{162}$Dy atoms employing an innovative technique based on a resonator-enhanced optical trap that allows efficient loading from the magneto-optical trap and fast evaporation. We characterize the scattering properties of the ultracold atoms for magnetic fields between 6 and 30 G. In addition to the typical chaotic distribution of narrow Feshbach resonances in Lanthanides, we discover two rather isolated broad features at around 22 G and 27 G. A characterization using the complementary measurements of losses, thermalization, anisotropic expansion and mole…
We investigate magnetoassociation of ultracold fermionic Feshbach molecules in a mixture of $^{40}$K and $^{87}$Rb atoms, where we can create as many as $7\times 10^4$ $^{40}$K$^{87}$Rb molecules with a conversion efficiency as high as 45%. In the perturbative regime, we find that the conversion efficiency depends linearly on the density overlap of the two gases, with a slope that matches a parameter-free model that uses only the atom masses and the known Feshbach resonance parameters. In the saturated regime, we find that the maximum number of Feshbach molecules depends on the atoms' phase-sp…
Decay of bound states due to coupling with free particle states is a general phenomenon occurring at energy scales from MeV in nuclear physics to peV in ultracold atomic gases. Such a coupling gives rise to Fano-Feshbach resonances (FFR) that have become key to understanding and controlling interactions - in ultracold atomic gases, but also between quasiparticles such as microcavity polaritons. The energy positions of FFR were shown to follow quantum chaotic statistics. In contrast, lifetimes which are the fundamental property of a decaying state, have so far escaped a similarly comprehensive …
A few 85Rb atoms were trapped in a micron-size magneto-optical trap with a high quadrupole magnetic-field gradient and the number of atoms was precisely controlled by suppressing stochastic loading and loss events via real-time feedback on the magnetic field gradient. The measured occupation probability of single atom was as high as 99%. Atoms up to five were also trapped with high occupation probabilities. The present technique could be used to make a deterministic atom source.
Collisional resonances are an important tool which has been used to modify interactions in ultracold gases, for realizing novel Hamiltonians in quantum simulations, for creating molecules from atomic gases and for controlling chemical reactions. So far, such resonances have been observed for atom-atom collisions, atom-molecule collisions and collisions between Feshbach molecules which are very weakly bound. Whether such resonances exist for ultracold ground state molecules has been debated due to the possibly high density of states and/or rapid decay of the resonant complex. Here we report a v…
Controlling physical systems and their dynamics on the level of individual quanta propels both fundamental science and quantum technologies. Trapped atomic and molecular systems, neutral and charged, are at the forefront of quantum science. Their extraordinary level of control is evidenced by numerous applications in quantum information processing and quantum metrology. Studying the long-range interactions between these systems when combined in a hybrid atom-ion trap has lead to landmark results. Reaching the ultracold regime, however, where quantum mechanics dominates the interaction, e.g., g…
The spectrum of two bosons and two fermions in a trap is calculated using a correlated-Gaussian basis throughout the range of a broad Fano-Feshbach resonance. The calculations provide a few-body solution to the magneto-association of fermionic Feshbach molecules. This solution is used to study the time evolution of the system as the scattering length changes, mimicking experiments with Bose-Fermi mixtures near Fano-Feshbach resonances. The structure of avoided crossings in the few-body spectrum enables an interpretation of the dynamics of the system as a sequence of Landau-Zener transitions. T…
We theoretically investigate the control of a magnetic Feshbach resonance using a bound-to-bound molecular transition driven by spatially modulated laser light. Due to the spatially periodic coupling between the ground and excited molecular states, there exists a band structure of bound states, which can uniquely be characterized by some extra bumps in radio-frequency spectroscopy. With the increasing of coupling strength, the series of bound states will cross zero energy and directly result in a number of scattering resonances, whose position and width can be conveniently tuned by the couplin…
We investigate ultracold magnetic-field-assisted collisions in the so far unexplored ErYb system. The nonsphericity of the Er atom leads to weakly anisotropic interactions that provide the mechanism for Feshbach resonances to emerge. The resonances are moderately sparsely distributed with a density of $0.1\,{\rm G}^{-1}-0.3\,{\rm G}^{-1}$ and exhibit chaotic statistics characterized by a Brody parameter $η\approx 0.5-0.7$. The chaotic behaviour of Feshbach resonances is accompanied by strong mixing of magnetic and rotational quantum numbers in near-threshold bound states. We predict the existe…
