We implement self-consistent microscopic calculations in order to describe out-of-equilibrium non-local transport in normal metal-superconductor-normal metal hybrid structures in the presence of a magnetic field and for arbitrary interface transparencies. A four terminal setup simulating usual experimental situations is described by means of a tight-binding model. We present results for the self-consistent order parameter and current profiles within the sample. These profiles illustrate a crossover from a quasi-equilibrium to a strong non-equilibrium situation when increasing the interface transparencies and the applied voltages. We analyze in detail the behavior of the non-local conductance in these two different regimes. While in quasi-equilibrium conditions this can be expressed as the difference between elastic cotunneling and crossed Andreev transmission coefficients, in a general situation additional contributions due to the voltage dependence of the self-consistent order parameter have to be taken into account. The present results provide a first step towards a self-consistent theory of non-local transport including non-equilibrium effects and describe qualitatively a recent experiment [Phys. Rev. Lett. 97, 237003 (2006)].
We study the transport properties of nanoscale superconducting (S) devices in which two superconducting electrodes are bridged by two parallel ferromagnetic (F) wires, forming an SFFS junction with a separation between the two wires less than the superconducting coherence length. This allows crossed Andreev reflection to take place. We find that the resistance as a function of temperature exhibits behavior reminiscent of the re-entrant effect and, at low temperatures and excitation energies below the superconducting gap, the resistance corresponding to antiparallel alignment of the magnetizati…
The Cooper-pair size (i.e., the BCS coherence length) in low-dimensional superconductors is dramatically modified by quantum-size effects. In particular, for nanowires made of conventional superconducting materials, we show that the coherence length exhibits size-dependent drops by two-three orders of magnitude and reaches values found in high-$T_c$ superconductors. This phenomenon is surprisingly similar to the well-known BCS-BEC crossover but with one important exception: it is driven by the transverse quantization of the electron spectrum rather than by the strength of the fermion-fermion i…
High temperature cuprate superconductors exhibit extremely local nanoscale phenomena and strong sensitivity to doping. While other experiments have looked at nanoscale interfaces between layers of different dopings, we focus on the interplay between naturally inhomogeneous nanoscale regions. Using scanning tunneling microscopy to carefully track the same region of the sample as a function of temperature, we show that regions with weak superconductivity can persist to elevated temperatures if bordered by regions of strong superconductivity. This suggests that it may be possible to increase the …
Our objective is to study the extreme and local electrodynamic properties of Niobium (Nb), and to relate these properties to specific defects that limit the ultimate RF performance of superconducting radio frequency (SRF) cavities made from Nb. Specifically, we wish to develop a microscopic measure of the response of Nb to RF magnetic fields up to the critical field (Hc) at microwave frequencies (few GHz), and at temperatures down to 4.2 K. In order to image the local electromagnetic response in the GHz frequency regime, a magnetic writer from a commercial hard drive is integrated into the nea…
The Tomasch effect (TE) is due to quasiparticle interference (QPI) as induced by a nonuniform superconducting order parameter, which results in oscillations in the density of states (DOS) at energies above the superconducting gap. Quantum confinement in nanoscale superconductors leads to an inhomogenerous distribution of the Cooper-pair condensate, which we found triggers the manifestation of a new TE. We investigate the electronic structure of the nanoscale superconductors by solving the Bogoliubov-de Gennes (BdG) equations self-consistently and obtain the TE determined by two types of proces…
Vortex matter in mesoscopic superconductors is known to be strongly affected by the geometry of the sample. Here we show that in nanoscale superconductors with coherence length comparable to the Fermi wavelength the shape resonances of the order parameter results in an additional contribution to the quantum topological confinement - leading to unconventional vortex configurations. Our Bogoliubov-de Gennes calculations in a square geometry reveal a plethora of asymmetric, giant multi-vortex, and vortex-antivortex structures, stable over a wide range of parameters and which are very different fr…
A Green functions approach is used to study superconductivity in nanofilms and nanowires. We show that the superconducting condensate results from the multimodal entanglement, or internal Josephson coupling, of the subcondensates associated with the manifold of Fermi surface subparts resulting from size-quantisation. This entanglement is of critical importance in these systems, since without it superconductivity would be extremely weak, if not completely negligible. Further, the multimodal character of the condensate generally results in multigap superconductivity, with great quantitative cons…
We solve the Bogoliubov-de Gennes equations self-consistently for d-wave superconductors with [110] surfaces. We find spontaneous breaking of time-reversal symmetry (TRS) caused by the spontaneous occurrence of a complex order parameter with an extended s-wave symmetry along the [110] surfaces. In the TRS-breaking phase, the d-wave order parameter itself becomes complex. We also show that vortex-antivortex pairs can appear along the [110] surfaces of nanoribbons. These pairs are detectable with surface sensitive probes.
