The frustrated magnet clinoatacamite, $γ$-Cu$_2$(OH)$_3$Cl, is attracting a lot of interest after suggestions that at low temperature it forms an exotic quantum state termed a Valence Bond Solid (VBS) made from dimerised Cu$^{2+}$ ($S=1/2$) spins.\cite{Lee_clinoatacamite} Key to the arguments surrounding this proposal were suggestions that the kagomé planes in the magnetic pyrochlore lattice of clinoatacamite are only weakly coupled, causing the system to behave as a quasi-2-dimensional magnet. This was reasoned from the near 95$^\circ$ angles made at the bridging oxygens that mediate exchange between the Cu ions that link the kagomé planes.
Recent work pointed out that this exchange model is inappropriate for $γ$-Cu$_2$(OH)$_3$Cl, where the oxygen is present as a $μ_3$-OH.\cite{Wills_JPC} Further, it used symmetry calculations and neutron powder diffraction to show that the low temperature magnetic structure ($T<6$ K) was canted and involved significant spin ordering on all the Cu$^{2+}$ spins, which is incompatible with the interpretation of simultaneous VBS and Néel ordering. Correspondingly, clinoatacamite is best considered a distorted pyrochlore magnet. In this report we show detailed inelastic neutron scattering spectra and revisit the responses of this frustrated quantum magnet.
Competing Ordering Modes in the Distorted Quantum Kagome Material Clinoatacamite Cu$_2$Cl(OH)$_3$
Technische Universität Braunschweig（布伦瑞克工业大学）；Forschungszentrum Jülich GmbH（于利希有限公司研究中心）；Okayama University（冈山大学）；Helmholtz-Zentrum Berlin für Materialien und Energie GmbH（柏林亥姆霍兹材料与能源中心有限公司）；Institut Laue-Langevin（朗之万研究所）；Federal University of Parana（巴拉那联邦大学）；Université Paris-Saclay（巴黎萨克雷大学）；PSI Center for Neutron and Muon Sciences（瑞士保罗谢勒研究所中子与缪子科学中心）
Frustrated one-dimensional (1D) magnets are known as ideal playgrounds for new exotic quantum phenomena to emerge. We consider an elementary frustrated 1D system: the spin-$\frac{1}{2}$ ferromagnetic ($J_1$) Heisenberg chain with next-nearest-neighbor antiferromagnetic ($J_2$) interactions. On the basis of density-matrix renormalization group calculations we show the existence of a finite spin gap at $J_2/|J_1|>1/4$ and we find the ground state in this region to be a valence bond solid (VBS) with spin-singlet dimerization between third-neighbor sites. The VBS is the consequence of spontaneous …
We investigate the ground-state phase diagram of the frustrated transverse field Ising (TFI) model on the checkerboard lattice (CL), which consists of Néel, collinear, quantum paramagnet and plaquette-valence bond solid (VBS) phases. We implement a numerical simulation that is based on the recently developed unconstrained tree tensor network (TTN) ansatz, which systematically improves the accuracy over the conventional methods as it exploits the internal gauge selections. At the highly frustrated region ($J_2=J_1$), we observe a second order phase transition from plaquette-VBS state to paramag…
Barlowite, Cu$_{4}$(OH)$_{6}$FBr, has attracted much attention as the parent compound of a new series of quantum spin liquid candidates, Zn$_{x}$Cu$_{4-x}$(OH)$_{6}$FBr. While it is known to undergo a magnetic phase transition to a long-range ordered state at $T_{N} = 15$ K, there is still no consensus over either its nuclear or magnetic structures. Here, we use comprehensive powder neutron diffraction studies on deuterated samples of barlowite to demonstrate that the only space group consistent with the observed nuclear and magnetic diffraction at low-temperatures is the orthorhombic $Pnma$ s…
We investigate the ground state nature of the transverse field Ising model on the $J_1-J_2$ square lattice at the highly frustrated point $J_2/J_1=0.5$. At zero field, the model has an exponentially large degenerate classical ground state, which can be affected by quantum fluctuations for non-zero field toward a unique quantum ground state. We consider two types of quantum fluctuations, harmonic ones by using linear spin wave theory (LSWT) with single-spin flip excitations above a long range magnetically ordered background and anharmonic fluctuations, by employing a cluster-operator approach (…
