The Casimir-Polder interaction of an atom with a metallic wall is investigated in the framework of the Lifshitz theory. It is demonstrated that in some temperature (separation) region the Casimir-Polder entropy takes negative values and goes to zero when the temperature vanishes. This result is obtained both for an ideal metal wall and for real metal walls. Simple analytical representations for the Casimir-Polder free energy and force are also obtained. These results are used to make a comparison between the phenomenological potential used in the theoretical description of quantum reflection and exact atom-wall interaction energy, as given by the Lifshitz theory. Computations are performed for the atom of metastable He${}^{\ast}$ interacting with metal (Au) and dielectric (Si) walls. It is shown that the relative differences between the exact and phenomenological interaction energies are smaller in the case of a metallic wall. This is explained by the effect of negative entropy which occurs only for a metal wall. More accurate atom-wall interaction energies computed here can be used for the interpretation of measurement data in the experiments on quantum reflection.
Problems in the Lifshitz theory of atom-wall interaction arise when the dc conductivity of dielectric wall is included into the model of the dielectric response. We review the low-temperature behavior of the free energy and entropy of dispersion interaction for both dielectric and metallic walls. Consistency of the obtained results with thermodynamics and experimental data is analyzed. Recent attempts to include the screening effects and diffusion currents into the Lifshitz theory are considered. It is shown that this leads to the violation of the Nernst heat theorem for wide classes of wall m…
We extend our previous work on the electromagnetic Casimir-Lifshitz interaction between two bodies when one is contained within the other. We focus on the fluctuation-induced pressure acting on the cavity wall, which is assumed to be spherical. This pressure can be positive or negative depending on the response functions describing the bodies and the medium filling the cavity. However, we find that, under general hypotheses, the sign is independent of the geometry of the configuration. This result is based on the representation of the Casimir-Lifshitz energy in terms of transition operators. I…
The Casimir effect, the dispersion force attracting neutral objects to each other, may be understood in terms of multiple scattering of light between the interacting bodies. We explore the simple model in which the bodies are assumed to possess reflection coefficients independent of the energy and angle of incidence of an impinging field and show how a multitude of information can be extracted within the geometry of two parallel plates. The full thermal behaviour of the model is found and we discuss how non-analytic behaviour emerges in the combined limits of zero temperature and perfect refle…
Lifshitz-type formulas are obtained for the van der Waals and Casimir interaction between graphene and a material plate, graphene and an atom or a molecule, and between a single-wall carbon nanotube and a plate. The reflection properties of electromagnetic oscillations on graphene are governed by the specific boundary conditions imposed on the infinitely thin positively charged plasma sheet, carrying a continuous fluid with some mass and charge density. The obtained formulas are applied to graphene interacting with Au and Si plates, to hydrogen atoms and molecules interacting with graphene, an…
Liouville transformations map in a rigorous manner one Schrödinger equation into another, with a changed scattering potential. They are used here to transform quantum reflection of an atom on an attractive well into reflection of the atom on a repulsive wall. While the scattering properties are preserved, the corresponding semiclassical descriptions are completely different. A quantitative evaluation of quantum reflection probabilities is deduced from this method.
Reflection of a normal incident matter wave by a perfectly reflecting wall moving with a constant velocity is investigated. A surprising phenomenon is found-that if the the wall moves faster than the phase velocity of the incident wave, both the reflected and incident waves propagate in the same direction. This counter-intuitive result is an example which shows that common sense is not always credible when one deals with quantum problems.
We develop a new theory for Casimir-Lifshitz and Casimir-Polder interactions with semiconductor surfaces that takes into account charge drift in the bulk material. The corresponding frequency-dependent dispersion relations describe a crossover between Lifshitz results for dielectrics and for good conductors. In the quasi-static limit, our calculated reflection amplitudes coincide with those recently computed to account for Debye screening in the thermal Lifshitz force with conducting surfaces with small density of carriers.
Recently D. A. R. Dalvit and S. K. Lamoreaux arXiv:0805.1676 [Phys. Rev. Lett. v.101, 163203 (2008)] suggested the modification of the reflection coefficients in the Lifshitz theory taking into account the screening effects and diffusion currents. We demonstrate that the suggested modification is thermodynamically and experimentally inconsistent.
