We have shown that alloying a noble metal (gold) with another metal (cadmium), which can contribute two electrons per atom to a free electron gas, can significantly improve the metals optical properties in certain wavelength ranges and make them worse in the other parts of the spectrum. In particular, in the gold-cadmium alloy we have demonstrated a significant expansion of the spectral range of metallic reflectance to shorter wavelengths. The experimental results and the predictions of the first principles theory demonstrate an opportunity for the improvement and optimization of low-loss metals for nanoplasmonic and metamaterials applications.
Layered metal-dielectric metamaterials have filtering properties both in the frequency domain and in the spatial frequency domain. Engineering their spatial filtering response is a way of designing structures with specific diffraction properties for such applications as sub-diffraction imaging, supercollimation, or optical signal processing at the nanoscale. In this paper we review the recent progress in this field. We also present a numerical optimization framework for layered metamaterials, based on the use of evolutionary algorithms. A measure of similarity obtained using Hoelder's inequali…
Optical systems that respect Parity-Time (PT) symmetry can be realized with proper incorporation of gain/loss materials. However, due to the absence of magnetic response at optical frequencies, the wave impedance is defined entirely by their permittivity and, hence, the PT-symmetric character is controlled solely via their refractive index. Here, we show that the separate control of the wave impedance enabled by metamaterials can grant access to further tuning of the Exceptional Points, appearance of mixed phases (coexistence of PT-symmetric and PT-broken phases) and occurrence of phase re-ent…
Recent experiments have shown the viability of the metamaterial approach to dielectric response engineering for moderately enhancing the transition temperature, Tc, of a superconductor. In this report, we demonstrate the use of Al2O3-coated aluminium nanoparticles to form the recently proposed epsilon near zero (ENZ) core-shell metamaterial superconductor with a Tc that is three times that of pure aluminium. IR reflectivity measurements confirm the predicted metamaterial modification of the dielectric function thus demonstrating the efficacy of the ENZ metamaterial approach to Tc engineering. …
The interaction of light with matter has triggered the interest of scientists for long time. The area of plasmonics emerges in this context through the interaction of light with valence electrons in metals. The random phase approximation in the long wavelength limit is used for analytical investigation of plasmons in three-dimensional metals, in a two-dimensional electron gas and finally in the most famous two-dimensional semi-metal, namely graphene. We show that plasmons in bulk metals as well as in a two-dimensional electron gas originate from classical laws, whereas, quantum effects appear …
In this paper, we employ the novel design of the metamaterial half-wave plate by using the multiple layers of the metamaterials with some specific rotation angles. The rotation angles are given by composite pulse control which is the well-known quantum control technique. A big advantage of this method can analytically calculate the rotation angles and can be easily extended to the multiple layers. The more layers of the metamaterials can present more bandwidth of half-wave plate. In this paper, we present 1, 3, 5, 7 configurations of layers of a metamaterial half-wave plate and we demonstrate …
Flexible control of the modal confinement in silicon photonic waveguides is an appealing feature for many applications, including sensing and hybrid integration of active materials. In most cases, strip waveguides are the preferred solution to maximize the light interaction with the waveguide surroundings. However, the only two degrees of freedom in Si strip waveguides are the width and thickness, resulting in limited flexibility in evanescent field control. Here, we propose and demonstrate a new strategy that exploits metamaterial engineering of the waveguide core and cladding to control the …
Sensing lower molecular weight in a diluted solution using a label-free biosensor is challenging and requires a miniaturized plasmonic structure, e.g., a vertical Au nanorod (AuNR) array based metamaterials. The sensitivity of a sensor mainly depends on transducer properties and hence for instance, the AuNR array geometry requires optimization. Physical vapour deposition methods (e.g., sputtering and e-beam evaporation) require a vacuum environment to deposit Au, which is costly, time-consuming, and thickness-limited. On the other hand, chemical deposition, i.e., electroplating deposit higher …
Metamaterials comprising assemblies of dielectric resonators have attracted much attention due to their low intrinsic loss and isotropic optical response. In particular, metasurfaces made from silicon dielectric resonators have shown desirable behaviors such as efficient nonlinear optical conversion, spectral filtering and advanced wave-front engineering. To further explore the potential of dielectric metamaterials, we present all-dielectric metamaterials fabricated from epitaxially grown III-V semiconductors that can exploit the high second-order optical susceptibilities of III-V semiconducto…
Plasmonics is a rapidly emerging platform for quantum state engineering with the potential for building ultra-compact and hybrid optoelectronic devices. Recent experiments have shown that despite the presence of decoherence and loss, photon statistics and entanglement can be preserved in single plasmonic systems. This preserving ability should carry over to plasmonic metamaterials, whose properties are the result of many individual plasmonic systems acting collectively, and can be used to engineer optical states of light. Here, we report an experimental demonstration of quantum state filtering…
Multipolar electromagnetic phenomena in sub-wavelength resonators are at the heart of metamaterial science and technology. In this letter, we demonstrate selective and enhanced coupling to specific multipole resonances via beam engineering. We first derive an analytical method for determining the scattering and absorption of spherical nanoparticles (NPs) that depends only on the local electromagnetic field quantities within an inhomogeneous beam. Using this analytical technique, we demonstrate the ability to drastically manipulate the scattering properties of a spherical NP by varying illumina…
