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arXiv 0907.4094cond-mat.supr-concond-mat.str-el
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BaMn2As2中磁序的性质

Nature of the Magnetic Order in BaMn2As2

Yogesh Singh, M. A. Green, Q. Huang, A. Kreyssig, R. J. McQueeney, D. C. Johnston, A. I. Goldman

摘要:

对BaMn_2As_2粉末样品在10 ~ 675 K温度范围内进行了中子衍射测量。这些测量结果表明,在低于Neel温度T_N = 625(1)K时,该化合物呈现出共线反铁磁有序。T = 10 K时有序磁矩μ = 3.88(4)μ B/Mn沿c轴取向,磁结构为G型,所有最近邻Mn磁矩反铁磁排列。有序矩的值表明Mn的氧化态是Mn^{2+},具有高自旋S = 5/2。μ的T依赖性表明,磁性转变是二阶性质。在对比密切相关的AFe 2As 2(A = Ca,Sr,Ba,Eu)化合物,没有观察到的BaMn 2As 2的磁有序状态的结构畸变。

英文摘要:

Neutron diffraction measurements have been performed on a powder sample of BaMn2As2 over the temperature T range from 10 K to 675 K. These measurements demonstrate that this compound exhibits collinear antiferromagnetic ordering below the Neel temperature T_N = 625(1) K. The ordered moment mu = 3.88(4) mu_B/Mn at T = 10 K is oriented along the c axis and the magnetic structure is G-type, with all nearest-neighbor Mn moments antiferromagnetically aligned. The value of the ordered moment indicates that the oxidation state of Mn is Mn^{2+} with a high spin S = 5/2. The T dependence of mu suggests that the magnetic transition is second-order in nature. In contrast to the closely related AFe2As2 (A = Ca, Sr, Ba, Eu) compounds, no structural distortion is observed in the magnetically ordered state of BaMn2As2.

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