We used oxygen ion irradiation to transfer the nanoscale pattern of a porous alumina mask into high- superconducting thin films. This causes a nanoscale spatial modulation of superconductivity and strongly affects the magneto-transport below, which shows a series of periodic oscillations reminiscent of the Little-Parks effect in superconducting wire networks. This irradiation technique could be extended to other oxide materials in order to induce ordered nanoscale phase segregation.
When the electron density of highly crystalline thin films is tuned by chemical doping or ionic liq- uid gating, interesting effects appear including unconventional superconductivity, sizeable spin-orbit coupling, competition with charge-density waves, and a debated low-temperature metallic state that seems to avoid the superconducting or insulating fate of standard two-dimensional electron systems. Some experiments also find a marked tendency to a negative electronic compressibility. We suggest that this indicates an inclination for electronic phase separation resulting in a nanoscopic inhomo…
The highest temperature superconductors are electronically inhomogeneous at the nanoscale, suggesting the existence of a local variable which could be harnessed to enhance the superconducting pairing. Here we report the relationship between local doping and local strain in the cuprate superconductor Bi$_2$Sr$_2$CaCu$_2$O$_{8+x}$. We use scanning tunneling microscopy to discover that the crucial oxygen dopants are periodically distributed, in correlation with local strain. Our picoscale investigation of the intra-unit-cell positions of all oxygen dopants provides essential structural input for …
The pinning of quantized flux lines, or vortices, in the mixed state is used to quantify the effect of impurities in iron-based superconductors (IBS). Disorder at two length scales is relevant in these materials. Strong flux pinning resulting from nm-scale heterogeneity of the superconducting properties leads to the very disordered vortex ensembles observed in the IBS, and to the pronounced maximum in the critical current density jc at low magnetic fields. Disorder at the atomic scale, most likely induced by the dopant atoms, leads to "weak collective pinning" and a magnetic field-independent …
We present microscopic, self-consistent calculations of the superconducting order parameter and pairing correlations near the interface of an $s$-wave superconductor and a three-dimensional topological insulator with spin-orbit coupling. We discuss the suppression of the order parameter by the topological insulator and show that the equal-time pair correlation functions in the triplet channel, induced by spin-flip scattering at the interface, are of $p_x\pm i p_y$ symmetry. We verify that the spectrum at sub-gap energies is well described by the Fu-Kane model. The sub-gap modes are viewed as i…
By performing experiments with thin-film resonators of NbSi, we elucidate a decoherence mechanism at work in disordered superconductors. This decoherence is caused by charged Two Level Systems (TLS) which couple to the conduction electrons in the BCS ground state; it does not involve any out-of-equilibrium quasiparticles, vortices, etc. Standard theories of mesoscopic disordered conductors enable making predictions regarding this mechanism, notably that decoherence should increase as the superconductor cross section decreases. Given the omnipresence of charged TLS in solid-state systems, this …
We use scanning tunneling microscopy to determine the surface structure and dopant distribution in Pr$_x$Ca$_{1-x}$Fe$_2$As$_2$, the highest-$T_c$ member of the 122 family of iron-based superconductors. We identify the cleaved surface termination by mapping the local tunneling barrier height, related to the work function. We image the individual Pr dopants responsible for superconductivity, and show that they do not cluster, but in fact repel each other at short length scales. We therefore suggest that the low volume fraction high-$T_c$ superconducting phase is unlikely to originate from Pr in…
We present a microscopic theory of dc Josephson current, based on the construction of a coherent temperature Green function in the tight-binding approximation, in junctions with multiband superconductors. This theory is applied to the junctions with multiband Fe-based superconductors (FeBS) described by anisotropic s-wave order parameter symmetries, which probably realized in FeBS. We confirm microscopically the previously suggested crucial experiment for determination of the type of the order parameter symmetry in FeBS.
