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arXiv 0908.4365cond-mat.mes-hall
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金属负载单分子膜上的钴纳米团簇:基底对团簇形成动力学和磁性的影响

Cobalt nano-clusters on metal supported Xe monolayers: influence of the substrate on cluster formation kinetics and magnetism

V. Sessi, K. Kuhnke, A. Enders, J. Zhang, P. Bencok, S. Bornemann, J. Minár, H. Ebert, J. Honolka, K. Kern

摘要:

用变温扫描隧道显微镜研究了在80 ~ 150 K温度范围内,缓冲层辅助生长过程中Co在Ag(111)和Pt(111)衬底上亚单层覆盖层的生长动力学。结果表明,如果衬底层足够薄,则团簇-衬底间的相互作用可以控制在衬底缓冲层上的团簇形成。X射线磁性圆二色性的解释的显微镜结果的支持下,监测集群基板相互作用的影响,形成的磁矩和磁各向异性的Co纳米团簇在不同的生长阶段。{ \it Ab-initio}计算表明,团簇的磁性受界面各向异性的控制,导致Co在Pt(111)上的垂直磁化。限制和新的潜在的缓冲层辅助生长的纳米团簇制造进行了讨论。

英文摘要:

The growth dynamics of submonolayer coverages of Cobalt during buffer layer assisted growth on Ag(111) and Pt(111) substrates is investigated by variable temperature scanning tunneling microscopy in the temperature range between 80 and 150 Kelvin. It is found that attractive cluster-substrate interactions can govern the cluster formation on the Xe buffer layer, if the Xe layer is sufficiently thin. The interpretation of the microscopy results are supported by x-ray magnetic circular dichroism which monitors the effect of cluster-substrate interactions on the formation of magnetic moments and magnetic anisotropy of Co nanocluster during the different stages of growth. {\it Ab-initio} calculations show that the cluster magnetism is controlled by the interface anisotropy, leading to perpendicular magnetization for Co on Pt(111). Limits of and new potential for nanocluster fabrication by buffer layer assisted growth are discussed.

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