We introduce a perturbative approach to solving the time dependent Schroedinger equation, named adiabatic perturbation theory (APT), whose zeroth order term is the quantum adiabatic approximation. The small parameter in the power series expansion of the time-dependent wave function is the inverse of the time it takes to drive the system's Hamiltonian from the initial to its final form. We review other standard perturbative and non-perturbative ways of going beyond the adiabatic approximation, extending and finding exact relations among them, and also compare the efficiency of those methods against the APT. Most importantly, we determine APT corrections to the Berry phase by use of the Aharonov-Anandan geometric phase. We then solve several time dependent problems allowing us to illustrate that the APT is the only perturbative method that gives the right corrections to the adiabatic approximation. Finally, we propose an experiment to measure the APT corrections to the Berry phase and show, for a particular spin-1/2 problem, that to first order in APT the geometric phase should be two and a half times the (adiabatic) Berry phase.
In this paper we present an invariant perturbation theory to adiabatic process according to the concepts of adiabatic orbits, adiabatic evolution orbit and U(1)-invariant adiabatic orbit. The probabilities of keeping the adiabatic orbit in the first-order and the second-order approximation are calculated, respectively. We also give a convenient sufficient condition.
We introduce an adiabatic perturbation theory for quantum systems with degenerate energy spectra. This perturbative series enables one to rigorously establish conditions for the validity of the adiabatic theorem of quantum mechanics for degenerate systems. The same formalism can be used to find non-adiabatic corrections to the non-Abelian Wilczek-Zee geometric phase. These corrections are relevant to assess the validity of the practical implementation of the concept of fractional exchange statistics. We illustrate the formalism by exactly solving a time-dependent problem and comparing its solu…
We restate the adiabatic elimination approximation as the first term in a singular perturbation expansion. We use the invariant manifold formalism for singular perturbations in dynamical systems to identify systematic improvements on adiabatic elimination, connecting with well established quantum mechanical perturbation methods. We prove convergence of the expansions when energy scales are well separated. We state and solve the problem of hermiticity of improved effective hamiltonians.
A potential problem with adiabatic switching in perturbation theory is that divergent terms appear in the series solution. An example of this was presented by C. Brouder et al [4] for a simple 2 state system where the evolution of system in the presence of a time dependent perturbation was considered. One of their results is that the evolution operator has no well-defined limit for adiabatic switching. We will rework this problem to show that for adiabatic switching the evolved states are well-defined with any divergences being absorbed in a time independent phase factor which can be removed. …
We investigate the origin of quantum geometric phases, gauge fields and forces beyond the adiabatic regime. In particular, we extend the notions of geometric magnetic and electric forces discovered in studies of the Born-Oppenheimer approximation to arbitrary quantum systems described by matrix valued quantum Hamiltonians. The results are illustrated by several physical relevant examples.
The proposal of the optical scheme for holonomic quantum computation is evaluated based on dynamical resolution to the system beyond adiabatic limitation. The time-dependent Schrödinger equation is exactly solved by virtue of the cranking representation and gauge transformation approach. Besides providing rigorous confirmation to holonomies of the geometrical prediction that holds for the ideally adiabatic situation, the dynamical resolution enables one to evaluate elaborately the amplitude of the nonadiabatic deviation, so that the errors induced to the quantum computation can be explicitly e…
We provide rigorous bounds for the error of the adiabatic approximation of quantum mechanics under four sources of experimental error: perturbations in the initial condition, systematic time-dependent perturbations in the Hamiltonian, coupling to low-energy quantum systems, and decoherent time-dependent perturbations in the Hamiltonian. For decoherent perturbations, we find both upper and lower bounds on the evolution time to guarantee the adiabatic approximation performs within a prescribed tolerance. Our new results include explicit definitions of constants, and we apply them to the spin-1/2…
We show that the physical mechanism of population transfer in a 3-level system with a closed loop of coherent couplings (loop-STIRAP) is not equivalent to an adiabatic rotation of the dark-state of the Hamiltonian but coresponds to a rotation of a higher-order trapping state in a generalized adiabatic basis. The concept of generalized adiabatic basis sets is used as a constructive tool to design pulse sequences for stimulated Raman adiabatic passage (STIRAP) which give maximum population transfer also under conditions when the usual condition of adiabaticty is only poorly fulfilled. Under cert…
The use of the adiabatic approximation in practical applications, as in adiabatic quantum computation, demands an assessment of the errors made in finite-time evolutions. Aiming at such scenarios, we derive bounds relating error and evolution time in the adiabatic approximation that go beyond typical scaling relations. Using the Adiabatic Perturbation Theory, we obtain leading-order expressions valid for long evolution time $T$, while explicitly determining the shortest time $T$ and the largest error $\varepsilon$ for which they are valid. In this validity regime, we can make clear and precise…
Adiabatic elimination is a standard tool in quantum optics, which produces an effective Hamiltonian for a relevant subspace of states, incorporating effects of its coupling to states with much higher unperturbed energy. It shares with techniques from other fields the emphasis on the existence of widely separated scales. Given this fact, the question arises whether it is feasible to improve on the adiabatic approximation, similarly to some of those other approaches. A number of authors have addressed the issue from the quantum optics/atomic physics perspective, and have run into the issue of no…
In this paper, we present an invariant perturbation theory of the adiabatic process based on the concepts of U(1)-invariant adiabatic orbit and U(1)-invariant adiabatic expansion. As its application, we propose and discuss new adiabatic approximation conditions.
