The quantum thermodynamic functions of a harmonic oscillator coupled to a heat bath through velocity-dependent coupling are obtained analytically. It is shown that both the free energy and the entropy decay fast with the temperature in relation to that of the usual coupling from. This implies that the velocity-dependent coupling helps to ensure the third law of thermodynamics.
The state function entropy and its quantum thermodynamical implication for two typical dissipative systems with anomalous spectral densities are studied by investigating on their low-temperature quantum behavior. In all cases it is found that the entropy decays quickly and vanishes as the temperature approaches zero. This reveals a good conformity with the third law of thermodynamics and provides another evidence for the validity of fundamental thermodynamical laws in the quantum dissipative region.
The consequences of the opening of a phason gap in incommensurate systems are studied on a simple model, the discrete frustrated $ϕ^4$-model. Analytical considerations and numerical results show that there is a very weak phase transition that can be characterized as third order.
The spin-1/2 Ising diamond chain in a magnetic field displays a remarkable pseudo-transition whenever it is driven sufficiently close to a ground-state phase boundary between a classical ferrimagnetic phase and a highly degenerate frustrated phase. The pseudo-transition of the spin-1/2 Ising diamond chain relates to intense thermal excitations from a nondegenerate ferrimagnetic ground state to a highly degenerate manifold of excited states with a frustrated character, which are responsible for an anomalous behavior of thermodynamic quantities. Temperature dependences of entropy and specific he…
Bento \textit{et al.} [Phys. Rev. E 91, 022105 (2015)] state that the Tsallis entropy violates the third law of thermodynamics for $q \leq 0$ and $0<q<1$. We show that their results are valid only for $q \geq 1$, since there is no distribution maximizing the Tsallis entropy for the intervals $q \leq 0$ and $0<q<1$ compatible with the system energy expression.
We have made a simple and natural modification of a recent quantum refrigerator model presented by Cleuren et al. in Phys. Rev, Lett.108, 120603 (2012). The original model consist of two metal leads acting as heat baths, and a set of quantum dots that allow for electron transport between the baths. It was shown to violate the dynamic third law of thermodynamics (the unattainability principle, which states that cooling to absolute zero in finite time is impossible), but by taking into consideration the finite energy level spacing in metals we restore the third law, while keeping all of the orig…
The Third Law of Thermodynamics constrains the phase diagram of{systems with a first-order quantum phase transition. For zero conjugate field, the coexistence curve has an infinite slope at T=0. If a tricritical point exists at T>0, then the associated tricritical wings are perpendicular to the T=0 plane, but not to the zero-field plane. These results are based on the third law and basic thermodynamics only, and are completely general. As an explicit example we consider the ferromagnetic quantum phase transition in clean metals, where a first-order quantum phase transition is commonly observed…
We review some of the most recent results on the dynamics of the Hamiltonian Mean Field (HMF) model, a systems of N planar spins with ferromagnetic infinite-range interactions. We show, in particular, how some of the dynamical anomalies of the model can be interpreted and characterized in terms of the weak-ergodicity breaking proposed in frameworks of glassy systems. We also discuss the connections with the nonextensive thermodynamics proposed by Tsallis.
Bento \textit{et al.} [Phys. Rev. E 91, 022105 (2015)] recently stated that the Tsallis entropy violates the third law of thermodynamics for $0 < q <1$ in the sub-additive regime. We first show that the division between the regimes $q < 1$ and $q > 1$ is already inherent in the fundamental incomplete structure of the deformed logarithms and exponentials underlying the Tsallis entropy. Then, we provide the complete deformed functions and show that the Tsallis entropy conforms to the third law of thermodynamics for both super-additive $q < 1$ and sub-additive $q > 1$ regimes. Finally, we remark …
Particle motion at the micro-scale is an incessant tug-of-war between thermal fluctuations and applied forces on one side, and the strong resistance exerted by fluid viscosity on the other. Friction is so strong that completely neglecting inertia - the overdamped approximation - gives an excellent effective description of the actual particle mechanics. In sharp contrast with this result, here we show that the overdamped approximation dramatically fails when thermodynamic quantities such as the entropy production in the environment is considered, in presence of temperature gradients. In the lim…
Curado \textit{et al.} [Ann. Phys. \textbf{366} (2016) 22] have recently studied the axiomatic structure and the universality of a three-parameter trace-form entropy inspired by the group-theoretical structure. In this work, we study the group-theoretical entropy $S_{a,b,r}$ in the context of the third law of thermodynamics where the parameters $\left\lbrace a,b,r \right\rbrace $ are all independent. We show that this three-parameter entropy expression can simultaneously satisfy the third law of thermodynamics and the three Khinchin axioms, namely continuity, concavity and expansibility only w…
