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arXiv 0802.1257cond-mat.mtrl-scicond-mat.soft
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双层铁磁流体的结构和热力学

Structure and thermodynamics of a ferrofluid bilayer

Carlos Alvarez, Martial Mazars, Jean-Jacques Weis

摘要:

我们提出了广泛的蒙特卡罗模拟的热力学和结构性质的平面双层的偶极硬球的密度,偶极矩和层间距的范围很广。导出了双层系统的应力张量和压力张量的表达式。对于所有的热力学状态被认为是层间能量是有吸引力的,远小于层内的能量贡献。它消失在两个硬球直径的顺序层分离。法向压力是负的并且作为层分离$h$的函数衰减为$-1/h^5$。给出了层内、层间电子对分布函数和角关联函数。尽管弱层间能量强的位置和取向的相关性存在于两个层中的粒子之间。

英文摘要:

We present extensive Monte Carlo simulations for the thermodynamic and structural properties of a planar bilayer of dipolar hard spheres for a wide range of densities, dipole moments and layer separations. Expressions for the stress and pressure tensors of the bilayer system are derived. For all thermodynamic states considered the interlayer energy is shown to be attractive and much smaller than the intralayer contribution to the energy. It vanishes at layer separations of the order of two hard sphere diameters. The normal pressure is negative and decays as a function of layer separation $h$ as $-1/h^5$. Intralayer and interlayer pair distribution functions and angular correlation functions are presented. Despite the weak interlayer energy strong positional and orientational correlations exist between particles in the two layers.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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