In multi-level systems, the commonly used adiabatic elimination is a method for approximating the dynamics of the system by eliminating irrelevant, non-resonantly coupled levels. This procedure is, however, somewhat ambiguous and it is not clear how to improve on it systematically. We use an integro-differential equation for the probability amplitudes of the levels of interest, which is equivalent to the original Schrodinger equation for all probability amplitudes. In conjunction with a Markov approximation, the integro-differential equation is then used to generate a hierarchy of approximatio…
We present an analysis of the adiabatic approximation to understand when it applies, in view of the recent criticisms and studies for the validity of the adiabatic theorem. We point out that this approximation is just the leading order of a perturbation series, that holds in a regime of a perturbation going to infinity, and so the conditions for its validity can be only obtained going to higher orders in the expansion and removing secular terms, that is terms that runs to infinity as the time increases. In this way, it is always possible to get the exact criteria for the approximation to hold.
We use the Rayleigh-Schrödinger perturbation theory to calculate the corrections to the adiabatic geometric phase due to a perturbation of the Hamiltonian. We show that these corrections are at least of second order in the perturbation parameter. As an application of our general results we address the problem of the adiabatic geometric phase for a one-dimensional particle which is confined to an infinite square well with moving walls.
The creation of single collective excitations in atomic ensembles via spontaneous Raman emission plays a key role in several quantum communication protocols, starting with the seminal DLCZ protocol [L.-M.Duan, M.D. Lukin, J.I. Cirac, and P. Zoller, Nature {\bf 414}, 413 (2001).] This process is usually analyzed theoretically under the assumptions that the write laser pulse inducing the Raman transition is far off-resonance, and that the atomic ensemble is only homogeneously broadened. Here we study the impact of near-resonance excitation for inhomogeneously broadened ensembles on the collectiv…
We concentrate on the geometric potential in the invariant perturbation theory of quantum adiabatic process which is presented in our recent papers. It is found out to be related to the geodesic curvature of the spherical curve in 2-dimension quantum systems. We also show that the geometric potential may affect adiabatic approximation remarkably.
We present details and expand on the framework leading to the recently introduced degenerate adiabatic perturbation theory [Phys. Rev. Lett. 104, 170406 (2010)], and on the formulation of the degenerate adiabatic theorem, along with its necessary and sufficient conditions given in [Phys. Rev. A 85, 062111 (2012)]. We start with the adiabatic approximation for degenerate Hamiltonians that paves the way to a clear and rigorous statement of the associated degenerate adiabatic theorem, where the non-abelian geometric phase (Wilczek-Zee phase) plays a central role to its quantitative formulation. W…
By introducing a temporal change timescale $τ_{\text{A}}(t)$ for the time-dependent system Hamiltonian, a general formulation of the Markovian quantum master equation is given to go well beyond the adiabatic regime. In appropriate situations, the framework is well justified even if $τ_{\text{A}}(t)$ is faster than the decay timescale of the bath correlation function. An application to the dissipative Landau-Zener model demonstrates this general result. The findings are applicable to a wide range of fields, providing a basis for quantum control beyond the adiabatic regime.
We demonstrate controlled pumping of Cooper pairs down to the level of a single pair per cycle, using an rf-driven Cooper-pair sluice. We also investigate the breakdown of the adiabatic dynamics in two different ways. By transferring many Cooper pairs at a time, we observe a crossover between pure Cooper-pair and mixed Cooper-pair-quasiparticle transport. By tuning the Josephson coupling that governs Cooper-pair tunneling, we characterize Landau-Zener transitions in our device. Our data are quantitatively accounted for by a simple model including decoherence effects.