In this paper, we demonstrate that in frustrated magnets when several conventional (i.e., symmetry-breaking) orders compete, and are "intertwined" by a Wess-Zumino-Witten (WZW) term, the possibility of spin liquid arises. The resulting spin liquid could have excitations which carry fractional spins and obey non-trivial self/mutual statistics. As a concrete example, we consider the case where the competing orders are the Néel and valence-bond solid (VBS) order on square lattice. Examining different scenarios of vortex condensation from the VBS side, we show that the intermediate phases, includi…
Optical Bragg, atom Bragg and cavity QED detections of quantum phases and excitation spectra of ultracold atoms in bipartite and frustrated optical lattices
We study effects of disorder (randomness) in a 2D square-lattice $S=1/2$ quantum spin system, the $J$-$Q$ model with a 6-spin interaction $Q$ supplementing the Heisenberg exchange $J$. In the absence of disorder the system hosts antiferromagnetic (AFM) and columnar valence-bond-solid (VBS) ground states. The VBS breaks $Z_4$ symmetry, and in the presence of arbitrarily weak disorder it forms domains. Using QMC simulations, we demonstrate two kinds of such disordered VBS states. Upon dilution, a removed site leaves a localized spin in the opposite sublattice. These spins form AFM order. For ran…
We study spin-$1/2$ chains with long-range power-law decaying unfrustrated (bipartite) Heisenberg exchange $J_r \propto r^{-α}$ and multi-spin interactions $Q$ favoring a valence-bond solid (VBS) ground state. Employing quantum Monte Carlo techniques and Lanczos diagonalization, we analyze order parameters and excited-state level crossings to characterize quantum states and phase transitions in the $(α,Q)$ plane. For weak $Q$ and sufficiently slowly decaying Heisenberg interactions (small $α$), the system has a long-range-ordered antiferromagnetic (AFM) ground state, and upon increasing $α$ th…
A quantum spin liquid (QSL) is a novel phase of matter with long-range entanglement where localized spins are highly correlated with the vanishing of magnetic order. Such exotic quantum states provide the opportunities to develop new theoretical frameworks for many-body physics and have the potential application in realizing robust quantum computations. Here we show that a gapless QSL can naturally emerge from a deconfined quantum critical point (DQCP), which is originally proposed to describe Landau forbidden continuous phase transition between antiferromagnetic (AFM) and valence-bond solid (…
Unifying Dirac Spin Liquids on Square and Shastry-Sutherland Lattices via Fermionic Deconfined Criticality
Universität Würzburg（维尔茨堡大学）；Flatiron Institute（平顿研究所）；Massachusetts Institute of Technology（麻省理工学院）；Indian Institute of Technology Madras（马德拉斯印度理工学院）；Harvard University（哈佛大学）
The ground state phase of spin-1/2 $J_1$-$J_2$ antiferromagnetic Heisenberg model on square lattice around the maximally frustrated regime ($J_2\sim 0.5J_1$) has been debated for decades. Here we study this model using the cluster update algorithm for tensor product states (TPSs). The ground state energies at finite sizes and in the thermodynamic limit (with finite size scaling) are in good agreement with exact diagonalization study. Through finite size scaling of the spin correlation function, we find the critical point $J_2^{c_1}=0.572(5)J_1$ and critical exponents $ν=0.50(8)$, $η_s=0.28(6)$…
The nature of the zero-temperature phase diagram of the spin-$1/2$ $J_1$-$J_2$ Heisenberg model on a square lattice has been debated in the past three decades, which may hold the key to understand high temperature superconductivity. By using the state-of-the-art tensor network method, specifically, the finite projected entangled pair state (PEPS) algorithm, to simulate the global phase diagram the $J_1$-$J_2$ Heisenberg model up to $24\times 24$ sites, we provide very solid evidences to show that the nature of the intermediate nonmagnetic phase is a gapless quantum spin liquid (QSL), whose spi…
