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arXiv 0902.0426physics.chem-ph
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通过相对论效应的均相金催化:水对丙炔的加成

Homogeneous Gold Catalysis through Relativistic Effects: Addition of Water to Propyne

Matthias Lein, A. Stephen K. Hashmi, Peter Schwerdtfeger

摘要:

在将水催化加成到丙炔中时,Au(III)催化剂在非相对论性条件下不稳定,并且解离成Au(I)化合物和Cl 2。这意味着催化循环中事件链的一个环节被打破,相对论很可能被视为Au(III)化合物是有效催化剂的原因。

英文摘要:

In the catalytic addition of water to propyne the Au(III) catalyst is not stable under non-relativistic conditions and dissociates into a Au(I) compound and Cl2. This implies that one link in the chain of events in the catalytic cycle is broken and relativity may well be seen as the reason why Au(III) compounds are effective catalysts.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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