We study the implications of primordial magnetic fields for the thermal and ionization history of the post-recombination era. In particular we compute the effects of dissipation of primordial magnetic fields owing to ambipolar diffusion and decaying turbulence in the intergalactic medium (IGM) and the collapsing halos and compute the effects of the altered thermal and ionization history on the formation of molecular hydrogen. We show that, for magnetic field strengths in the range $2 \times 10^{-10} {\rm G} \la B_0 \la 2 \times 10^{-9} {\rm G}$, the molecular hydrogen fraction in IGM and collapsing halo can increase by a factor 5 to 1000 over the case with no magnetic fields. We discuss the implication of the increased molecular hydrogen fraction on the radiative transfer of UV photons and the formation of first structures in the universe.
CMBR distortion concerned with recombination of the primordial plasma is calculated in frequency band from 1 GHz to 100 GHz in the frame of the standard cosmological model for different values of cosmological density parameters: nonrelativistic matter density $Ω_m$ and baryonic matter density $Ω_b$. Comparison of these results with observational data which will be obtained from planned experiments may be used for independent determination of the cosmological parameters $Ω_m$ and $Ω_b$.
The dependences on z of fractional number densities of H+ and He+ ions are calculated with a proper allowance for two-photon decays of upper levels of hydrogen and parahelium and radiative transfer in intercombination line 2 3P_1 --> 1 1S_0 of helium. It is shown that for hydrogen this gives corrections for a degree of ionization in no more than a few percents but for helium this leads to a significant acceleration of recombination compared to the recent papers by Seager et al. (1999; 2000) where these effects were ignored.
Thermal and chemical evolution of primordial gas clouds irradiated with far-ultraviolet (FUV; < 13.6 eV) radiation is investigated. In clouds irradiated by intense FUV radiation, sufficient hydrogen molecules to be important for cooling are never formed. However, even without molecular hydrogen, if the clouds are massive enough, they start collapsing via atomic hydrogen line cooling. Such clouds continue to collapse almost isothermally owing to successive cooling by H^{-} free-bound emission up to the number density of 10^{16} cm^{-3}. Inside the clouds, the Jeans mass eventually falls well be…
It is shown that taking into account a recoil for radiation scattering in the Ly-alpha line can lead to a noticable acceleration of primordial hydrogen recombination. Thus for LambdaCDM model a decrease of ionization degree exceeds 1% for redshifts z in a range 800 - 1050 achieving approximately 1.3% at z=900. Corresponding corrections to the cosmic microwave background power spectra can achieve 1.1% for TT spectra and 1.7% for EE ones. Radiative transfer in these calculations was treated in a quasistationary approximation. Numerical solutions are also obtained in diffusion approximation for a…
We use one-dimensional radiative transfer simulations to study the evolution of H_2 gas-phase (H^- catalyzed) formation and photo-dissociation regions in the primordial universe. We find a new positive feedback mechanism capable of producing shells of H_2 in the intergalactic medium, which are optically thick in some Lyman-Werner bands. While these shells exist, this feedback effect is important in reducing the H_2 dissociating background flux and the size of photo-dissociation spheres around each luminous object. The maximum background opacity of the IGM in the H_2 Lyman-Werner bands is τ_{H_…
This paper investigates the effect of collisional enhancement of the hydrogen lines on the derivation of the helium abundances in low metallicity H II regions. For this, we have constructed a grid of photoionization models relevant for the analysis of giant \hii regions in blue compact galaxies. We show that the effect of collisional excitation on the Halpha/Hbeta ratio can be quite important (up to 8% or more). The impact of this effect on the determination of the helium mass fraction has been tracked on four low-metallicity blue compact galaxies for which Keck spectra are available and which…
The HeII->HeI recombination of primordial helium plasma (z = 1500 - 3000) is considered in terms of the standard cosmological model. This process affects the formation of cosmic microwave background anisotropy and spectral distortions. We investigate the effect of neutral hydrogen on the HeII->HeI recombination kinetics with partial and complete redistributions of radiation in frequency in the HeI resonance lines. It is shown that to properly compute the HeII->HeI recombination kinetics, one should take into account not only the wings in the absorption and emission profiles of the HeI resonanc…
