Spin-polarized current through an Al nanoparticle in tunnel contact with two ferromagnets is measured as a function of the direction of the applied magnetic field. The nanoparticle filters the spin of injected electrons along a direction specified by the magnetic field. The characteristic field scale for the filtering corresponds to a lower limit of $8ns$ for the spin-dephasing time. Spin polarized current versus applied voltage increases stepwise, confirming that the spin relaxation time is long only in the ground state and the low-lying excited states of the nanoparticle.
Aluminum-oxygen reaction is important in many highly energetic, high pressure generating systems. Recent experiments with nanostructured thermites suggest that oxidation of aluminum nanoparticles occurs in a few microseconds. Such rapid reaction cannot be explained by a conventional diffusion-based mechanism. We present a rapid oxidation model of a spherical aluminum nanoparticle, using Cabrera-Mott moving boundary mechanism, and taking self-heating into account. In our model, electric potential solves the nonlinear Poisson equation. In contrast with the Coulomb potential, a "double-layer" typ…
Numerous applications of nanotechnologies rely on the wide availability of high-quality crystalline nanoparticles (NPs). Although the chemical synthesis of noble metal nanoparticles (gold and silver) is well mastered, pushing the optical response of metallic nanoparticles towards the ultraviolet requires other materials, such as aluminum. Although a few demonstrations of chemical synthesis of Al nanoparticles have been reported so far, an elaboration path allowing for a wide range of NP size that is compatible with mass production has yet to be demonstrated. In this article, we report on the p…
Aluminum oxide nanoparticles are increasingly sought in numerous technological applications. However, as the nanoparticles grow during the synthesis, two phase transitions occur. At the nanoscale, numerical simulation of the stability of the alumina phases requires the use of empirical potentials that are reliable over a large range of system sizes going from a few atoms to several hundred thousand atoms. In this work, we confronted four different empirical potentials that are currently employed for bulk alumina. We found that only two of them are correct at the molecular level when compared t…
Plasmonic nanocrystals with hot spots are able to localize optical energy in small spaces. In such physical systems, near-field interactions between molecules and plasmons can become especially strong. This paper considers the case of a nanoparticle dimer and a chiral biomolecule. In our model, a chiral molecule is placed in the gap between two plasmonic nanoparticles, where the electromagnetic hot spot occurs. Since many important biomolecules have optical transitions in the UV, we consider the case of Aluminum nanoparticles, as they offer strong electromagnetic enhancements in the blue and U…
A model describing spin-polarized current via discrete energy levels of a metallic nanoparticle, which has strongly asymmetric tunnel contacts to two ferromagnetic leads, is presented. In absence of spin-relaxation, the model leads to a spin-accumulation in the nanoparticle, a difference ($Δμ$) between the chemical potentials of spin-up and spin-down electrons, proportional to the current and the Julliere's tunnel magnetoresistance. Taking into account an energy dependent spin-relaxation rate $Ω(ω)$, $Δμ$ as a function of bias voltage ($V$) exhibits a crossover from linear to a much weaker dep…
Hot electrons and holes generated from the decay of localized surface plasmons (LSPs) in aluminum nanostructures have significant potential for applications in photocatalysis, photodetection and other optoelectronic devices. Here, we present a theoretical study of hot-carrier generation in aluminum nanospheres using a recently developed modelling approach that combines a solution of the macroscopic Maxwell equation with large-scale atomistic tight-binding simulations. Different from standard plasmonic metals, such as gold or silver, we find that the energetic distribution of hot electrons and …
The presence of spin-orbit scattering within an aluminum nanoparticle affects measurements of the discrete energy levels within the particle by (1) reducing the effective g-factor below the free-electron value of 2, (2) causing avoided crossings as a function of magnetic field between predominantly-spin-up and predominantly-spin-down levels, and (3) introducing magnetic-field-dependent changes in the amount of current transported by the tunneling resonances. All three effects can be understood in a unified fashion by considering a simple Hamiltonian. Spin-orbit scattering from 4% gold impuriti…
