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arXiv 0906.1745cond-mat.str-el
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CeCo Ge $_{4}$中的反铁磁行为

Antiferromagnetic behavior in CeCo$_{9}$Ge$_{4}$

C. Gold, L. Peyker, E. -W. Scheidt, H. Michor, W. Scherer

摘要:

本文用$X$射线衍射、磁化率和比热测量等方法研究了新型三元金属间化合物\emph{R} Co $_{9}$ Ge $_{4}$(其中\emph{R} = La和Ce)。CeCo $_{9}$ Ge $_{4}$的空间群为${I}$ 4/ ${mcm}$,具有两种不同的磁性亚晶格共存的特征. Ce基亚晶格的有效磁矩接近Ce $^{3+}$ -离子的预期值,表现出磁有序基态,具有$T_{\mathrm{N}}=12.5$ K。然而,钴基亚晶格,由于巡回3 $d$电子表现出磁矩。Ce-亚晶格的磁比热贡献进行了讨论的共振能级模型暗示之间的相互作用的反铁磁相变和Kondo效应和一个潜在的肖特基异常表示分裂成三个双重退化的微观状态($Δ_1 = 69$ K,$Δ_2 = 133$ K)的晶体场能级计划。

英文摘要:

We investigate the novel intermetallic ternary compounds \emph{R}Co$_{9}$Ge$_{4}$ with \emph{R} = La and Ce by means of $X$-ray diffraction, susceptibility and specific heat measurements. CeCo$_{9}$Ge$_{4}$ crystallizes in the space group ${I}$ 4/ ${mcm}$ and is characterized by the coexistence of two different magnetic sublattices. The Ce-based sublattice, with an effective moment close to the expected value for a Ce$^{3+}$-ion, exhibits a magnetically ordered ground state with $T_{\mathrm{N}}=12.5$ K. The Co-based sublattice, however, exhibits magnetic moments due to itinerant 3$d$ electrons. The magnetic specific heat contribution of the Ce-sublattice is discussed in terms of a resonance-level model implying the interplay between an antiferromagnetic phase transition and the Kondo-effect and an underlying Schottky-anomaly indicating a crystal field level scheme splitting into three twofold degenerated micro states ($Δ_1 = 69$ K, $Δ_2 = 133$ K).

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