We show that the quantum reflection coefficient of ultracold heavy atoms scattering off a dielectric surface can be tuned in a wide range by suitable choice of surface and environment temperatures. This effect results from a temperature dependent long-range repulsive part of the van der Waals-Casimir-Polder-Lifshitz atom-surface interaction potential.
The applicability of the Lifshitz formula is discussed to the case of two thick parallel plates made of real metal. The usual description of the zero-point vacuum oscillations on the background of the frequency-dependent dielectric permittivity is shown to be in contradiction with thermodynamics. Instead, the Lifshitz formula for the Casimir free energy should be reformulated in terms of the reflection coefficients containing the surface impedance instead of the dielectric permittivity. This approach is presently confirmed experimentally by precision measurements of the van der Waals and Casim…
We explain why a system of cold $^{85}Rb$ atoms at temperatures of the order $T\approx 7.78\times 10^{-5}$ K and below, but not too low to lie in the quantum reflection regime, should be automatically repelled from the surface of a conductor without the need of an evanescent field, as in a typical atom mirror, to counteract the van der Waals attraction. The repulsive potential arises naturally outside the conductor and is effective at distances from the conductor surface of about 400nm, intermediate between the van der Waals and the Casimir-Polder regions of variation. We propose that such a f…
We present a study of atom-wall interactions in non-relativistic quantum electrodynamics by functional integral methods. The Feynman-Kac path integral representation is generalized to the case when the particle interacts with a radiation field, providing an additional effective potential that contains all the interactions induced by the field. We show how one can retrieve the standard van der Waals, Casimir-Polder and classical Lifshiftz forces in this formalism for an atom in its ground state. Moreover, when electrostatic interactions are screened in the medium, we find low temperature correc…
The Lifshitz-type formulas for the free energy and Casimir-Polder force acting between an atom possessing a permanent magnetic moment and a wall made of different materials are derived. Simple model allowing analytic results is considered where the atomic magnetic susceptibility is frequency-independent and wall is made of ideal metal. Numerical computations of the Casimir-Polder force are performed for H atom interacting with walls made of ideal metal, nonmagnetic (Au) and ferromagnetic (Fe) metals and of ferromagnetic dielectric. It is shown that for the first three wall materials the inclus…
We derive an expression for the Casimir force between slabs with arbitrary dielectric properties characterized by their reflection coefficients. The formalism presented here is applicable to media with a local or a non-local dielectric response, an infinite or a finite width, inhomogeneous dissipative, etc. Our results reduce to the Lifshitz formula for the force between semi-infinite dielectric slabs by replacing the reflection coefficients by the Fresnel amplitudes.
We provide a Quantum Field Theory derivation of Lifshitz formula for the Casimir force due to a fluctuating real scalar field in $d+1$ dimensions. The field is coupled to two imperfect, thick, plane mirrors, which are modeled by background potentials localized on their positions. The derivation proceeds from the calculation of the vacuum energy in the Euclidean version of the system, reducing the problem to the evaluation of a functional determinant. The latter is written, via Gelfand-Yaglom's formula, in terms of functions depending on the structure of the potential describing each mirror; th…
Based on the theory of macroscopic quantum electrodynamics, we generalize the expression of the Casimir force for nonreciprocal media. The essential ingredient of this result is the Green's tensor between two nonreciprocal semi-infinite slabs including a reflexion matrix with four coefficients that mixes optical polarizations. This Green's tensor does not obey Lorentz's reciprocity and thus violates time-reversal symmetry. The general result for the Casimir force is analyzed in the retarded and nonretarded limits, concentrating on the influences arising from reflections with or without change …
The thermal free energy and pressure of dispersion interaction between two graphene sheets described by the Dirac model are calculated using the Lifshitz formula with reflection coefficients expressed via the polarization tensor. The obtained results for a pristine graphene are found to be in agreement with computations using Coulomb coupling between density fluctuations. For a graphene with nonzero mass gap parameter a qualitatively different behavior for the free energy and pressure is obtained. The Lifshitz formula with reflection coefficients expressed via the polarization tensor is used a…
