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arXiv 0810.0397cond-mat.str-el
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相互作用极化子的跳跃动力学

Hopping dynamics of interacting polarons

S. Ciuchi, S. Fratini

摘要:

我们推导了一个有效的团簇模型来研究相互作用的小极化子的输运性质。我们提出了一种解耦方案,其中任何给定粒子的跳跃动力学是通过明确分离出其环境的自由度来确定的,这些自由度被视为统计浴。这里开发的一般腔方法表明,载流子之间的长程库仑排斥导致电输运的热激活势垒的净增加,因此载流子迁移率的相当大的减少。基于已知的二维和三维相互作用液体的关联函数,提供了这种效应的平均场计算。目前的理论给出了一个自然的解释最近的实验中进行的有机场效应晶体管与高度极化的栅极负离子,并可能在其他类别的极化系统,如掺杂的过渡金属氧化物中找到应用。

英文摘要:

We derive an effective cluster model to address the transport properties of mutually interacting small polarons. We propose a decoupling scheme where the hopping dynamics of any given particle is determined by separating out explicitly the degrees of freedom of its environment, which are treated as a statistical bath. The general cavity method developed here shows that the long-range Coulomb repulsion between the carriers leads to a net increase of the thermal activation barrier for electrical transport, and hence to a sizable reduction of the carrier mobility. A mean-field calculation of this effect is provided, based on the known correlation functions of the interacting liquid in two and three dimensions. The present theory gives a natural explanation of recent experiments performed in organic field-effect transistors with highly polarizable gate dielectrics, and might well find application in other classes of polaronic systems such as doped transition-metal oxides.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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