arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 0907.2815cond-mat.mes-hallcond-mat.mtrl-sci
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粒径对相互作用的La0 .67Sr0.33MnO3纳米颗粒磁性能的影响

Particle size effect on magnetic properties of interacting La0.67Sr0.33MnO3 nanoparticles

Ali Rostamnejadi, Hadi salamati, Parviz Kameli

摘要:

采用溶胶-凝胶法制备了平均粒径分别为13、16、18和21 nm的La0.67Sr0.33MnO3(LSMO)磁性纳米颗粒。采用Rietveld精修法和透射电子显微镜(TEM)对合成粉末的晶体结构和平均粒径进行了X射线衍射(XRD)分析。傅里叶变换红外(FTIR)透射光谱表明,拉伸和弯曲模式的煅烧温度的影响。在室温下进行了样品的直流磁化强度与磁场的关系。在不同频率和交流磁场下,通过测量样品的交流磁化率与温度的关系,研究了样品的磁动力学。在交流磁化率与温度的关系中观察到一个依赖于频率的峰,该峰由Vogel-Fulcher和临界慢化定律以及经验和参数很好地描述。用Vogel-Fulcher定律和临界慢化定律对实验数据进行拟合,得到了弛豫时间、特征温度、磁各向异性能、有效磁各向异性常数和临界指数zv。从Vogel-Fulcher定律得到的c1、c2、T0和t0值支持磁性纳米颗粒之间存在强相互作用。从临界慢化拟合得到的zv和t0值表明不同尺寸的LSMO纳米颗粒中存在超自旋玻璃行为。

英文摘要:

Magnetic nanoparticles of La0.67Sr0.33MnO3 (LSMO) manganite with mean particle sizes of 13, 16, 18 and 21 nm were prepared by the sol-gel method. The crystal structure and mean particle size of the synthesized powders were estimated by X-ray diffraction (XRD) analysis using rietveld refinement and transmission electron microscopy (TEM). Fourier transform infrared (FTIR) transmission spectroscopy revealed that stretching and bending modes are influenced by calcinations temperature. Dc magnetization versus magnetic field of the samples was carried out at room temperature. Magnetic dynamics of the samples was studied by the measurement of ac magnetic susceptibility versus temperature at different frequencies and ac magnetic fields. A frequency-dependent peak was observed in ac magnetic susceptibility versus temperature which is well described by Vogel-Fulcher and critical slowing down laws, and empirical and parameters. By fitting the experimental data with Vogel-Fulcher and critical slowing down laws, the relaxation time, characteristic temperature, magnetic anisotropy energy, effective magnetic anisotropy constant and critical exponent zv have been estimated. The obtained values of c1, c2, T0 and t0 from the Vogel-Fulcher law support of the presence of strong interaction between magnetic nanoparticles. The values of zv and t0 obtained from critical slowing down fit suggest the presence of superspin glass behavior in LSMO nanoparticles of different sizes.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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