One of the most outstanding problems in the gravitational collapse scenario of early structure formation is the cooling of primordial gas to allow for small mass objects to form. As the neutral primordial gas is a poor radiator at temperatures (T\le10^4\unit{K}), molecular hydrogen is needed for further cooling down to temperatures (T\sim100\unit{K}). The formation of molecular hydrogen is catalyzed by the presence of free electrons, which could be provided by the ionization due to an early population of cosmic rays. In order to investigate this possibility we developed a code to study the eff…
It is now well known that a primordial chemistry, involving light elements produced during the nucleosynthesis period, might develop during the hydrogen post-recombination era. In particular, molecular ions and primordial molecules such as H2, HD and LiH will be produced. We summarize this primordial chemistry after the recombination epoch, and then present a simple gravitational collapse model of a cloud. The potentiality of fragmentation of this collapsing protoclouds through the thermal instability is also discussed. We suggest that this study could also be extended to the CO molecule, beca…
We have reviewed the chemistry and cooling behaviour of low-density (n<10^4 cm^-3) primordial gas and devised a cooling model wich involves 19 collisional and 9 radiative processes and is applicable for temperatures in the range (1 K < T < 10^8 K). We derived new fits of rate coefficients for the photo-attachment of neutral hydrogen, the formation of molecular hydrogen via H-, charge exchange between H2 and H+, electron detachment of H- by neutral hydrogen, dissociative recombination of H2 with slow electrons, photodissociation of H2+, and photodissociation of H2. Further it was found that the…
We present the results of a deep search for the molecular hydrogen shock fronts associated with young stellar outflows in the giant molecular cloud and massive star forming region W51. A total of 14 outflows were identified, and a few of these were studied in detail with high-resolution imaging and spectroscopy.
Semi-empirical molecular dynamics is used to simulate several gaseous atomic hydrogen interactions with hydrocarbon grains in space: recoil, adsorption, diffusion, chemisorption and recombination into molecular hydrogen. Their probabilities are determined by multiple numerical experiments, as a function of initial velocity of gas atoms. The equilibrium hydrogen coverage of free grains is then derived. These data can be used in calculations of material and energy balance as well as rates of hydrogen recombination on grains. The role of grain temperature is also considered.
Many questions in physical cosmology regarding the thermal history of the intergalactic medium, chemical enrichment, reionization, etc. are thought to be intimately related to the nature and evolution of pregalactic structure. In particular the efficiency of primordial star formation and the primordial IMF are of special interest. We present results from high resolution three--dimensional adaptive mesh refinement simulations that follow the collapse of primordial molecular clouds and their subsequent fragmentation within a cosmologically representative volume. Comoving scales from 128 kpc down…
We derive radial and vertical distributions of HI and H2 gas densities in our Galaxy by using the terminal velocity method. We calculate the molecular fraction (f_mol) defined as the ratio of the molecular hydrogen to total hydrogen gas density at galactic longitude l= 33 to 64 deg and galactic latitude b=-2 to +2 deg. The thickness of the molecular dominant region f_mol > 0.8 is approximately constant (109 +/- 12 pc) at galactocentric distance R = 4.7 to 7.2 kpc. The molecular fraction decreases suddenly at a critical height from the galactic plane, below which the gas disk is almost totally …
The z ~ 0.701 absorption system towards the QSO PG1718+4807 is the only example of a QSO absorption system which might have a deuterium/hydrogen ratio approximately ten times the value found towards other QSOs. We have obtained new STIS spectra from the Hubble Space Telescope of the Lyman alpha and Lyman limit regions of the system. These spectra give the redshift and velocity dispersion of the neutral hydrogen which produces most of the observed absorption. The Lyman alpha line is too narrow to account for all of the observed absorption. It was previously known that extra absorption is needed…
The evolution of collapsing metal free protostellar clouds is investigated for various masses and initial conditions. We perform hydrodynamical calculations for spherically symmetric clouds taking account of radiative transfer of the molecular hydrogen lines and the continuum, as well as of chemistry of the molecular hydrogen. The collapse is found to proceed almost self-similarly like Larson-Penston similarity solution. In the course of the collapse, efficient three-body processes transform atomic hydrogen in an inner region of $\sim 1 M_{\sun}$ entirely into molecular form. However, hydrogen…