The notion of spontaneous formation of an inhomogeneous superconducting state is at the heart of most theories attempting to understand the superconducting state in the presence of strong disorder. Using scanning tunneling spectroscopy and high resolution scanning transmission electron microscopy, we experimentally demonstrate that under the competing effects of strong homogeneous disorder and superconducting correlations, the superconducting state of a conventional superconductor, NbN, spontaneously segregates into domains. Tracking these domains as a function of temperature we observe that t…
Advanced synchrotron radiation focusing down to a size of 300 nm has been used to visualize nanoscale phase separation in the K0.8Fe1.6Se2 superconducting system using scanning nanofocus single-crystal X-ray diffraction. The results show an intrinsic phase separation in K0.8Fe1.6Se2 single crystals at T< 520 K, revealing coexistence of i) a magnetic phase characterized by an expanded lattice with superstructures due to Fe vacancy ordering and ii) a non-magnetic phase with an in-plane compressed lattice. The spatial distribution of the two phases at 300 K shows a frustrated or arrested nature o…
A characteristic feature of a superconductor made of multiple condensates is the possibility of the shape resonances in superconducting gaps. Shape resonances belong to class of Fano resonances in configuration interaction between open and closed scattering channels. The Shape resonances arise because of the exchange interaction, a Josephson-like term, for transfer of pairs between different condensates in different Fermi surface spots in the special cases where at least one Fermi surface is near a 2.5 Lifshitz topological transition. We show that tuning the shape resonances show first, the ga…
Using heterostructures that combine a large-polarization ferroelectric (BiFeO3) and a high-temperature superconductor (YBa2Cu3O7-δ), we demonstrate the modulation of the superconducting condensate at the nanoscale via ferroelectric field effects. Through this mechanism, a nanoscale pattern of normal regions that mimics the ferroelectric domain structure can be created in the superconductor. This yields an energy landscape for magnetic flux quanta and, in turn, couples the local ferroelectric polarization to the local magnetic induction. We show that this form of magnetoelectric coupling, toget…
Motivated by the recent experiment of Wang et al. [Nature Physics 6, 389 (2010)], who observed a highly unusual transport behavior of ferromagnetic Cobalt nanowires proximity-coupled to superconducting electrodes, we study proximity effect and temperature-dependent transport in such a mesoscopic hybrid structure. It is assumed that the asymmetry in the tunneling barrier gives rise to the Rashba spin-orbit-coupling in the barrier that enables induced p-wave superconductivity in the ferromagnet to exist. We first develop a microscopic theory of Andreev scattering at the spin-orbit-coupled interf…
Square arrays of sub-micrometer columnar defects in thin YBa$_{2}$Cu$_{3}$O$_{7-δ}$ (YBCO) films with spacings down to 300 nm have been fabricated by a He ion beam projection technique. Pronounced peaks in the critical current and corresponding minima in the resistance demonstrate the commensurate arrangement of flux quanta with the artificial pinning landscape, despite the strong intrinsic pinning in epitaxial YBCO films. Whereas these vortex matching signatures are exactly at predicted values in field-cooled experiments, they are displaced in zero-field cooled, magnetic-field ramped experime…
Recent experiments on disordered superconductors find that the superfluid density $n_s(T)$ decreases dramatically and characteristically with disorder, differently from what is expected for a mean order parameter field or BCS, amplitude only, picture for the superconductor. We describe here a new microscopic free energy functional which explicitly describes its dependence on both the amplitude and phase of superconducting order, in a gauge invariant manner. We use this here in an approximation of noninteracting phase fluctuations (Gaussian or harmonic approximation) to obtain $n_s(T)$ in the p…
