Using flow visualizations in Couette geometry, we demonstrate the existence of Taylor-like vortices in the shear-banding flow of a giant micelles system. We show that vortices stacked along the vorticity direction develop concomitantly with interfacial undulations. These cellular structures are mainly localized in the induced band and their dynamics is fully correlated with that of the interface. As the control parameter increases, we observe a transition from a steady vortex flow to a state where pairs of vortices are continuously created and destroyed. Normal stress effects are discussed as potential mechanisms driving the three-dimensional flow.
We investigate theoretically shear banding in large amplitude oscillatory shear (LAOS) of polymers and wormlike micelles. In LAOStrain we find banding at low frequencies and sufficiently high strain rate amplitudes in fluids for which the underlying constitutive curve of shear stress as a function of shear rate is non-monotonic. This is the direct analogue of quasi steady state banding seen in slow strain rate sweeps along the flow curve. At higher frequencies and sufficiently high strain amplitudes we report a different but related phenomenon, which we call `elastic' shear banding. This is as…
In this work, we use flow visualization and rheometry techniques to study the dynamics and evolution of secondary flows in a model wormlike micellar solution sheared between concentric cylinders, i.e., in a Taylor-Couette (TC) cell. The wormlike micellar solution studied in this work contains cetyltrimethylammonium bromide (CTAB) and sodium salicylate (NaSal). This system can be shear banding and highly elastic, non-shear banding and moderately elastic, or nearly Newtonian as the temperature is varied over a narrow range. The effect of elasticity on transitions and instabilities is probed by c…
We use a hybrid method that combines the Multiparticle collision dynamics (MPCD) for solvent particles with the molecular dynamics for equilibrium polymers to simulate the shearing of the equilibrium polymers (or Wormlike micelles) at a mesoscopic length scale. The MPCD method incorporates the hydrodynamic interaction with the polymeric chains. We show successful implementation of the method on the model equilibrium polymers (or Wormlike micelles) and observe that the order of the Iso-Nem transition of the polymeric system is affected by the shear rate. Moreover, the chains of the equilibrium …
Using high-resolution confocal rheometry, we study the shear profiles of well-entangled DNA solutions under large amplitude oscillatory shear (LAOS) in a rectilinear planar shear cell. With increasing Weissenberg number (Wi), we observe successive transitions from normal Newtonian linear shear profiles to wall-slip dominant shear profiles and finally to shear-banding profiles at high Wi. To investigate the microscopic origin of the observed shear banding, we study the dynamics of micron-sized tracers embedded in DNA solutions. Surprisingly, tracer particles in the shear frame exhibit transient…
Many soft materials, including foams, dense emulsions, micro gel bead suspensions, star polymers, dense packing of surfactant onion micelles, and textured morphologies of liquid crystals, share the basic "glassy" features of structural disorder and metastability. These in turn give rise to several notable features in the low frequency shear rheology (deformation and flow properties) of these materials: in particular, the existence of a yield stress below which the material behaves like a solid, and above which it flows like a liquid. In the last decade, intense experimental activity has also r…
We investigate the effects of micellar entanglement number on the kinetics of shear banding flow formation in a Taylor-Couette flow. Three sets of wormlike micellar solutions, each set with a similar fluid elasticity and zero-shear-rate viscosity, but with varying entanglement densities, are studied under start-up of steady shear. Our experiments indicate that in the set with the low fluid elasticity, the transient shear banding flow is characterized by the formation of a transient flow reversal in a range of entanglement densities. Outside of this range, the transient flow reversal is not obs…
