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arXiv 0804.3930astro-ph
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多环芳烃的电荷态在紫外消光中的作用

The role of the charge state of PAHs in ultraviolet extinction

C. Cecchi-Pestellini, G. Malloci, G. Mulas, C. Joblin, D. A. Williams

摘要:

目的:探讨多环芳烃(PAHs)的电荷状态与消光曲线形态的关系。研究方法:我们拟合消光曲线的尘埃模型,包括核幔混合化学成分的球形颗粒(硅酸盐核心,$sp^2$和$sp^3$碳质层),和一个额外的分子组分。我们使用精确的方法来计算消光由于经典粒子和准确计算的吸收光谱的多环芳烃在不同的电荷状态,由于分子组分的贡献,沿着一个样本的五个相当不同的视线。结果:经典的尘埃颗粒和真正的多环芳烃的混合物的组合令人满意地匹配所观察到的星际消光曲线。多环芳烃在不同的电荷状态下的光谱特性的变化产生的变化与不同的相对强度的颠簸和非线性远紫外线上升一致。

英文摘要:

Aims: We explore the relation between charge state of polycyclic aromatic hydrocarbons (PAHs) and extinction curve morphology. Methods: We fit extinction curves with a dust model including core-mantle spherical particles of mixed chemical composition (silicate core, $sp^2$ and $sp^3$ carbonaceous layers), and an additional molecular component. We use exact methods to calculate the extinction due to classical particles and accurate computed absorption spectra of PAHs in different charge states, for the contribution due to the molecular component, along a sample of five rather different lines of sight. Results: A combination of classical dust particles and mixtures of real PAHs satisfactorily matches the observed interstellar extinction curves. Variations of the spectral properties of PAHs in different charge states produce changes consistent with the varying relative strengths of the bump and non-linear far-UV rise.

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