We investigate the magnetization dynamics of a conducting magnetic nanoparticle weakly coupled to source and drain electrodes, under the assumption that all relaxation comes from exchange of electrons with the electrodes. The magnetization dynamics is characterized by a relaxation time $t_1$, which strongly depends on temperature, bias voltage, and gate voltage. While a direct measure of a nanoparticle magnetization might be difficult, we find that $t_1$ can be determined through a time resolved transport measurement. For a suitable choice of gate voltage and bias voltage, the magnetization pe…
We consider a simple cubic array of metallic nanoparticles supporting extended collective plasmons that arise from the near-field dipolar interaction between localized surface plasmons in each nanoparticle. We develop a fully analytical quantum theory of the strong-coupling regime between these collective plasmons and photons resulting in plasmon polaritons in the nanoparticle array. Remarkably, we show that the polaritonic band gap and the dielectric function of the metamaterial can be significantly modulated by the polarization of light. We unveil how such an anisotropic behavior in the plas…
Voltage-tunable Josephson Junctions on Germanium Quantum Wells with in-situ Aluminum Contacts
Laboratory for Physical Sciences（物理科学实验室）；University of Maryland, College Park（马里兰大学帕克分校）；Department of Materials Science & Engineering, University of Maryland, College Park（马里兰大学帕克分校材料科学与工程系）；University of Arkansas（阿肯色大学）；Pacific Northwest National Laboratory（太平洋西北国家实验室）
The exchange bias (EB) effect has been observed in magnetic Bi$_{0.9}$Gd$_{0.1}$Fe$_{0.9}$Ti$_{0.1}$O$_3$ nanoparticles. The influence of magnetic field cooling on the exchange bias effect has also been investigated. The magnitude of the exchange bias field ($H_{EB}$) increases with the cooling magnetic field, showing that the strength of the exchange bias effect is tunable by the field cooling. The $H_{EB}$ values are also found to be dependent on the temperature. This magnetically tunable exchange bias obtained at temperatures up to 250 K in Bi$_{0.9}$Gd$_{0.1}$Fe$_{0.9}$Ti$_{0.1}$O$_3$ nano…
Two-dimensional semiconducting transition metal dichalcogenides (TMDCs) are extremely attractive materials for optoelectronic applications in the visible and near-IR range. Here, we address for the first time to the best of our knowledge the issue of resonance coupling in hybrid exciton-polariton structures based on single Si nanoparticles coupled to monolayer WS2. We predict a transition from weak to strong coupling regime , with a Rabi splitting energy exceeding 200 meV for a Si nanoparticle covered by monolayer WS 2 at the magnetic optical Mie resonance. This large transition is achieved du…
A series of fluorescein-encapsulated zeolitic imidazolate framework-8 (fluorescein@ZIF-8) luminescent nanoparticles with a scalable guest loading has been fabricated and characterized. The successful encapsulation of the organic dye (fluorescein) is supported by both experimental evidence and theoretical simulations. The measured optical band gap is found to be comparable with the computed values of a hypothetical guest-host system. Isolated monomers and aggregates species of fluorescein confined in ZIF-8 nanocrystals have been systematically investigated through fluorescence lifetime spectros…
We develop multipolar theory of nonlinear generation of entangled photons from subwavelength dielectric particles due to the spontaneous parametric downconversion. We demonstrate that optical excitation in resonance with the high-quality supercavity mode of the aluminum gallium arsenide (AlGaAs) nanodisk leads to a strong enhancement of generation of entangled photon pairs associated with electric and magnetic dipole modes. Our rigorous numerical results are corroborated by an analytical model, universally describing formation of high-$Q$ resonant states and dark states due to the interference…
We study the behavior of charged spherical Au nanoparticles in a nanofluidic slit as a function of the separation of the symmetrically charged confining surfaces. A dedicated setup called the nano-fluidic confinement apparatus (NCA) allows us to parallelize the two confining surfaces and to continuously approach them down to direct contact. Interferometric scattering (iSCAT) detection is used to measure the particle contrast with 2 ms temporal resolution. We obtain the confinement gap distance from the interference signal of the glass and the oxide-covered silicon wafer surface with nanometer …
The dynamical motion of the magnetization plays a key role in the properties of magnetic materials. If the magnetization is initially away from the equilibrium direction in a magnetic nanoparticle, it will precess at a natural frequency and, with some damping present, will decay to the equilibrium position in a short lifetime. Here we investigate a simple but important situation where a magnetic nanoparticle is driven non-resonantly by an oscillating magnetic field, not at the natural frequency. We find a surprising result that the lifetime of the transient motion is strongly tunable, by facto…