In a finite system driven out of equilibrium by a constant external force the thermodynamic uncertainty relation (TUR) bounds the variance of the conjugate current variable by the thermodynamic cost of maintaining the non-equilibrium stationary state. Here we highlight a new facet of the TUR by showing that it also bounds the time-scale on which a finite system can exhibit anomalous kinetics. In particular, we demonstrate that the TUR bounds subdiffusion in a single file confined to a ring as well as a dragged Gaussian polymer chain even when detailed balance is satisfied. Conversely, the TUR …
In this work, low temperature thermodynamic behaviour in the context of dissipative diamagnetism with anomalous coupling is analyzed. We find that finite dissipation substitutes the zero-coupling result of exponential decay of entropy by a power law behaviour at low temperature. For Ohmic bath, entropy vanishes linearly with temperature, $T$, in conformity with Nernst's theorem. It is also shown that entropy decays faster in the presence of anomalous coupling than that of the usual coordinate-coordinate coupling. It is observed that velocity-velocity coupling is the most advantageous coupling …
We explore the metastability effects across the order-disorder transition pertaining to the peak effect phenomenonon in critical current density ($J_c$) via the first and the third harmonic ac susceptibility measurements in the weakly pinned single crystals of $2H$-$NbSe_2$. An analysis of our data suggests that an imprint of the limiting (spinodal) temperature above which $J_c$ is path independent can be conveniently located in the third harmonic data ($χ_{3ω}^{\prime}$).
The thermodynamics expected of systems undergoing third order phase transition has been investigated by identifying the orders through the analytic continuation of the functional of the free energy, using Ehrenfest thermodynamic theory. We developed the Euler - Lagrange equations for the order parameter and the vector potential and solved them for the first time using well - known mathematical formulations.
Thermodynamics, the branch of physics concerned with the description of macroscopic bodies, heat exchange and the conversion of different forms of energy is based on four laws: the zeroth law, which states that bodies in thermal contact reach a state of thermal equilibrium, the first law, which postulates the energy conservation and establishes the way in which different forms of energy transform into each-other, the second law, which states that the entropy increases or stays constant in time in any isolated system, and, finally, the third law (or Nernst postulate), which states that the entr…
The quantum thermodynamic property of the fractional damping system is investigated extensively. A fractional power-law decaying entropy function is revealed which presents another evidence for the validity of the third law of thermodynamics in the quantum dissipative region. Several non-trivial characters are excavated such as that the entropy varies from a non-linear diverging function to a semi-linear decaying function of the fractional exponent as the temperature tends to absolute zero.
The first in a long series of papers by John T. Lewis, G. W. Ford and the present author, considered the problem of the most general coupling of a quantum particle to a linear passive heat bath, in the course of which they derived an exact formula for the free energy of an oscillator coupled to a heat bath in thermal equilibrium at temperature T. This formula, and its later extension to three dimensions to incorporate a magnetic field, has proved to be invaluable in analyzing problems in quantum thermodynamics. Here, we address the question raised in our title viz. Nernst's third law of thermo…
The standard {\em system-plus-reservoir} approach used in the study of dissipative systems can be meaningfully generalized to a dissipative coupling involving the momentum, instead of the coordinate: the corresponding equation of motion differs from the Langevin equation, so this is called {\em anomalous} dissipation. It occurs for systems where such coupling can indeed be derived from the physical analysis of the degrees of freedom which can be treated as a dissipation bath. Starting from the influence functional corresponding to anomalous dissipation, it is shown how to derive the effective …
We study subdiffusive overdamped Brownian ratchets periodically rocked by an external zero-mean force in viscoelastic media within the framework of non-Markovian Generalized Langevin equation (GLE) approach and associated multi-dimensional Markovian embedding dynamics. Viscoelastic deformations of the medium caused by the transport particle are modeled by a set of auxiliary Brownian quasi-particles elastically coupled to the transport particle and characterized by a hierarchy of relaxation times which obey a fractal scaling. The most slowly relaxing deformations which cannot immediately follow…
The quantum thermodynamic behaviour of a charged oscillator in the presence of a magnetic field and coupled to a heat bath through different coupling schemes is obtained analytically. It is shown that finite dissipation substitutes the zero-coupling result of exponential decay of entropy by a power law behaviour at low temperature. For the coordinate-coordinates coupling scheme the low temperature explicit results for the case of Ohmic, exponentially correlated and more generalized heat bath models are derived. In all the above mentioned cases free energy and entropy vanish linearly with tempe…