Supraparticles are coordinated assemblies of discrete nanoscale building blocks into complex and hierarchical colloidal superstructures. Holistic optical responses in such assemblies are not observed in an individual building block or in their bulk counterparts. Furthermore, subwavelength dimensions of the unit building blocks enable engraving optical metamaterials within the supraparticle, which thus far has been beyond the current pool of colloidal engineering. This can lead to effective optical features in a colloidal platform with unprecedented ability to tune the electromagnetic responses…
Structural colors are a result of the scattering of certain frequencies of the incident light on micro- or nanoscale features in a material. This is a quite different phenomenon from that of colors produced by absorption of different frequencies of the visible spectrum by pigments or dyes, which is the most common way of coloring used in our daily life. However, structural colors are more robust and can be engineered to span most of the visible spectrum without changing the base material, only its internal structure. They are abundant in nature, with examples as colorful as beetle shells and b…
Photoluminescence is a phenomenon of significant interest due to its wide range of technological applications in plasmonics, nanolasers, spasers, lasing spasers, loss compensation and gain in metamaterials, and luminescent media. Nanostructured materials are known to have very different luminescence characteristics to bulk samples or planar films. Here we show that by engineering a nanostructured meta-surface, we can choose the position of photoluminescence absorption and emission lines of thin gold films. The nanostructuring also aids to strong enhancement of the emission from gold, by a fact…
Metamaterials are fascinating tools that can structure not only surface plasmons and electromagnetic waves but also electromagnetic vacuum fluctuations. The possibility of shaping the quantum vacuum is a powerful concept that ultimately allows engineering the interaction between macroscopic surfaces and quantum emitters such as atoms, molecules or quantum dots. The long-range atom-surface interaction, known as Casimir-Polder interaction, is of fundamental importance in quantum electrodynamics but also attracts a significant interest for platforms that interface atoms with nanophotonic devices.…
Metamaterials are artificially engineered periodic structures with exceptional optical properties that are not found in conventional materials. However, this definition of metamaterials can be extended if we introduce a quantum degree of freedom by adding some quantum elements (e.g quantum dots, cold atoms, Josephson junctions, molecules). Quantum metamaterials can then be defined as artificially engineered nanostructures made up of quantum elements. Furthermore, they exhibit controllable quantum states, maintain quantum coherence for times much higher than the transversal time of the electrom…
Searching for natural materials exhibiting larger electron-electron interactions constitutes a traditional approach to high temperature superconductivity research. Very recently we pointed out that the newly developed field of electromagnetic metamaterials deals with the somewhat related task of dielectric response engineering on a sub-100 nm scale. Considerable enhancement of the electron-electron interaction may be expected in such metamaterial scenarios as in epsilon near zero (ENZ) and hyperbolic metamaterials. In both cases dielectric function may become small and negative in substantial …
Electromagnetic (EM) composites have stimulated tremendous fundamental and practical interests owing to their flexible electromagnetic properties and extensive potential engineering applications. Hence, it is necessary to systematically understand the physical mechanisms and design principles controlling EM composites. In this tutorial, we first provide an overview of the basic theory of electromagnetism about electromagnetic constitutive parameters that can represent the electromagnetic properties of materials. We show how this corpus allows a consistent construction of effective medium theor…
Mesoscopic photonic systems with tailored optical responses have great potential to open new frontiers in implantable biomedical devices. However, biocompatibility is typically a problem, as engineering of optical properties often calls for using toxic compounds and chemicals, unsuitable for in vivo applications. Here, we demonstrate a unique approach to biofriendly delivery of optical resonances. We show that the controllable infusion of gold nanoseeds into polycrystalline submicron vaterite spherulites gives rise to a variety of electric and magnetic Mie resonances, producing a tuneable meso…
Optical phase shifters are extensively used in integrated optics not only for telecom and datacom applications, but also for sensors and quantum computing. While various active solutions have been demonstrated, progress in passive phase shifters is still lacking. Here, we present a new type of ultra-broadband 90° phase shifter, which exploits the anisotropy and dispersion engineering in subwavelength metamaterial waveguides. Our Floquet-Bloch calculations predict a phase shift error below $\pm$1.7° over an unprecedented operation range from 1.35 $μ$m to 1.75 $μ$m, i.e. 400 nm bandwidth coverin…
In this review, we take an extensive look at the role that the principles of causality and passivity have played in various areas of physics and engineering, including in the modern field of metamaterials. The aim is not to provide a comprehensive list of references as that number would be in the thousands, but to review the major results and contributions which have animated these areas and to provide a unified framework from which to understand the developments in different fields. Towards these goals, we chart the early history of the field through its dual beginnings in the analysis of the…
National Laboratory of Solid State Microstructures, Nanjing University（南京大学固体微结构物理国家重点实验室）；School of Advanced Manufacturing Engineering, Nanjing University（南京工程学院（注：原文为Nanjing University，但通常Suzhou校区对应苏州大学或南京大学苏州研究院，此处严格按原文翻译）南京大学先进制造工程学院）；Institute of Theoretical Physics, Chinese Academy of Sciences（中国科学院理论物理研究所）；Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences（中国科学院金属研究所沈阳材料科学国家研究中心）；New Cornerstone Science Laboratory, Department of Physics, The University of Hong Kong（香港大学新基石科学学院物理学系）；School of Physical Science and Technology, Soochow University（苏州大学物理科学与技术学院）；School of Physical Sciences, University of Science and Technology of China（中国科学技术大学物理学院）；School of Physics Science and Engineering, Tongji University（同济大学物理科学与工程学院）；Suzhou Institute for Advanced Research, University of Science and Technology of China（中国科学技术大学苏州高等研究院）；National Laboratory of Solid State Microstructures and Department of Materials Science and Engineering, Nanjing University（南京大学固体微结构物理国家重点实验室和材料科学与工程系）