The current density in a superconductor with turnarounds or constrictions is non-uniform due to a geometrical current crowding effect. This effect reduces the critical current in the superconducting structure compared to a straight segment and is of importance when designing superconducting devices. We investigate the current crowding effect in numerical simulations within the generalized time-dependent Ginzburg-Landau (GTDGL) model. The results are validated experimentally by measuring the magnetic field dependence of the critical current in superconducting nanowire structures, similar to tho…
In semiconductor electronics, the field-effect refers to the control of electrical conductivity in nanoscale devices, which underpins the field-effect transistor, one of the cornerstones of present-day semiconductor technology. The effect is enabled by the penetration of the electric field far into a weakly doped semiconductor, whose charge density is not sufficient to screen the field. On the contrary, the charge density in metals and superconductors is so large that the field decays exponentially from the surface and can penetrate only a short distance into the material. Hence, the field-eff…
We microscopically examine the intergrain Josephson current in iron-pnictide superconductors in order to solve the puzzle of why the intergrain current is much lower than the intragrain one. The theory predicts that the intergrain Josephson current is significantly reduced by the $\pm$s-wave symmetry when the incoherent tunneling becomes predominant and the density of states and the gap amplitude between two bands are identical. We find in such a situation that the temperature dependence of the intergrain Josephson current shows an anomalously flat curve over a wide temperature range. Finally,…
We have found a quantitative connection between the evolution of the inhomogeneous nanoscale electronic gaps (INSEG) state detected in Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$ by scanning tunneling microscopy/spectroscopy (STM/S) and the two universal, the upper and the lower, pseudogaps in high-temperature cuprate superconductors (HTCS). When the doping and temperature dependent INSEG map were analyzed by using our proposed hole-scale, we find that the two pseudogaps are connected to two specific coverages of the CuO$_2$ plane by INSEG: the 50\% and 100\% coverages of the CuO$_2$ planes by INSEG corresp…
Using the standard Bardeen-Cooper-Schrieffer (BCS) theory, we revise microscopic derivation of the superconductor-insulator boundary conditions for the Ginzburg-Landau (GL) model. We obtain a negative contribution to free energy in the form of surface integral. Boundary conditions for the conventional superconductor have the form $\textbf{n} \cdot \nabla ψ= \text{const} ψ$. These are shown to follow from considering the order parameter reflected in the boundary. The boundary conditions are also derived for more general GL models with higher-order derivatives and pair-density-wave states. It sh…
A procedure to derive the Ginzburg-Landau (GL) theory from the multiband BCS Hamiltonian is developed in a general case with an arbitrary number of bands and arbitrary interaction matrix. It combines the standard Gor'kov truncation and a subsequent reconstruction in order to match accuracies of the obtained terms. This reconstruction recovers the phenomenological GL theory as obtained from the Landau model of phase transitions but offers explicit microscopic expressions for the relevant parameters. Detailed calculations are presented for a three-band system treated as a prototype multiband sup…
Vortices play a crucial role in determining the properties of superconductors as well as their applications. Therefore, characterization and manipulation of vortices, especially at the single vortex level, is of great importance. Among many techniques to study single vortices, scanning tunneling microscopy (STM) stands out as a powerful tool, due to its ability to detect the local electronic states and high spatial resolution. However, local control of superconductivity as well as the manipulation of individual vortices with the STM tip is still lacking. Here we report a new function of the ST…