We study the prospects for observing H$_2$ emission during the assembly of primordial molecular cloud kernels. The primordial molecular cloud cores, which resemble those at the present epoch, can emerge around $1+z=20$ according to recent numerical simulations. The kernels form inside the cores, and the first stars will appear inside the kernels. A kernel typically contracts to form one of the first generation stars with an accretion rate that is as large as $\sim 0.01 M_\odot$ year$^{-1}$. This occurs due to the primordial abundances that result in a kernel temperature of order 1000K, and the…
Estimates of the deuterium abundance in quasar absorbers are reviewed, including a brief account of incorrect claims published by the author and a brief review of the problem of hydrogen contamination. It is concluded that the primordial abundance may be universal with a value $(D/H)_P\approx 10^{-4}$, within about a factor of two, corresponding to $Ω_B h_{0.7}^2\approx 0.02$ or $η_{10}\approx 2.7$ in the Standard Big Bang. This agrees with current limits on primordial helium, $Y_P\le 0.243$, which are shown to be surprisingly insensitive to models of stellar enrichment. It also agrees with a …
We have modeled self-consistently the density and temperature profiles of gas and dust in protoplanetary disks, taking into account irradiation from a central star. Making use of this physical structure, we have calculated the level populations of molecular hydrogen and the line emission from the disks. As a result, we can reproduce the observed strong line spectra of molecular hydrogen from protoplanetary disks, both in the ultraviolet (UV) and the near-infrared, but only if the central star has a strong UV excess radiation.
We have detected emission of molecular hydrogen from a classical T Tauri star, LkHalpha 264 in the v=1-0 S(1) line at 2.122 micron. The line velocity is coincident with the rest velocity of the star. The line profile is well reproduced by a model in which the line emanates from material in a Keplerian rotating circumstellar disk. Fluorescence by X-ray ionization and shock excitation due to accretion or a low-velocity wind are considered for the emission mechanism of molecular hydrogen.
We report on laboratory measurements of molecular hydrogen formation and recombination on an olivine slab as a function of surface temperature under conditions relevant to those encountered in the interstellar medium. On the basis of our experimental evidence, we recognize that there are two main regimes of H coverage that are of astrophysical importance; for each of them we provide an expression giving the production rate of molecular hydrogen in interstellar clouds.
The subject of cosmological hydrogen recombination has received much attention recently because of its importance to predictions for and cosmological constraints from CMB observations. While the central role of the two-photon decay 2s->1s has been recognized for many decades, high-precision calculations require us to consider two-photon decays from the higher states ns,nd->1s (n>=3). Simple attempts to include these processes in recombination calculations have suffered from physical problems associated with sequences of one-photon decays, e.g. 3d->2p->1s, that technically also produce two phot…
We study the ejecta chemistry of a zero-metallicity progenitor, massive, supernova using a novel approach based on chemical kinetics. Species considered span the range of simple, di-atomic molecules such as CO or SiO to more complex species involved in dust nucleation processes. We describe their formation from the gas phase including all possible relevant chemical processes and apply it to the ejecta of a primordial 170 Msun supernova. Two ejecta cases are explored: full mixing of the heavy elements, and a stratified ejecta reflecting the progenitor nucleosynthesis. Penetration of hydrogen fr…
Many questions in physical cosmology regarding the thermal history of the intergalactic medium, chemical enrichment, reionization, etc. are thought to be intimately related to the nature and evolution of pregalactic structure. In particular the efficiency of primordial star formation and the primordial IMF are of special interest. We present results from high resolution three-dimensional adaptive mesh refinement simulations that follow the collapse of primordial molecular clouds and their subsequent fragmentation within a cosmologically representative volume. Comoving scales from 128 kpc down …
Molecular hydrogen clouds can contribute substantially to the galactic halo< dark matter and may lead to the birth of massive halo objects (MHOs) observed indirectly by microlensing. We present a method to detect these molecular clouds in the halo of M31 using the Doppler shift effect. We also consider the possibility to directly observe MHOs in the halo of M31 via their infrared emission.
We report the discovery of molecular hydrogen absorption in a Galactic high-velocity cloud (HVC) in the direction of the Large Magellanic Cloud. For the same HVC we derive an iron abundance which is half of the solar value. Thus, all evidence points to a Galactic origin for high-velocity cloud complex in front of the LMC.