The magnetization process of the S=1/2 Heisenberg antiferromagnet on the kagome lattice is studied by the numerical-diagonalization method. We successfully obtain a new result of the magnetization process of a 42-site cluster in the entire range. Our analysis clarifies that the critical behavior around one-third of the height of the saturation is different from the typical behavior of the well-known magnetization plateau in two-dimensional systems. We also examine the effect of the $\sqrt{3}\times\sqrt{3}$-type distortion added to the kagome lattice. We find at one-third of the height of the s…
The third law of thermodynamics in the form of the unattainability principle states that exact ground-state cooling requires infinite resources. Here we investigate the amount of non-equilibrium resources needed for approximate cooling. We consider as resource any system out of equilibrium, allowing for resources beyond the i.i.d. assumption and including the input of work as a particular case. We establish in full generality a sufficient and a necessary condition for cooling and show that for a vast class of non-equilibrium resources these two conditions coincide, providing a single necessary…
We employ classical thermodynamics to gain information about absolute entropy, without recourse to statistical methods, quantum mechanics or the Third Law of thermodynamics. The Gibbs-Duhem equation yields various simple methods to determine the absolute entropy of a fluid. We also study the entropy of an ideal gas and the ionization of a plasma in thermal equilibrium. A single measurement of the degree of ionization can be used to determine an unknown constant in the entropy equation, and thus determine the absolute entropy of a gas. It follows from all these examples that the value of entrop…
We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body systems. We first describe how an open system nonequilibrium dynamics (ONEq) approach is different from the closed combined system + environment in a global thermal state (CGTs) setup. Only after the open system equilibrates will it be amenable to conventional thermodynamics descriptions, thus quantum thermodynamics (QTD) comes at the end rather than assumed…
Thermodynamic conditions ensure the stability of third-order extended heat conduction
HUN-REN Wigner Research Centre for Physics（匈牙利科学院维格纳物理研究中心）；Budapest University of Technology and Economics（布达佩斯科技大学）；Montavid Thermodynamic Research Group（蒙塔维德热力学研究组）；Eötvös Loránd University（厄特沃什·罗兰大学）
We consider open quantum systems consisting of a finite system of independent fermions with arbitrary Hamiltonian coupled to one or more equilibrium fermion reservoirs (which need not be in equilibrium with each other). A strong form of the third law of thermodynamics, $S(T) \rightarrow 0$ as $T\rightarrow 0$, is proven for fully open quantum systems in thermal equilibrium with their environment, defined as systems where all states are broadened due to environmental coupling. For generic open quantum systems, it is shown that $S(T)\rightarrow g\ln 2$ as $T\rightarrow 0$, where $g$ is the numbe…
The mixed spin-1/2 Ising model and spin-1 Blume-Capel model in an hexagonal nanowire structure under the presence of crystal field is considered. The free energy is obtained through the transfer matrix technique, which is solved numerically. Our main result lies in the presence of pseudo-transition in low temperature region near the ferrimagnetic/ferromagnetic boundary, due to the influence of a crystal field. The evidence of a pseudo-transition is observed in several quantities. Free energy first derivative quantities like entropy and internal energy show an abrupt but continuous jump, wherea…
We study by molecular dynamics simulations the thermodynamics of an anomalous fluid confined in a slit pore with one wall structured and attractive and another unstructured and repulsive. We find that the phase diagram of the homogeneous part of the confined fluid is shifted to higher temperatures, densities and pressures with respect to the bulk, but it can be rescaled on the bulk case. We calculate a moderate increase of mobility of the homogeneous confined fluid that we interpret as a consequence of the layering due to confinement and the collective modes due to long-range correlations. We …
We study functionals, such as heat and work, along trajectories of a class of multi-dimensional generalized Langevin systems in various limiting situations that correspond to different level of homogenization. These are the situations where one or more of the inertial time scale(s), the memory time scale(s) and the noise correlation time scale(s) of the systems are taken to zero. We find that, unless one restricts to special situations that do not break symmetry of the Onsager matrix associated with the fast dynamics, it is generally not possible to express the effective evolution of these fun…
We derive the criterion for the Bose-Einstein condensation (BEC) of a Gaussian field $ϕ$ (real or complex) in the thermodynamic limit. The field is characterized by its covariance function and the control parameter is the intensity $u=\|ϕ\|_2^2/V$, where $V$ is the volume of the box containing the field. We show that for any dimension $d$ (including $d=1$), there is a class of covariance functions for which $ϕ$ exhibits a BEC as $u$ is increased through a critical value $u_c$. In this case, we investigate the probability distribution of the part of $u$ contained in the condensate. We show that…
We comment that the model proposed in Phys. Rev. Lett. 108, 120603 (2012) violates the dynamical version of the third law of thermodynamics. We discuses the different formulations of the third law of thermodynamics and suggest a possible reason for the violation.
