用相对论Hartree-Fock方法和组态相互作用方法以及多体微扰理论计算了$^{205}$ Tl的宇称和时间不变性破坏电偶极矩。考虑了电子电偶极矩与内电场的相互作用以及标量-赝标电子-核子（T，P）奇相互作用的贡献。结果为$d(^{205}{\rm Tl})=-582(20) d_e$或$d(^{205}{\rm Tl})=-7.0(2)\times 10^{-18}C^{SP} e {\rm cm}$。解释的测量进行了讨论。$^{133}$ Cs的类似计算结果为$d(^{133}{\rm Cs})=124(4) d_e$或$d(^{133}{\rm Cs})=0.76(2)\times 10^{-18}C^{SP} e {\rm cm}$。
英文摘要：
Parity and time invariance violating electric dipole moment of $^{205}$Tl is calculated using the relativistic Hartree-Fock and configuration interaction methods and the many-body perturbation theory. Contributions from the interaction of the electron electric dipole moments with internal electric field and scalar-pseudoscalar electron-nucleon (T,P)-odd interaction are considered. The results are $d(^{205}{\rm Tl})=-582(20) d_e$ or $d(^{205}{\rm Tl})=-7.0(2)\times 10^{-18}C^{SP} e {\rm cm}$. Interpretation of the measurements are discussed. The results of similar calculations for $^{133}$Cs are $d(^{133}{\rm Cs})=124(4) d_e$ or $d(^{133}{\rm Cs})=0.76(2)\times 10^{-18}C^{SP} e {\rm cm}$.
We present state-of-the-art configuration interaction and coupled cluster calculations of the electron electric dipole moment, the nucleon-electron scalar-pseudoscalar, and the magnetic hyperfine interaction constants ($α_{d_e}, α_{C_S}, A_{||}$, respectively) for the thallium atomic ground state $^2P_{1/2}$. Our present best values are $α_{d_e} = -559 \pm 28$, $α_{C_S} = 6.77 \pm 0.34$ $[10^{-18} e$ cm$]$, and $A_{||} = 21172 \pm 1059$ [MHz]. These findings lead to a significant reduction of the theoretical uncertainties for ${\cal{P,T}}$-odd interaction constants but not to stronger constrai…
Comment on "Reappraisal of the Electric Dipole Moment Enhancement Factor for Thallium"
Nataraj { \em et al}（Phys. Rev. Lett. { \bf 106}，200403（2011））提供了T1的EDM增强因子的计算，其与先前最精确的计算不一致。作者声称，由于对高阶相关性的更完整处理，他们对TI EDM的计算是最准确的。在本说明中，我们认为这一主张没有足够的证据支持。Nataraj { \em et al}也对我们的计算给出了误导性的评论。我们解释了我们的方法并回复了Nataraj { \em et al}的评论。
We report high-precision measurements on the thallium fluoride $\tilde{J} = 1$ hyperfine manifold of the $B^3Π_1$ ($ν= 0$) state. This state is of special interest because it is central to an optical cycling scheme that is envisioned to play an important role in enhancing the sensitivity of the CeNTREX nuclear Schiff-moment experiment presently under construction. The measurements are made by monitoring the fluorescence induced by narrow-band laser excitation of a cryogenic molecular beam. We use a multipass arrangement of the laser beam to enhance fluorescence. When viewed with a camera, we c…
We report a measurement of the transition amplitude ratio $χ$ of an electric quadrupole ($E2$) to a magnetic dipole ($M1$) of the $6P_{1/2}\rightarrow6P_{3/2}$ transition in atomic thallium. We utilized the electromagnetically induced transparency (EIT) mechanism and the sideband-bridging technique to resolve the isotopic transitions and their hyperfine manifold. Our measurement gave $χ_{205}~=~0.2550(20)(7)$ for $^{205}$Tl, and $χ_{203}=0.2532(73)(7)$ for $^{203}$Tl, which was measured for the first time. Our result provides a reference point for the theoretical calculation of atomic structur…
We present relativistic many-body calculations of atomic and molecular Schiff-moment interaction constants including interelectron correlation effects using atomic Gaussian basis sets specifically optimized for the Schiff interaction. Our present best results employing a Gaussian nuclear density function are $α_{\text{SM}} = (0.364 \pm 0.025) \times 10^{-17} \frac{e \text{cm}}{e \text{fm}^3}$ for atomic $^{129}$Xe, $α_{\text{SM}} = (-2.40 \pm 0.24) \times 10^{-17} \frac{e \text{cm}}{e \text{fm}^3}$ for atomic $^{199}$Hg, and $W_{\text{SM}} = (39967\pm 3600)$ a.u. for the thallium nucleus in th…
We calculate the effect of the P, CP-odd electron-nucleon interaction on the electric dipole moment of the $^{199}$Hg atom by evaluating the nuclear spin matrix elements in terms of the nuclear shell model. It is found that the neutron spin matrix element of the $^{199}$Hg nucleus is $\langle Ψ|\, σ_{nz} | Ψ\rangle \approx -0.4$ with a dominant configuration of $p_{1/2}$ orbital neutron. We also derive constraints on the CP phases of Higgs-doublet models, supersymmetric models, and leptoquark models from the latest experimental limit $|d_{\rm Hg}| < 7.4 \times 10^{-30}e$ cm.
