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arXiv 0907.3107cond-mat.stat-mech
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二维紧致分形上半柔性高分子链临界指数的刚度依赖性

Stiffness dependence of critical exponents of semiflexible polymer chains situated on two-dimensional compact fractals

Ivan Zivic, Suncica Elezovic-Hadzic, Sava Milosevic

摘要:

利用精确的蒙特卡罗重整化群(MCRG)方法研究了半柔性高分子链在无限族平面填充(PF)分形上的行为。分形是紧凑的,也就是说,他们的分形维数$d_f$是等于2的所有成员的分形家庭所列举的奇数$b$($3\le b< \infty$)。对于链的刚度参数$s$的不同值,在PF分形上(对于$3\le b\le 9$),我们精确地计算临界指数$ν$(与聚合物链的均方端到端距离相关)和$γ$(与不同聚合物链的总数相关)。此外,我们计算$ν$和$γ$通过MCRG方法为$b$高达201。我们的研究结果表明,对于每一个特定的$b$,临界指数是刚度依赖的功能,在这样一种方式,刚性聚合物链(具有较小的值的$s$)显示放大的值的$ν$,和减少值的$γ$。另一方面,对于任何特定的$s$,临界指数$ν$单调减小,而临界指数$γ$单调增加,具有缩放参数$b$。我们反映了一个可能的相关性PF家庭的分形相同的问题上的经常欧几里德格的半柔性聚合物链的临界性。

英文摘要:

We present an exact and Monte Carlo renormalization group (MCRG) study of semiflexible polymer chains on an infinite family of the plane-filling (PF) fractals. The fractals are compact, that is, their fractal dimension $d_f$ is equal to 2 for all members of the fractal family enumerated by the odd integer $b$ ($3\le b< \infty$). For various values of stiffness parameter $s$ of the chain, on the PF fractals (for $3\le b\le 9$) we calculate exactly the critical exponents $ν$ (associated with the mean squared end-to-end distances of polymer chain) and $γ$ (associated with the total number of different polymer chains). In addition, we calculate $ν$ and $γ$ through the MCRG approach for $b$ up to 201. Our results show that, for each particular $b$, critical exponents are stiffness dependent functions, in such a way that the stiffer polymer chains (with smaller values of $s$) display enlarged values of $ν$, and diminished values of $γ$. On the other hand, for any specific $s$, the critical exponent $ν$ monotonically decreases, whereas the critical exponent $γ$ monotonically increases, with the scaling parameter $b$. We reflect on a possible relevance of the criticality of semiflexible polymer chains on the PF family of fractals to the same problem on the regular Euclidean lattices.

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