The adiabatic perturbation is shown to be singular from the exact solution of a spin-1/2 particle in a uniformly rotating magnetic field. Due to a non-adiabatic effect, its quantum trajectory on a Bloch sphere is a cycloid traced by a circle rolling along an adiabatic path. As the magnetic field rotates more and more slowly, the time-energy uncertainty, proportional to the distance of the quantum trajectory, calculated by the exact solution is entirely different from the one obtained by the adiabatic path traced by the instantaneous state. However, the non-adiabatic Aharonov-Anandan geometric …
The propagation of matter waves in curved geometry is relevant for electrons in nano-wires, solid-state physics structures and atomtronics. Curvature effects are usually addressed within the adiabatic limit and treated via an effective potential acting on the manifold to which the particles are strongly confined. However, the strength of the confinements that can be achieved experimentally are in practice limited, and the adiabatic approximation framework often appears too restrictive for the realistic design of relevant propagation structures. Here, we explore the design of 2D sharply bent wa…
Non-adiabatic decay rates for a radio-frequency dressed magnetic trap are calculated using Fermi's Golden Rule: that is, we examine the probability for a single atom to make transitions out of the dressed trap and into a continuum in the adiabatic limit, where perturbation theory can be applied. This approach can be compared to the semi-classical Landau-Zener theory of a resonant dressed atom trap, and it is found that, when carefully implemented, the Landau-Zener theory overestimates the rate of non-adiabatic spin flip transitions in the adiabatic limit. This indicates that care is needed whe…
Duality is considered for the perturbation theory by deriving, given a series solution in a small parameter, its dual series with the development parameter being the inverse of the other. A dual symmetry in perturbation theory is identified. It is then shown that the dual to the Dyson series in quantum mechanics is given by a recent devised series having the adiabatic approximation as leading order. A simple application of this result is given by rederiving a theorem for strongly perturbed quantum systems.
One often needs to estimate how fast an evolving state of a quantum system can depart from some target state or target subspace of a Hilbert space. Such estimates are known as quantum speed limits. We derive a quantum speed limit for a general time-dependent target subspace. When the target subspace is an instantaneous invariant subspace of a time-dependent Hamiltonian, the obtained quantum speed limit bounds the adiabatic fidelity, which is a figure of merit of quantum adiabaticity. We also compare two states evolving under two different Hamiltonians and derive a bound on the Loschmidt echo.
We prove the validity of linear response theory at zero temperature for perturbations of gapped Hamiltonians describing interacting fermions on a lattice. As an essential innovation, our result requires the spectral gap assumption only for the unperturbed Hamiltonian and applies to a large class of perturbations that close the spectral gap. Moreover, we prove formulas also for higher order response coefficients. Our justification of linear response theory is based on a novel extension of the adiabatic theorem to situations where a time-dependent perturbation closes the gap. According to the st…
We give a systematic review of the adiabatic theorem and the leading non-adiabatic corrections in periodically-driven (Floquet) systems. These corrections have a two-fold origin: (i) conventional ones originating from the gradually changing Floquet Hamiltonian and (ii) corrections originating from changing the micro-motion operator. These corrections conspire to give a Hall-type linear response for non-stroboscopic (time-averaged) observables allowing one to measure the Berry curvature and the Chern number related to the Floquet Hamiltonian, thus extending these concepts to periodically-driven…
In the past decades, it was recognized that quantum chaos, which is essential for the emergence of statistical mechanics and thermodynamics, manifests itself in the effective description of the eigenstates of chaotic Hamiltonians through random matrix ensembles and the eigenstate thermalization hypothesis. Standard measures of chaos in quantum many-body systems are level statistics and the spectral form factor. In this work, we show that the norm of the adiabatic gauge potential, the generator of adiabatic deformations between eigenstates, serves as a much more sensitive measure of quantum cha…
In quantum mechanics, adiabatic elimination is a standard tool that produces a low-lying reduced Hamiltonian for a relevant subspace of states, incorporating effects of its coupling to states with much higher energy. Suppose this powerful elimination approach is applied to quasi-energy states in periodically-driven systems, a critical question then arises that the violation of the adiabatic condition caused by driven forces challenges such a presence of spectral reduction in the non-equilibrium driven system. Here, both theoretically and experimentally, we newly reported two kinds of driven-in…