We report the calculation of the isovector CP-odd $πN$ interaction generated by the Weinberg operator, the CP violating three-gluon operator. This enables to restrict models which induce the operator by using experimental data of atomic electric dipole moment. The QCD sum rules are used to determine the matrix element required to assess the CP-odd $πN$ interactions. The relation between the Weinberg operator and the Hg and Xe EDMs is clarified, and the constraint on the Weinberg operator is obtained using the experimental data for the Hg EDM.
Electric dipole moments of Hg, Xe, Rn, Ra, Pu, and TlF induced by the nuclear Schiff moment and limits on time-reversal violating interactions
We have calculated the atomic electric dipole moments (EDMs) induced in ^{199}Hg, ^{129}Xe, ^{223}Rn, ^{225}Ra, and ^{239}Pu by their respective nuclear Schiff moments S. The results are (in units 10^{-17}S(e {fm}^{3})^{-1}e cm): d(^{199}Hg)=-2.8, d(^{129}Xe)=0.38, d(^{223}Rn)=3.3, d(^{225}Ra)=-8.5, d(^{239}Pu)=-11. We have also calculated corrections to the parity- and time-invariance-violating (P,T-odd) spin-axis interaction constant in TlF. These results are important for the interpretation of atomic and molecular experiments on EDMs in terms of fundamental P,T-odd parameters.
Postulating the existence of a fnite-mass mediator of T,P-odd coupling between atomic electrons and nucleons we consider its effect on permanent electric dipole moment (EDM) of diamagnetic atoms. We present both numerical and analytical analysis for such mediator-induced EDMs and compare it with EDM results for the conventional contact interaction. Based on this analysis we derive limits on coupling strengths and carrier masses from experimental limits on EDM of 199Hg atom.
Microscopic study of low-lying states in odd-mass nuclei for atomic electric dipole moment searches
School of Physics and Astronomy, Sun Yat-sen University（中山大学物理学院）；Guangdong Provincial Key Laboratory of Quantum Metrology and Sensing, Sun Yat-Sen University（中山大学广东省量子计量与传感重点实验室）
The effective electric field experienced by the unpaired electron in the ground state of PbF, which is a potential candidate in the search of electron electric dipole moment due to some special characteristics, is calculated using Z-vector method in the coupled cluster single- and double- excitation approximation with four component Dirac spinor. This is an important quantity to set the upper bound limit of the electron electric dipole moment. Further, we have calculated molecular dipole moment and parallel magnetic hyperfine structure constant (A$_\|$) of $^{207}$Pb in PbF to test the accurac…
The contribution of the CP violating three-gluon Weinberg operator, $\frac{1}{3!} w f^{abc} ε^{νραβ} G^a_{μν} G^b_{αβ} G^{c μ}_ρ$, to the atomic and nuclear EDMs is estimated using QCD sum rules. After calculating the transition matrix element between the pion and the vacuum through the Weinberg operator, we obtain the long-range CP-odd nuclear force by determining the isovector CP-odd pion-nucleon vertex, using chiral perturbation theory at NLO. The EDMs of $^{199}$Hg, $^{129}$Xe, $^{225}$Ra, $^2$H, and $^3$He are finally given including comprehensive uncertainty analysis. While the leading c…
Highly correlated pure {\it{ab initio}} relativistic configuration interaction theory is in the present paper applied to the calculation of the tensor-pseudotensor ${\cal{(P,T)}}$-violating nucleon-electron interaction constant in the electronic ground states of atomic mercury and radium. The final best obtained results are $R_T$(Hg) = $-4.43$\, [$10^{-20}$ $\left<σ_N\right>$ $e$ cm] and $R_T$(Ra) = $-15.0$\, [$10^{-20}$ $\left<σ_N\right>$ $e$ cm]. The accuracy of the employed electronic-structure models are confirmed by determining the static electric dipole polarizability $α_d$(Hg) = $35.7$ …
In the quest to find a favourable triatomic molecule for detecting electric dipole moment of an electron (eEDM), we identify mercury hydroxide (HgOH) as an extremely attractive candidate from both experimental and theoretical viewpoints. Our calculations show that there is a four-fold enhancement in the effective electric field of HgOH compared to the recently proposed ytterbium hydroxide (YbOH) [Phys. Rev. Lett. 119, 133002 (2017)] for eEDM measurement. Thus, in the (010) bending state associated with the electronic ground state, it could provide better sensitivity than YbOH from a theoretica…