Mainly on nano-scale, but maybe not exclusively, it can be imagined a spontaneous charge disjunction inside certain media due to the fluctuations, collisions, wall effects, radiation or/and other presently unknown interactions. The repulsive Casimir-Lifshitz force may be also a good candidate as a source of this kind of phenomenon. To cover this assumption mathematically an additional term should appear in the Maxwell equations. As a consequence of this term, similar Klein-Gordon equations with a negative mass term will be obtained for the electric and magnetic fields. These equations may have…
The Lifshitz-type formulas describing the free energy and the force of the van der Waals interaction between an atom (molecule) and a single-wall carbon nanotube are obtained. The single-wall nanotube is considered as a cylindrical sheet carrying a two-dimensional free electron gas with appropriate boundary conditions on the electromagnetic field. The obtained formulas are used to calculate the van der Waals free energy and force between a hydrogen atom (molecule) and single-wall carbon nanotubes of different radia. Comparison studies of the van der Waals interaction of hydrogen atoms with sin…
We theoretically demonstrate that an external magnetic field can be used to control quantum reflection of matter waves in graphene due to its extraordinary magneto-optical properties. We calculate the quantum reflection probabilities in graphene for three experimentally relevant atomic species (He, Na, and Rb) using the full Casimir-Polder potential computed by Lifshitz formula valid at all distance regimes, going beyond the traditional approach to quantum reflection, based on power law potentials, which are known to be valid only in the short distance (non-retarded van der Waals) or in the la…
We theoretically investigate the quantum reflection of different atoms by two-dimensional (2D) materials of the graphene family (silicene, germanene, and stanene), subjected to an external electric field and circularly polarized light. By using Lifshitz theory to compute the Casimir-Polder potential, which ensures that our predictions apply to all regimes of atom-2D surface distances, we demonstrate that the quantum reflection probability exhibits distinctive, unambiguous signatures of topological phase transitions that occur in 2D materials. We also show that the quantum reflection probabilit…
The Casimir Force between Two Graphene Sheets: 2D Fresnel Reflection Coefficients, Contributions of Different Polarizations, and the Role of Evanescent Waves
A general theory of photon-mediated energy and momentum transfer in N-body planar systems out of thermal equilibrium is introduced. It is based on the combination of the scattering theory and the fluctuational-electrodynamics approach in many-body systems. By making a Landauer-like formulation of the heat transfer problem, explicit formulas for the energy transmission coefficients between two distinct slabs as well as the self-coupling coefficients are derived and expressed in terms of the reflection and transmission coefficients of the single bodies. We also show how to calculate local equili…
We calculate the interaction energy and force between atoms and molecules and single-walled carbon nanotubes described by the Dirac model of graphene. For this purpose the Lifshitz-type formulas adapted for the case of cylindrical geometry with the help of the proximity force approximation are used. The results obtained are compared with those derived from the hydrodymanic model of graphene. Numerical computations are performed for hydrogen atoms and molecules. It is shown that the Dirac model leads to larger values of the van der Waals force than the hydrodynamic model. For a hydrogen molecul…
The recent investigation of chains of Rydberg atoms has brought back the problem of commensurate-incommensurate transitions into the focus of current research. In 2D classical systems, or in 1D quantum systems, the commensurate melting of a period-p phase with p larger than 4 is known to take place through an intermediate floating phase where correlations between domain walls or particles decay only as a power law, but when p is equal to 3 or 4, it has been argued by Huse and Fisher that the transition could also be direct and continuous in a non-conformal chiral universality class with a dyna…
We study quantum reflection of antihydrogen atoms from nanoporous media due to the Casimir-Polder (CP) potential. Using a simple effective medium model, we show a dramatic increase of the probability of quantum reflection of antihydrogen atoms if the porosity of the medium increases. We discuss the limiting case of reflections at small energies, which have interesting applications for trapping and guiding antihydrogen using material walls.
We compare the experimental data of the first measurement of a temperature dependence of the Casimir-Polder force by Obrecht et al. [Phys. Rev. Lett. {\bf 98}, 063201 (2007)] with the theory taking into account small, but physically real, static conductivity of the dielectric substrate. The theory is found to be inconsistent with the data. The conclusion is drawn that the conductivity of dielectric materials should not be included in the model of the dielectric response in the Lifshitz theory. This conclusion obtained from the long separation measurement is consistent with related but differen…