Ultracold potassium is an interesting candidate for quantum technology applications and fundamental research as it allows controlling intra-atomic interactions via low-field magnetic Feshbach resonances. However, the realization of high-flux sources of Bose-Einstein condensates remains challenging due to the necessity of optical trapping to use magnetic fields as free parameter. We investigate the production of all-optical $^{39}$K Bose-Einstein condensates with different scattering lengths using a Feshbach resonance near $33$ G. By tuning the scattering length in a range between $75\, a_0$ an…
We study $^{87}$Rb cold collisions in a static magnetic field and a single-color radio frequency (RF) field by employing the multi-channel quantum defect theory in combination with the Floquet method to solve the two-body time-dependent Schrödinger equation. Our results show that RF fields can modify the two-body scattering length by a large scale through Feshbach resonances both in low and high static magnetic field regimes. Such RF induced Feshbach resonances can be applied to quenching experiments or controlling interactions in spinor condensates. Here, we also show that analogous to photo-…
We investigate the interactions between ultracold alkali metal atoms and closed-shell atoms using electronic structure calculations on the prototype system Rb+Sr. There are molecular bound states that can be tuned across atomic thresholds with magnetic field, and there are previously neglected terms in the collision Hamiltonian that can produce zero-energy Feshbach resonances with significant widths. The largest effect comes from the interaction-induced variation of the Rb hyperfine coupling. The resonances may be used to form paramagnetic polar molecules if the magnetic field can be controlle…
We have studied interspecies scattering in an ultracold mixture of $^{87}$Rb and $^{133}$Cs atoms, both in their lowest-energy spin states. The three-body loss signatures of 30 incoming s- and p-wave magnetic Feshbach resonances over the range 0 to 667 G have been catalogued. Magnetic field modulation spectroscopy was used to observe molecular states bound by up to 2.5 MHz$\times h$. Magnetic moment spectroscopy along the magneto-association pathway from 197 to 182 G gives results consistent with the observed and calculated dependence of the binding energy on magnetic field strength. We have c…
Overlapping Feshbach resonances are commonly observed in experiments with ultracold atoms and can influence the molecule production process. We derive an effective approach to describe magnetoassociation in an external trap in the presence of multiple overlapping resonances. We study how the strength and shape of the trap affects the energy level structure and demonstrate the existence of a regime in which the conventional two-channel Landau-Zener description of the molecule production process breaks down.
The association process of Feshbach molecules is well described by a Landau-Zener (LZ) transition above the Fermi temperature, such that two-body physics dominates the dynamics. However, using $^6$Li atoms and the associated Feshbach resonance at $B_r=834.1$ G, we observe an enhancement of the atom-molecule coupling as the fermionic atoms reach degeneracy, demonstrating the importance of many-body coherence not captured by the conventional LZ model. In the experiment, we apply a linear association ramp ranging from adiabatic to non-equilibrium molecule association for various temperatures. We …
We investigate magnetically tunable Feshbach resonances between ultracold europium atoms and between europium and alkali-metal atoms using multichannel quantum scattering calculations. For ultracold gases of europium atoms both homonuclear $^{153}$Eu+$^{153}$Eu and heteronuclear $^{151}$Eu+$^{153}$Eu systems are studied. Calculations for mixtures of europium and alkali-metal atoms are carried out for prototype systems of $^{153}$Eu+$^{87}$Rb and $^{153}$Eu+$^7$Li. We analyze the prospects for the control of scattering properties, observation of quantum chaotic behavior, and magnetoassociation …
Interactions in a spin-polarized ultracold Fermi gas are governed by $p$-wave collisions and can be characterized by the $p$-wave scattering volume. Control of these collisions by Feshbach resonances is hampered by huge inelastic losses. Here, we suggest non-resonant light control of $p$-wave collisions, exploiting the anisotropic coupling of non-resonant light to the polarizability of the atoms. The $p$-wave scattering volume can be controlled by strong non-resonant light, in close analogy to the $s$-wave scattering length. For collision partners that are tightly trapped, the non-resonant lig…