Present limit on the electron electric dipole moment ($e$EDM) is based on the electron spin precession measurement. We propose an alternative approach - observation of the $\mathcal{P}$,$\mathcal{T}$-odd Faraday effect in an external electric field on atoms and molecules using cavity-enhanced polarimetric scheme in combination with molecular (atomic) beam crossing the cavity. Our calculations of the effective electric fields and theoretical simulation of the proposed experiment on Tl and Pb atoms, PbF, YbF, ThO, and YbOH show that the present limit on the $e$EDM can be improved by 6-7 orders o…
The LuOH$^+$ cation is a promising system to search for manifestations of time reversal and spatial parity violation effects. Such effects in LuOH$^+$ induced by the electron electric dipole moment $e$EDM and the scalar-pseudoscalar interaction of the nucleus with electrons, characterized by $k_s$ constant, in LuOH$^+$ are studied. The enhancement factors, polarization in the external electric field, hyperfine interaction, rovibrational structure are calculated. The study is required for the experiment preparation and extraction of the eEDM and ks values from experimental data.
It is demonstrated that the TaN molecule is the best candidate to search for T,P-violating nuclear magnetic quadrupole moment (MQM), it also looks promising to search for other T,P-odd effects. We report results of coupled-cluster calculations of T,P-odd effects in TaN produced by the Ta nucleus MQM, electron electric dipole moment (EDM), scalar$-$pseudoscalar nucleus$-$electron interactions, also of the molecule-axis hyperfine structure constant and dipole moment. Nuclear calculations of $^{181}$Ta MQM are performed to express the T,P-odd effect in terms of the strength constants of T,P-odd n…
Parity and time-reversal violating electric dipole moment (EDM) of $^{171}$Yb is calculated accounting for the electron correlation effects over the Dirac-Hartree-Fock (DHF) method in the relativistic Rayleigh-Schrödinger many-body perturbation theory, with the second (MBPT(2) method) and third order (MBPT(3) method) approximations, and two variants of all-order relativistic many-body approaches, in the random phase approximation (RPA) and coupled-cluster (CC) method with singles and doubles (CCSD method) framework. We consider electron-nucleus tensor-pseudotensor (T-PT) and nuclear Schiff mom…
We observe the direct excitation of pairs of Cs atoms from the ground state to molecular states correlating asymptotically to $ns\,n'f$ asymptotes. The molecular resonances are interpreted as originating from the dipole-quadrupole interaction between the $ns\,n'f$ pair states and close-by $np\,np$ asymptotes ($22\leq n \leq 32$). This interpretation is supported by Stark spectroscopy of the pair states and a detailed modeling of the interaction potentials. The dipole-quadrupole interaction mixes electronic states of opposite parity and thus requires a coupling between electronic and nuclear mo…
A Laboratory Search for a Long-Range T-odd, P-odd Interaction from Axion-Like Particles using Dual Species Nuclear Magnetic Resonance with Polarized Xe-129 and Xe-131 Gas
Recent relativistic coupled-cluster (RCC) calculations of electric dipole moments (EDMs) of diamagnetic atoms due to parity and time-reversal violating (P,T-odd) interactions, that are essential ingredients for probing new physics beyond the standard model of particle interactions, differ substantially from the previous theoretical results. It is therefore necessary to perform an independent test of the validity of these results. In view of this, the normal coupled-cluster (NCC) method has been extended to the relativistic regime to calculate the EDMs of atoms by simultaneously incorporating t…
The observation of electric dipole moments (EDMs) in atomic systems due to parity and time-reversal violating (P,T-odd) interactions can probe new physics beyond the standard model and also provide insights into the matter-antimatter asymmetry in the Universe. The EDMs of open-shell atomic systems are sensitive to the electron EDM and the P,T-odd scalar-pseudoscalar (S-PS) semi-leptonic interaction, but the dominant contributions to the EDMs of diamagnetic atoms come from the hadronic and tensor-pseudotensor (T-PT) semi-leptonic interactions. Several diamagnetic atoms like $^{129}$Xe, $^{171}$…