We investigate the formation of molecular hydrogen (H_2) in a primordial H+He gas cloud irradiated by a power-law UV flux. We find that at high densities (>1 cm^{-3}) and low temperatures (<10^4 K), the background radiation enhances the formation of H_2 and results in molecular cooling dominating over photoionization heating. This process could accelerate the collapse and fragmentation of dense objects at high redshifts.
We present newly calculated low-temperature opacities for gas with a primordial chemical composition. In contrast to earlier calculations which took a pure metal-free Hydrogen/Helium mixture, we take into account the small fractions of Deuterium and Lithium as resulting from Standard Big Bang Nucleosynthesis. Our opacity tables cover the density range -16 < log rho [g cm^{-3}] < -2 and temperature range of 1.8 < T [K] < 4.6, while previous tables were usually restricted to T > 10^3 K. We find that, while the presence of Deuterium does not significantly alter the opacity values, the presence of…
We present NICMOS imaging of broad band and molecular hydrogen emission in Seyfert galaxies. In 6 of 10 Seyferts we detect resolved or extended emission in the 1-0 S(1) 2.121 or 1-0 S(3) 1.9570 micron molecular hydrogen lines. We did not detect emission in the most distant galaxy or in the 2 Seyfert 1 galaxies in our sample because of the luminosity of the nuclear point sources. In NGC 5643, NGC 2110 and MKN 1066, molecular hydrogen emission is detected in the extended narrow line region on scales of a few hundred pc from the nucleus. Emission is coincident with [OIII] and H alpha+[NII] line e…
Molecular hydrogen has an important role in the early stages of star formation as well as in the production of many other molecules that have been detected in the interstellar medium. In this review we show that it is now possible to study the formation of molecular hydrogen in simulated astrophysical environments. Since the formation of molecular hydrogen is believed to take place on dust grains, we show that surface science techniques such as thermal desorption and time-of-flight can be used to measure the recombination efficiency, the kinetics of reaction and the dynamics of desorption. The…
Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They turn out to be significantly higher than those obtained for polycrystalline silicates, demonstrating the importance of grain morphology. Using these barriers we evaluate the efficiency of molecular hydrogen formation on amorphous silicate grains under interstellar conditions. It is found that unlike polycrystalline silicates, amorphous silicate grains are effi…
We report the first observation of Ly$α$ pumped molecular hydrogen emission lines in planetary nebulae. The H$_{2}$ emission observed in the ultraviolet spectra of NGC 6853 and NGC 3132 can be explained by excitation of vibrationally hot H$_{2}$ by Ly$α$ photons. Constraints are placed on the nebular Ly$α$ emission profile, as well as the molecular hydrogen temperature, column density and turbulent motion. These parameters are similar for the two nebulae, pointing to similar physical conditions in these objects. The ro-vibrational cascade following Ly$α$ pumping is predicted to have low surfac…
We describe a phenomenological model for molecular hydrogen formation suited for applications in galaxy formation simulations, which includes on-equilibrium formation of molecular hydrogen on dust and approximate treatment of both its self-shielding and shielding by dust from the dissociating UV radiation. The model is applicable in simulations in which individual star forming regions - the giant molecular complexes - can be identified (resolution of tens of pc) and their mean internal density estimated reliably, even if internal structure is not resolved. In agreement with previous studies, c…
We have included the chemical rate network responsible for the formation of molecular Hydrogen in the N-body hydrodynamic code, Hydra, in order to study the formation of the first cosmological at redshifts between 10 and 50. We have tested our implementation of the chemical and cooling processes by comparing N-body top hat simulations with theoretical predictions from a semi-analytic model and found them to be in good agreement. We find that post-virialization properties are insensitive to the initial abundance of molecular hydrogen. Our main objective was to determine the minimum mass ($M_{SG…
A knowledge of the recombination time on the grain surfaces has been a major obstacle in deciding the production rate of molecular hydrogen and other molecules in the interstellar medium. We present a numerical study to compute this time for molecular hydrogen for various cloud and grain parameters. We also find the time dependence, particularly when a grain is freshly injected into the system. Apart from the fact that the recombination times seem to be functions of the grain parameters such as the activation barrier energy, temperature etc, our result also shows the dependence on the number o…