We analyze several approaches to the thermodynamics of tachyon matter. The energy spectrum of tachyons $ε_k=\sqrt{k^2-m^2}$ is defined at $k\geq m$ and it is not evident how to determine the tachyonic distribution function and calculate its thermodynamical parameters. Integrations within the range $k\in (m,\infty) $ yields no imaginary quantities and tachyonic thermodynamical functions at zero temperature satisfy the third law of thermodynamics. It is due to an anomalous term added to the pressure. This approach seems to be correct, however, exact analysis shows that the entropy may become neg…
The third law of thermodynamics has a controversial past and a number of formulations due to Planck, Einstein, and Nernst. It's most accepted version, the unattainability principle, states that "any thermodynamic process cannot reach the temperature of absolute zero by a finite number of steps and within a finite time." Although formulated in 1912, there has been no general proof of the principle, and the only evidence we have for it is that particular cooling methods become less efficient as the temperature decreases. Here we provide the first derivation of a general unattainability principle…
In this work, we expose the role of environment, confinement and external magnetic field ($B$) in determining the low temperature thermodynamic behaviour in the context of cyclotron motion of a charged oscillator with anomalous dissipative coupling involving the momentum instead of the much studied coordinate coupling. Explicit expressions for different quantum thermodynamic functions (QTF) are obtained at low temperatures for different quantum heat bath characterized by spectral density function, $μ(ω)$. The power law fall of different QTF are in conformity with third law of thermodynamics. B…
We review the works devoted to third and fifth harmonic susceptibilities in glasses, namely $χ$ (3) 3 and $χ$ (5) 5. We explain why these nonlinear responses are especially well adapted to test whether or not some amorphous correlations develop upon cooling. We show that the experimental frequency and temperature dependences of $χ$ (3) 3 and of $χ$ (5) 5 have anomalous features, since their behavior is qualitatively different to that of an ideal gas, which is the high-temperature limit of a fluid. Most of the works have interpreted this anomalous behavior as reflecting the growth, upon cooling…
A free particle coupled to a heat bath can exhibit a number of thermodynamic anomalies like a negative specific heat or reentrant classicality. These low-temperature phenomena are expected to be modified at very low temperatures where finite-size effects associated with the discreteness of the energy spectrum become relevant. In this paper, we explore in which form the thermodynamic anomalies of the free damped particle appear for a damped harmonic oscillator. Since the discreteness of the oscillator's energy spectrum is fully accounted for, the results are valid for arbitrary temperatures. As…
Although the third law of thermodynamics was established almost a century ago, it is not yet universally considered to be a fundamental law of physics. A major problem is that there are many materials having residual entropy. Amorphous materials and random alloy systems are well-known examples. A conventional view is that amorphous materials are not in thermodynamic equilibrium and must be exempted from the law. The recent development of material sciences has let to a variety of new materials. Some of them have ambiguous structures which do not fit the qualitative description of metastability.…
We revisit here the effect of quantum dissipation on the much - studied problem of Landau diamagnetism, and analyze the results in the light of the third law of thermodynamics. The case of an additional parabolic potential is separately assessed. We find that dissipation arising from strong coupling of the system to its environment qualitatively alters the low-temperature thermodynamic attributes such as the entropy and the specific heat.
The temperature dependent effective potential (TDEP) method is generalized beyond pair interactions. The second and third order force constants are determined consistently from ab initio molecular dynamics simulations at finite temperature. The reliability of the approach is demonstrated by calculations of the Mode Grüneisen parameters for Si. We show that the extension of TDEP to higher order allows for an efficient calculation of the phonon life time, in Si as well as in $ε$-FeSi, a system that exhibits anomalous softening with temperature.
The Nernst formulation of the third law of ordinary thermodynamics (often referred to as the ``Nernst theorem'') asserts that the entropy, $S$, of a system must go to zero (or a ``universal constant'') as its temperature, $T$, goes to zero. This assertion is commonly considered to be a fundamental law of thermodynamics. As such, it seems to spoil the otherwise perfect analogy between the ordinary laws of thermodynamics and the laws of black hole mechanics, since rotating black holes in general relativity do not satisfy the analog of the ``Nernst theorem''. The main purpose of this paper is to …
Localization in one-dimensional disordered or quasiperiodic non-interacting systems in presence of power-law hopping is very different from localization in short-ranged systems. Power-law hopping leads to algebraic localization as opposed to exponential localization in short-ranged systems. Exponential localization is synonymous with insulating behavior in the thermodynamic limit. Here we show that the same is not true for algebraic localization. We show, on general grounds, that depending on the strength of the algebraic decay, the algebraically localized states can be actually either conduct…