We demonstrate the formation of a single NaCs molecule in an optical tweezer by magnetoassociation through an s-wave Feshbach resonance at 864.11(5)G. Starting from single atoms cooled to their motional ground states, we achieve conversion efficiencies of 47(1)%, and measure a molecular lifetime of 4.7(7)ms. By construction, the single molecules are predominantly (77(5)%) in the center-of-mass motional ground state of the tweezer. Furthermore, we produce a single p-wave molecule near 807G by first preparing one of the atoms with one quantum of motional excitation. Our creation of a single weak…
A frequency-stabilized light source emitting at 556 nm is realized by frequency-doubling a 1112-nm laser, which is phase-locked to a fiber-based optical frequency comb. The 1112-nm laser is either an ytterbium (Yb)-doped distributed feedback fiber laser or a master-slave laser system that uses an external cavity diode laser as a master laser. We have achieved the continuous frequency stabilization of the light source over a five-day period. With the light source, we have completed the second-stage magneto-optical trapping (MOT) of Yb atoms using the 1S0 - 3P1 intercombination transition. The t…
We investigate the Bose-Einstein condensation (BEC, superfluidity) of particle-hole pairs in ultracold Fermionic atoms with repulsive interactionsand arbitrary polarization, which are trapped within optical lattices. Near a Feshbach resonance, the dynamics of particle-hole pairs can be described by a hard-core Bose-Hubbard model. The insulator - superfluid and charge-density-wave (CDW) - superfluid phase transitions can be induced by decreasing and increasing the potential depths with controlling the trapping laser intensity, respectively. The parameter and polarization dependence of the criti…
We report on the observation and characterisation of an inelastic loss feature in collisions between ultracold Rb-85 |F=2, m_F=-2> atoms at a magnetic field of 220 G. Our apparatus creates ultracold Rb-85 clouds by sympathetic cooling with a Rb-87 reservoir, and can produce pure Rb-87 condensates of 10^6 atoms by a combination of evaporative cooling in a quadrupole-Ioffe magnetic trap and further evaporation in a weak, large-volume optical dipole trap. By combining Rb-85 and Rb-87 atoms collected in a dual-species magneto-optical trap and selectively evaporating the heavier isotope, we demonst…
In this study, we achieved magnetic control of reactive scattering in an ultracold mixture of $^{23}$Na atoms and $^{23}$Na$^{6}$Li molecules. In most molecular collisions, particles react or are lost near short range with unity probability, leading to the so-called universal rate. By contrast, the Na{+}NaLi system was shown to have only $\sim4\%$ loss probability in a fully spin-polarized state. By controlling the phase of the scattering wave function via a Feshbach resonance, we modified the loss rate by more than a factor of $100$, from far below to far above the universal limit. The result…
Simultaneous sub-Doppler laser cooling and optical trapping of bosonic $^{39}$K-$^{133}$Cs and $^{41}$K-$^{133}$Cs mixtures
Institute of Experimental Physics, University of Warsaw（华沙大学实验物理研究所）；Durham University（杜伦大学）；Stockholm University（斯德哥尔摩大学）；eleQtron GmbH（eleQtron有限公司）；Warsaw University of Technology（华沙理工大学）
We create fermionic dipolar $^{23}$Na$^6$Li molecules in their triplet ground state from an ultracold mixture of $^{23}$Na and $^6$Li. Using magneto-association across a narrow Feshbach resonance followed by a two-photon STIRAP transfer to the triplet ground state, we produce $3\,{\times}\,10^4$ ground state molecules in a spin-polarized state. We observe a lifetime of $4.6\,\text{s}$ in an isolated molecular sample, approaching the $p$-wave universal rate limit. Electron spin resonance spectroscopy of the triplet state was used to determine the hyperfine structure of this previously unobserve…
We employ collisions of individual atomic cesium (Cs) impurities with an ultracold rubidium (Rb) gas to probe atomic interaction with hyperfine- and Zeeman-state sensitivity. Controlling the Rb bath's internal state yields access to novel phenomena observed in inter-atomic spin-exchange. These can be tailored at ultra-low energies, owing to the excellent experimental control over all relevant energy scales. First, detecting spin-exchange dynamics in the Cs hyperfine state manifold, we resolve a series of previously unreported Feshbach resonances at magnetic fields below 300 mG, separated by en…
We report the Bose-Einstein condensation (BEC) of the most magnetic atom, dysprosium. The Dy BEC is the first for an open f-shell lanthanide (rare-earth) element and is produced via forced evaporation in a crossed optical dipole trap loaded by an unusual, blue-detuned and spin-polarized narrow-line magneto-optical trap. Nearly pure condensates of 1.5x10^4 164Dy atoms form below T = 30 nK. We observe that stable BEC formation depends on the relative angle of a small polarizing magnetic field to the axis of the oblate trap, a property of trapped condensates only expected in the strongly dipolar …