We present clear spectroscopic detections of molecular hydrogen in the outer filaments of the H-alpha nebula surrounding the central galaxy of the Perseus cluster, NGC 1275. This implies the presence of warm molecular gas clouds at projected distances up to 24 kpc from the nucleus of the host galaxy, embedded in the hot intracluster medium. The emission-line intensity ratios reveal that the molecular hydrogen is predominately thermally excited with excitation temperatures of 1600-2200K, suggesting a lack of pressure balance between the molecular component and its surrounding medium. Excitation…
We study formation of molecules in primordial prestellar clumps and evaluate the line luminosities to assess detectability by next-generation facilities. If the initial H_2 fraction is sufficiently high, HD becomes an important coolant in the clumps. The luminosity from such HD cooling clumps is lower than that from H_2 cooling ones because of lower temperature (<100K). As for Li reactions, we include the three-body LiH formation approximately. The Li molecular fraction remains very low (<10^{-3}) throughout the evolution owing to the high dissociative reaction rate of LiH +H -> Li + H_2. LiH …
The possibility to detect cosmological signals from the post-recombination Universe is one of the main aims of modern cosmology. In a previous paper we emphasized the role that elastic resonant scattering through LiH molecules can have in dumping primary CBR anisotropies and raising secondary signals. Here we extend our analysis to all the evolutionary stages of a primordial cloud, starting with the linear phase, through the turn-around and to the non linear collapse. We have done calculations for proto-clouds in a CDM scenario and, more generally, for a set of clouds with various masses and v…
We study the prospects for observing H$_2$ and HD emission during the assembly of primordial molecular cloud cores. The primordial molecular cloud cores, which resemble those at the present epoch, can emerge around $1+z \sim 20$ according to recent numerical simulations. A core typically contracts to form the first generation of stars and the contracting core emits H$_2$ and HD line radiation. These lines show a double peak feature. The higher peak is the H$_2$ line of the $J=2-0$ (v=0) rotational transition, and the lower peak is the HD line of the $J=4-3$ (v=0) rotational transition. The rat…
The first FUV (lambda lambda 1350-1750 A) spectral imaging observations of the Eridanus superbubble, obtained with the SPEAR/FIMS mission, have revealed distinct fluorescent emission from molecular hydrogen. In this study, the observed emission features were compared with those from a photo-dissociation region model with assumed illuminating stellar fields. The result showed rather high line ratios of I_{1580}/I_{1610}, which may imply the existence of high-temperature molecular clouds in the region. The H_2 fluorescence intensity showed a proportional correlation with H-alpha emission, indica…
We discuss how measurements of fluctuations in the absorption of cosmic microwave background (CMB) photons by neutral gas during the cosmic dark ages, at redshifts z ~ 7--200, could reveal the primordial deuterium abundance of the Universe. The strength of the cross-correlation of brightness-temperature fluctuations due to resonant absorption of CMB photons in the 21-cm line of neutral hydrogen with those due to resonant absorption of CMB photons in the 92-cm line of neutral deuterium is proportional to the fossil deuterium to hydrogen ratio [D/H] fixed during big bang nucleosynthesis (BBN). A…
The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption processes are obtained. The more porous morphology of the low density ice gives rise to a broader spectrum of energy barriers compared to the high density ice. Inserting these parameters into the rate equation model under steady state conditions we evaluate the production rate of molecular hydrogen on ice-coated interstellar dust grains.
Recent experimental results about the formation of molecular hydrogen on astrophysically relevant surfaces under conditions close to those encountered in the interstellar medium are analyzed using rate equations. The parameters of the rate equation model are fitted to temperature-programmed desorption curves obtained in the laboratory. These parameters are the activation energy barriers for atomic hydrogen diffusion and desorption, the barrier for molecular hydrogen desorption, and the probability of spontaneous desorption of a hydrogen molecule upon recombination. The model is a generalizatio…
Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented for the first time and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They turn out to be significantly higher than those obtained earlier for polycrystalline silicates, demonstrating the importance of grain morphology. Using these barriers we evaluate the efficiency of molecular hydrogen formation on amorphous silicate grains under interstellar conditions. It is found that unlike polycrystalline silicates, amorpho…