We have observed enhancement and shift in the spin reorientation transition temperature as a consequence of coexistence of orthorhombic and hexagonal phases and higher aspect ratio in nanoscale LuFeO3. Nanoparticles and nanofibers of LuFeO3 are considered for this work. Nanoparticles have 75 % orthorhombic phase and 25 % hexagonal phase, while nanofibers have 23% orthorhombic phase and 77%-hexagonal phase. Larger aspect ratio in case of nanofibers is seen to help strain-stabilize the hexagonal phase in the material. Magnetic measurements show significant difference in the magnetic behavior and…
A method for growing nanoparticles with different elemental compositions simply by changing pulsing parameters in a power supply is demonstrated. The technique is based on high power pulsed hollow cathode sputtering, and the difference in particle composition ranges from pure Fe and Ni, to fully alloyed FeNi particles. Several pulses, or bursts, from a hollow cathode are needed in order to grow a nanoparticle using high power pulses. With this in mind, we devised a setup with two hollow cathodes of different material, Fe and Ni, situated in the vicinity of each other. By using two power suppli…
Contacts between high critical field superconductors and semiconductor nanowires are important in the context of topological quantum circuits in which superconductivity must be sustained to high magnetic fields. Here we demonstrate gate-tunable supercurrent in NbTiN-Ge/Si core/shell nanowire-NbTiN junctions. We observe supercurrents up to magnetic fields of 800 mT. The induced soft superconducting gap measured by co-tunneling through a quantum dot is 220 μeV. To improve contact transparency, we deposit an aluminum interlayer prior to NbTiN and observe a systematic change in the device pinch-of…
Understanding the size- and shape-dependent properties of platinum nanoparticles is critical for enabling the design of nanoparticle-based applications with optimal and potentially tunable functionality. Toward this goal, we evaluated nine different empirical potentials with the purpose of accurately modeling faceted platinum nanoparticles using molecular dynamics simulation. First, the potentials were evaluated by computing bulk and surface properties-surface energy, lattice constant, stiffness constants, and the equation of state-and comparing these to prior experimental measurements and qua…
Hybrid superconductor-semiconductor structures attract increasing attention owing to a variety of potential applications in quantum computing devices. They can serve to the realization of topological superconducting systems, as well as gate-tunable superconducting quantum bits. Here we combine a SiGe/Ge/SiGe quantum-well heterostructure hosting high-mobility two-dimensional holes and aluminum superconducting leads to realize prototypical hybrid devices, such as Josephson field-effect transistors (JoFETs) and superconducting quantum interference devices (SQUIDs). We observe gate-controlled supe…
Nanoplasmonics exploits the coupling between light and collective electron density oscillations (plasmons) to bypass the stringent limits imposed by diffraction. This coupling enables confinement of light to sub-wavelength volumes and is usually exploited in nanostructured metals. Substantial efforts are being made at the current frontier of the field to employ electron systems in semiconducting and semimetallic materials since these add the exciting possibility of realizing electrically tunable and/or active nanoplasmonic devices. Here we demonstrate that a suitable design of the doping profi…
We develop a quantum theory of plasmon polaritons in chains of metallic nanoparticles, describing both near- and far-field interparticle distances, by including plasmon-photon Umklapp processes. Taking into account the retardation effects of the long-range dipole-dipole interaction between the nanoparticles, which are induced by the coupling of the plasmonic degrees of freedom to the photonic continuum, we reveal the polaritonic nature of the normal modes of the system. We compute the dispersion relation and radiative linewidth, as well as the group velocities of the eigenmodes, and compare ou…
We demonstrate that by means of a local top-gate current oscillations can be observed in extended, monolayered films assembled from monodisperse metal nanocrystals -- realizing transistor function. The oscillations in this metal-based system are due to the occurrence of a Coulomb energy gap in the nanocrystals which is tunable via the nanocrystal size. The nanocrystal assembly by the Langmuir-Blodgett method yields homogeneous monolayered films over vast areas. The dielectric oxide layer protects the metal nanocrystal field-effect transistors from oxidation and leads to stable function for mon…
